Class: 3

Hazard statements (CLP)

H225, H226, H304, H315, H319, H336, H361d, H373

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Appearance TOLUENE The following sections were modified: Reg. no. 01-2119475103-46 MAK DEU

Special Provisions

640D 1500 400 liquid 3000 800 - ADR: European Agreement concerning the carriage of Dangerous goods by Road Colour Partition coefficient: n-octanol/water. IMDG: TLV DNK EMS: F-E, S-E 540 150 transparent 2,73 Limited Quantities: 5 L 6.2. Environmental precautions.

2.1 Classification of the substance or mixture

10.6. Hazardous decomposition products. Hydrocarbons, C11-C12, isoalkanes, < 2% aromatics 01 / 02 / 03 / 04 / 06 / 07 / 08 / 09 / 10 / 11 / 12 / 14 / 15. - CAS NUMBER: Chemical Abstract Service Number Odour BCF. IATA: The product must not penetrate into the sewer system or come into contact with surface water or ground water. VLA ESP Cargo: 1460 400 characteristic 90 Maximum quantity: 220 L Packaging instructions: 366 - CE50: Effective concentration (required to induce a 50% effect) CAS. 90622-57-4 20 ≤ x < 30 Flam. Liq. 3 H226, Asp. Tox. 1 H304, EUH066 Odour threshold. VLEP FRA Pass.: 1400 400 Not available. Maximum quantity: 60 L Packaging instructions: 355 The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released. - CE NUMBER: Identifier in ESIS (European archive of existing substances) The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments EC. 918-167-1 6.3. Methods and material for containment and cleaning up. pH. ETHYL ACETATE WEL GBR Special Instructions: 200 N. A. A3, A72, A192 400 and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and - CLP: EC Regulation 1272/2008 and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and INDEX. Melting point / freezing point. Partition coefficient: n-octanol/water. Collect the leaked product into a suitable container. If the product is flammable, use explosion-proof equipment. Evaluate the compatibility of TLV GRC 1400 400 Not available. 0,68 - DNEL: Derived No Effect Level Reg. no. 01-2119472146-39 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code. subsequent amendments. Initial boiling point. BCF. subsequent amendments. OEL NLD 550 > 35 30 1100 °C.

TOXICOLOGICAL INFORMATION

TOLUENE the container to be used, by checking section 10. Absorb the remainder with inert absorbent material. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. - EmS: Emergency Schedule Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Boiling range. NDS POL 200 Not available. 600 Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. - GHS: Globally Harmonized System of classification and labeling of chemicals CAS. 108-88-3 0 ≤ x < 1 Flam. Liq. 2 H225, Repr. 2 H361d, Asp. Tox. 1 H304, STOT RE 2 H373, Skin Irrit. 2 H315, 11.1. Information on toxicological effects. 12.4. Mobility in soil. Flash point. Information not relevant. MAK SWE 500 150 < 23 1100 °C. 300 Hazard classification and indication: - IATA DGR: International Air Transport Association Dangerous Goods Regulation Hazard classification and indication: STOT SE 3 H336 6.4. Reference to other sections. Evaporation Rate Information not available. TLV-ACGIH 1441 400 Not available. - IC50: Immobilization Concentration 50% EC. Flammable liquid, category 2 203-625-9 H225 Highly flammable liquid and vapour. Flammability of solids and gases TOLUENE Any information on personal protection and disposal is given in sections 8 and 13. Not available. SECTION 15. Regulatory information. - IMDG: International Maritime Code for dangerous goods INDEX. 601-021-00-3 Aspiration hazard, category 1 H304 May be fatal if swallowed and enters airways.

Results of PBT and vPvB assessment

Lower inflammability limit. It has a toxic effect on the central and peripheral nervous system (with encephalopathies and polyneuritis). Irritating to the skin, conjunctivae, Not available. - IMO: International Maritime Organization Reg. no. 01-2119471310-51 Eye irritation, category 2 H319 Causes serious eye irritation. Upper inflammability limit. cornea and respiratory apparatus. Not available. TOLUENE SECTION 7. Handling and storage. - INDEX NUMBER: Identifier in Annex VI of CLP Threshold Limit Value. Lower explosive limit. On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. Specific target organ toxicity - single exposure, category 3 H336 Not available. May cause drowsiness or dizziness. 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture. The full wording of hazard (H) phrases is given in section 16 of the sheet. - LC50: Lethal Concentration 50% Upper explosive limit. ACUTE TOXICITY. Type Country TWA/8h Not available. STEL/15min

2.2 Label elements

7.1. Precautions for safe handling. - LD50: Lethal dose 50% Vapour pressure. mg/m3 ppm Not available. mg/m3 ppm Seveso Category - Directive 2012/18/EC: P5c Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Vapours may catch fire and an explosion may - OEL: Occupational Exposure Level Vapour density LC50 (Inhalation - vapours) of the mixture: TLV BGR 150