H317

Hazard statements (CLP)

H226, H302, H304, H315, H317, H319, H332, H335, H361d, H361f, H372, H400, H410, H412

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

SECTION 9. Physical and chemical properties VLEP FRA 215 50 - PNEC: Predicted no effect concentration Identification In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released. Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: WEL GBR x = Conc. % 430 100

2.1 Classification of the substance or mixture

1272/2008 (CLP) 1080 250 SECTION 14. Transport information Block the leakage if there is no hazard. STOT - SINGLE EXPOSURE - REACH: EC Regulation 1907/2006 None TLV GRC 425 100 1050 250 Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent - RID: Regulation concerning the international transport of dangerous goods by train 9.1. Information on basic physical and chemical properties

UN Number

STYRENE any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency OEL NLD 107

TOXICOLOGICAL INFORMATION

The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments CAS May cause respiratory irritation - TLV: Threshold Limit Value Substances subject to the Rotterdam Convention: The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments MAK 100-42-5 SWE 30 ≤ x < 40 43 10 Flam. Liq. 3 H226, Repr. 2 H361d, Acute Tox. 4 H332, STOT RE 1 H372, 86 20 SKIN procedures. - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. Appearance None and supplements). The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation 2015/830. TLV-ACGIH 85 20 Asp. Tox. 1 H304, Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, dense liquid 170 40 11.1. Information on toxicological effects ADR / RID, IMDG, IATA: STOT - REPEATED EXPOSURE - TWA STEL: Short-term exposure limit 3269 Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Predicted no-effect concentration - PNEC Colour Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Aquatic Chronic 3 H412, transparent Send away individuals who are not suitably equipped. Eliminate all sources of ignition (cigarettes, flames, sparks, etc.) from the leakage site. - TWA: Time-weighted average exposure limit 14.2. UN proper shipping name Odour Substances subject to the Stockholm Convention: Normal value in fresh water STYRENE Classification note according to Annex VI to the CLP Regulation: D characteristic of solvent 0,028 mg/l Hazard classification and indication: Causes damage to organs - VOC: Volatile organic Compounds EC Odour threshold None Hazard classification and indication: Normal value in marine water 202-851-5 -31°C 0,028 mg/l 6.2. Environmental precautions

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation Flammable liquid, category 3 STYRENE: Acute toxicity following inhalation at 1000 ppm involves the central nervous system with headache and dizziness, lack of H226 INDEX pH Normal value for fresh water sediment 601-026-00-0 Not available Flammable liquid and vapour. 0,614 ADR / RID:

Aspiration hazard

WGK: Water hazard classes (German). mg/kg coordination; irritation of the mucous membranes of the eyes and respiratory tract occurs at 500 ppm concentrations. Chronic POLYESTER RESIN KIT Reg. no. Melting point / freezing point Healthcare controls Reproductive toxicity, category 2 Normal value for marine water sediment Reproductive toxicity, category 2 01-2119457861-32 Not available H361d Suspected of damaging the unborn child. 0,0614 mg/kg The product must not penetrate into the sewer system or come into contact with surface water or ground water. IMDG: exposure produces depression of the Central and peripheral nervous system with loss of memory, headache and somnolence starting POLYESTER RESIN KIT COBALT BIS 2-ETHYL HEXANOATE Initial boiling point Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks Specific target organ toxicity - repeated exposure, Normal value for the terrestrial compartment Specific target organ toxicity - repeated exposure, 145 °C H372 Causes damage to organs through prolonged or repeated 0,2 Does not meet the classification criteria for this hazard class IATA: mg/kg at 20 ppm; digestive disorders with nausea and loss of appetite; irritation of the respiratory tract with chronic bronchitis and POLYESTER RESIN KIT exposure. CAS Health - Derived no-effect level - DNEL / DMEL Boiling range related to the workers' health and safety are modest and that the 98/24/EC directive is respected. category 1 136-52-7 0 ≤ x < 1 Repr. 2 H361f, Acute Tox. 4 H302, Skin Irrit. 2 H315, Skin Sens. 1 H317, Not available 6.3. Methods and material for containment and cleaning up GENERAL BIBLIOGRAPHY dermatosis. Flash point Eye irritation, category 2 Effects on consumers Aquatic Acute 1 H400 M=1, Aquatic Chronic 1 H410 M=1 31 °C H319 Effects on workers Causes serious eye irritation. 14.3. Transport hazard class(es) 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament 15.2. Chemical safety assessment EC Evaporation Rate Skin irritation, category 2

Principle Routes of Exposure

Skin irritation, category 2 205-250-6 Acute Not available Chronic H315 Chronic H315 Acute local Causes skin irritation. Acute

ECOLOGICAL INFORMATION

Collect the leaked product into a suitable container. If the product is flammable, use explosion-proof equipment. Evaluate the compatibility of Metabolism, toxicokinetics, mechanism of action and other information 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament Chronic INDEX Flammability of solids and gases Specific target organ toxicity - single exposure, local systemic Not available local H335 systemic H335 May cause respiratory irritation. systemic the container to be used, by checking section 10. Absorb the remainder with inert absorbent material. ADR / RID: 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament local systemic Class: 3 Label: 3 Reg. no. Lower inflammability limit This product is dangerous for the environment and the aquatic organisms. In the long term, it have negative effects on aquatic environment. No chemical safety assessment has been processed for the mixture and the substances it contains. category 3 Oral category 3 05-2117096703-34 Not available VND 2,1 Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. Information not available 4. Regulation (EU) 2015/830 of the European Parliament Upper inflammability limit Hazardous to the aquatic environment, chronic Not available H412 mg/kg H412 Harmful to aquatic life with long lasting effects. 12.1. Toxicity 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament The full wording of hazard (H) phrases is given in section 16 of the sheet. Lower explosive limit toxicity, category 3 Inhalation toxicity, category 3 182,75 174,25 Not available VND 10,6 306 289 6.4. Reference to other sections

Further information

Information on likely routes of exposure 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament VND 85 Upper explosive limit IMDG: Class: 3 mg/m3 Label: 3 Not available mg/m3

2.2 Label elements

7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament Vapour pressure Skin 6,67 VND hPa 343