Libman Toilet Bowl Cleaner Item 2070

Hazard statements (CLP)

H316, H319, H360, H402

Code

Statements

H316

Causes mild skin irritation

SECTION 2: Hazards identification

1999/45/EC EMERGENCY OVERVIEW: This product is a pale blue liquid with bubbles and a fresh scent.

Health hazards

May cause serious eye irritation. May be irritating to the skin. May be a reproductive hazard Flammability Hazards: This product is considered a Non-Flammable liquid. Reactivity Hazards: None.

Environmental hazards

The environmental effects of this product have not been investigated, however release may cause adverse environmental effects. US DOT SYMBOLS CANADA (WHMIS) SYMBOL(S) EUROPEAN and (GHS) Hazard Symbol(s) Non-Regulated Material Classified per WHMIS 2015

Signal word

Danger! EU LABELING AND CLASSIFICATION This product does meet the definition of a hazardous substance or preparation as defined by the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives EU HAZARD CLASSIFICATION OF INGREDIENTS PER DIRECTIVE 1272/2008/EC Index Number 603-411-9 is not listed in Annex VI 216-700-6 is not listed in Annex VI 215-090-9 is not listed in Annex VI Substances not listed either individually or in group entries must be self classified Component(s) Contributing to Classification(s) Borax, Lauramine oxide, Sodium xylene sulfonate

Classification according to GHS

Skin Irritation Category 3 Serious Eye Irritation Category 2A Reproductive Toxicity Category 1B Aquatic Acute Category 3

Hazard statements

H316: Causes mild skin irritation H319: Causes serious eye irritation H360: May damage fertility or the unborn child H402: Harmful to aquatic life

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P264: Wash thoroughly after handling. P280: Use protective gloves/protective clothing/eye protection/face protection. P273: Avoid release to the environment.

Response

P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313P IF EYE IRRITATION PERSISTS Get medical advice / attention P332+P313 If skin irritation occurs Get medical advice / attention P308+P313 IF exposed or concerned Get medical advice/attention

Storage

P403+P235: Store in a well-ventilated place. Keep cool P405: Store locked up.

Disposal

P501: Dispose of contents/container in accordance with local/regional/national/international regulations 2.3 HEALTH HAZARDS OR RISKS FROM EXPOSURE: SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of overexposure for this product are by contact with eyes and skin. The symptoms of overexposure are described in the following paragraphs. ACUTE: INHALATION: May cause mild respiratory system irritation. CONTACT WITH SKIN: May cause mild to moderate irritation. EYE CONTACT: Avoid contact with the eyes. May cause severe irritation, swelling, tearing, or redness. INGESTION: May cause irritation to the gastrointestinal tract, diarrhea, nausea or vomiting. CHRONIC: No data available. TARGET ORGANS Acute Eyes, Skin Chronic: No data available

2.1 Classification of the substance or mixture

This product does meet the definition of a hazardous substance or preparation as defined by the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives. EU HAZARD CLASSIFICATION OF INGREDIENTS PER DIRECTIVE 1272/2008/EC: Index Number: 603-411-9 is not listed in Annex VI 216-700-6 is not listed in Annex VI 215-090-9 is not listed in Annex VI Substances not listed either individually or in group entries must be self classified. Component(s) Contributing to Classification(s) Borax, Lauramine oxide, Sodium xylene sulfonate