not

Hazard statements (CLP)

H301, H302, H311, H314, H315, H317, H318, H330, H335, H400, H410, H411

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

GLYCOL 1B 603-027-00-1 arising from Skin the 0.1 substance corrosion, ≤ x < 0.15 category or mixture not available class 1B Acute Tox. 4 H302 Parliament +90 262 728 "ПРЕДЕЛЬНО 10 71 e-mail address of the competent person 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament ВРЕДНЫХ ВЕЩЕСТВ В ВОЗДУХЕ РАБОЧЕЙ ЗОНЫ" EC Colour TUR not applicable Avoid Eye Dam. exposure 1 203-473-3 to: sources of Serious Türkiye heat,naked eye damage, flames. not category Maddelerle Çalışmalarda Sağlık ve Güvenlik Önlemleri Hakkında Yönetmelik 12.08.2013 available ATE 1 Oral: 500 mg/kg responsible SERIOUS EYE 12. Regulation (EU) 2016/1179 (IX Atp. CLP) for the DAMAGE Safety / Data IRRITATION Sheet Kimyasal info@sandeco.com.tr 10.5. CAS Odour AMMONIA Incompatible Skin Irrit. CAUSED 2 107-21-1 materials BY EXPOSURE Skin irritation, IN THE EVENT / 28733; 20.10.2023 / 32345. category characteristic OF 2 FIRE 13. Regulation (EU) 2017/776 (X Atp. CLP) AMMONIA Do Melting Degradability: Transport STOT not breathe point SE / 3 information freezing combustion United class(es) point not products. Kingdom available Specific target organ not EH40/2005 toxicity Workplace exposure limits (Fourth Edition 2020) available - single exposure, category 3 1.4. 14.3. GBR Does 14. Emergency Regulation not meet hazard telephone the

EU Classification

2018/669 number (XI criteria Atp. CLP) for this

Hazard categories

INDEX Initial AMMONIA EU Skin boiling Sens. point 1 007-001-01-2 OEL EU Skin 0 sensitization, < x < 0.05 category Directive (EU) 2022/431; Directive (EU) 2019/1831; Directive (EU) 2019/130; Directive (EU) not available 1 Skin Corr. 1B H314, Eye Dam. 1 H318, STOT SE 3 H335, Aquatic Acute 1 5.3. Flammability 15. Regulation (EU) 2019/521 (XII Atp. CLP) 1,2-BENZISOTHIAZOLIN-3-ONE Advice Incompatible Skin Sens. for firefighters 1A with: silver,silver Skin salts,lead,lead sensitization, salts,zinc,zinc category not available 1A H400 salts,hydrochloric M=1, Classification acid,nitric note acid,oleum,halogens,acrolein,nitromethane,acrylic according to Annex VI to the CLP Regulation: For not applicable RESPIRATORY 16. Delegated Regulation (UE) 2018/1480 (XIII Atp. CLP) urgent inquiries OR refer SKIN to SENSITISATION 2019/983; Tel: Directive +90 262 (EU) 728 2017/2398; 10 88 Directive (EU) 2017/164; Directive 2009/161/EU; Directive Lower Solubility acid. Aquatic explosive in water Acute limit 1 Hazardous to the aquatic 2006/15/EC; not available Directive 1288

Environmental hazards

B mg/l 2004/37/EC; acute toxicity, category 1 Directive 2000/39/EC; Directive 98/24/EC; Directive 17. Regulation (EU) 2019/1148 Ulusal Zehir Danışma Merkezi(UZEM): 114 10.6. EC 14.4. Packing group GENERAL Upper Rapidly Hazardous Aquatic explosive degradable INFORMATION Chronic decomposition 215-647-6 limit 1 products Hazardous to the aquatic 91/322/EEC. not available STOT SE 3 chronic H335: toxicity, ≥ 5% category 1 Sensitising 18. Delegated CAS Use Flash Aquatic jets point of water for the Chronic Regulation 1336-21-6 to cool skin 2 the containers (UE) 2020/217 (XIV Atp. CLP) Hazardous to prevent to the aquatic product not available decomposition chronic and the toxicity, development category of 2 substances potentially hazardous for 19. Delegated Regulation (UE) 2020/1182 (XV Atp. CLP) TLV-ACGIH ACGIH 2023 SECTION 1,2-BENZISOTHIAZOLIN-3-ONE health. Auto-ignition AMMONIA 2-METHYLISOTHIAZOL-3(2H)-ONE not applicable H330 Always 2. temperature wear full fire prevention identification Fatal if gear. inhaled. Collect extinguishing not available water to prevent it from draining into the sewer system. Dispose of GERM 20. Delegated INDEX contaminated Decomposition Solubility May H301 develop: CELL MUTAGENICITY in water water Regulation (UE) 2021/643 (XVI Atp. CLP) temperature 613-088-00-6 nitric used oxide. for extinction Toxic 0 if < and swallowed. x < the 0.05 remains not of available 489000 the Acute fire according mg/l Tox. 4 H302, to applicable Eye Dam. regulations. 1 H318, Skin Irrit. 2 H315, Skin Sens. 1 H317, Delegated Regulation (UE) 2021/849 (XVII Atp. CLP) 2.1. 21. AMMONIA SPECIAL pH ETHYLENE Degradability: Classification H311 PROTECTIVE GLYCOL information of the substance EQUIPMENT not available Toxic or in mixture FOR contact FIRE-FIGHTERS with 8-9 skin Aquatic Acute 1 H400 M=1, Aquatic Chronic 2 H411 Threshold Does 22. Delegated Environmental not meet Regulation Limit Value the classification hazards UE) 2022/692 criteria for (XVIII this hazard Atp. CLP) class EC Normal Kinematic May H302 fire Type develop viscosity fighting 220-120-9 hydroxyacetaldehyde,glyoxal,acetaldehyde,methane,carbon clothing i.e. fire Country Harmful TWA/8h kit (BS if swallowed EN 469), gloves not available BS Skin EN Sens STEL/15min 659) 1 and H317 boots monoxide,hydrogen (HO 0.05% specification A29 and A30) in combination with Remarks / Observations The 23. Delegated CAS self-contained Dynamic ETHYLENE H314 product viscosity GLYCOL is Regulation open classified (UE) 2023/707 2634-33-5 circuit as positive hazardous Causes pressure pursuant severe compressed skin to the VISCOUS burns provisions air and breathing ATE eye Oral set damage forth apparatus 500 in mg/kg EC) (BS Regulation Dam. 1 H318, are given Skin in Sens sections 1A H317, and Aquatic of this Acute contains, The Merck sheet. 1 H400 M=10, using Index the - criteria 10th Edition specified in the applicable regulation for classification Density It not Personal is applicable Bioaccumulative H317 and/or relative potential therefore precautions, necessary to protective density May cause an allergic 1.23 take into account equipment the concentration and emergency skin reaction Aquatic Chronic 1 H410 M=1, EUH071 of the procedures individual hazardous substances indicated in section 3, to evaluate the Temperature: 20 °C Hazard Handling ETHYLENE EC Relative H400 classification vapour 220-239-6 Chemical GLYCOL density and indication Safety Very toxic to aquatic not life. available Skin Sens. 1A H317: ≥ 0.0015% toxicological effects of exposure to the product INRS - Available Fiche Toxicologique studies have (toxicological shown no carcinogenic sheet) potential. In a carcinogenicity study lasting two years, carried out by the US National ETHYLENE GLYCOL 14.7. Block CAS Particle Threshold Maritime Skin H410 characteristics the leakage sensitization, Limit transport 2682-20-4 Value if there in is bulk category 1A Very toxic to aquatic not no hazard according to IMO instruments life applicable with ATE long Oral lasting 100 H317 effects mg/kg, ATE May Dermal cause 300 an allergic mg/kg, skin LC50 reaction Inhalation Patty - Toxicology 1,2-BENZISOTHIAZOLIN-3-ONE H411 Industrial Hygiene Program and (NTP), Toxicology Toxic to aquatic life with long mists/powders in which ethylene glycol was administered in the feed, "no evidence of carcinogenic activity" in male and lasting effects. 0.11 mg/l/4h Wear N.I. Sax female Information Type suitable protective Dangerous B6C3F1 properties on hazard Country mice was of observed equipment classes TWA/8h as Industrial (NTP, including defined personal Materials-7, in Regulation 1993). 1989 Edition protective EC) equipment STEL/15min

Results of PBT and vPvB assessment

International Maritime Code for dangerous goods medical Any well information Does Regulation Contact: aired anuria not hamit.aydin@sandeco.com.tr advice/attention. meet through (EU) the 2019/1148 and on effective

2.1 Classification of the substance or mixture

EQUIPMENT not available Toxic or in mixture FOR contact FIRE-FIGHTERS with 8-9 skin. Aquatic Acute 1 H400 M=1, Aquatic Chronic 2 H411 14.5. Threshold Does 22. Delegated Environmental not meet Regulation Limit Value the classification hazards (UE) 2022/692 criteria for (XVIII this hazard Atp. CLP) class EC Normal Kinematic May H302 fire Type develop: viscosity fighting 220-120-9 hydroxyacetaldehyde,glyoxal,acetaldehyde,methane,carbon clothing i.e. fire Country Harmful TWA/8h kit (BS if swallowed. EN 469), gloves not available (BS Skin EN Sens. STEL/15min 659) 1 and H317: boots monoxide,hydrogen. ≥ (HO 0.05% specification A29 and A30) in combination with Remarks / Observations The 23. Delegated CAS self-contained Dynamic ETHYLENE H314 product viscosity GLYCOL is Regulation open classified (UE) 2023/707 2634-33-5 circuit as positive hazardous Causes pressure pursuant severe compressed skin to the VISCOUS burns provisions air and breathing ATE eye Oral: set damage. forth apparatus 500 in mg/kg (EC) (BS Regulation EN 137). 1272/2008 Temperature: (CLP) 25 (and SECTION not applicable CARCINOGENICITY 24. Delegated 11. Toxicological information °C subsequent Regulation (UE) 2023/1434 mg/m3 (XIX Atp. ppm CLP) mg/m3 ppm amendments 2-METHYLISOTHIAZOL-3(2H)-ONE Solubility H318 in water and supplements). Causes The product serious thus eye requires not damage. available 1000 a safety - 10000 datasheet mg/l that complies with the provisions of (EU) Regulation 24. Delegated Regulation (UE) 2023/1435 (XX Atp. CLP) OEL EU 14 20 36 50 2020/878. INDEX Partition Rapidly H315 degradable coefficient: 613-326-00-9 n-octanol/water Causes 0.0015 skin ≤ irritation. x < 0.06 not available Acute Tox. 2 H330, Acute Tox. 3 H301, Acute Tox. 3 H311, Skin Corr. 1B 14.6. In SECTION Does the Special not absence meet precautions the of experimental Accidental classification for user data release criteria for for the this product hazard itself, class health hazards are evaluated according to the properties of the substances it Any Vapour H335 additional 6. pressure information concerning May cause the risks measures respiratory for health not irritation. available and/or H314, the Eye environment Dam. 1 H318, are given Skin in Sens. sections 1A H317, 11 and Aquatic 12 of this Acute contains, - The Merck sheet. 1 H400 M=10, using Index. the - criteria 10th Edition specified in the applicable regulation for classification. 12.3. Density 6.1. It not Personal is applicable Bioaccumulative H317 and/or relative potential therefore precautions, necessary to protective density May cause an allergic 1.23 take into account equipment the concentration and emergency skin reaction. Aquatic Chronic 1 H410 M=1, EUH071 of the procedures individual hazardous substances indicated in section 3, to evaluate the Temperature: 20 °C Hazard - Handling ETHYLENE EC Relative H400 classification vapour 220-239-6 Chemical GLYCOL density and indication: Safety Very toxic to aquatic not life. available Skin Sens. 1A H317: ≥ 0.0015% toxicological effects of exposure to the product. - INRS - Available Fiche Toxicologique studies have (toxicological shown no carcinogenic sheet) potential. In a carcinogenicity study lasting two years, carried out by the US National ETHYLENE GLYCOL 14.7. Block CAS Particle Threshold Maritime Skin H410 characteristics the leakage sensitization, Limit transport 2682-20-4 Value if there in is bulk category 1A Very toxic to aquatic not no hazard. according to IMO instruments life applicable with ATE long Oral: lasting 100 H317 effects. mg/kg, ATE May Dermal: cause 300 an allergic mg/kg, skin LC50 reaction. Inhalation - Patty - Toxicology 1,2-BENZISOTHIAZOLIN-3-ONE H411 Industrial Hygiene Program and (NTP), Toxicology Toxic to aquatic life with long mists/powders: in which ethylene glycol was administered in the feed, "no evidence of carcinogenic activity" in male and lasting effects. 0.11 mg/l/4h 11.1. Wear - N.I. Sax female Information Type suitable protective - Dangerous B6C3F1 properties on hazard Country mice was of observed equipment classes TWA/8h as Industrial (NTP, (including defined personal Materials-7, in Regulation 1993). 1989 Edition protective (EC) equipment STEL/15min No 1272/2008 referred to under Section Remarks 8 of / Observations the safety data sheet) to prevent Partition EUH071 coefficient: n-octanol/water Corrosive to the respiratory 0.7 tract. any Information contamination not relevant website of skin, eyes and mg/m3 personal clothing. ppm These indications 2.2. - IFA mg/m3 apply for both The BCF Label GESTIS full elements wording of hazard (H) phrases is given in section 16 ppm processing staff and those involved in emergency

Hazard statements

Identifier of available in Annex data, VI of the CLP product does not contain any PBT or vPvB in percentage ≥ than 0,1%. 11.2. CALCULATION Personal protective equipment must be CE marked, showing that it complies with applicable standards. Information on METHODS

2.3 Other hazards

FOR - LC50: Lethal Concentration 50% May H317 cause an allergic skin reaction. Rescuer Provide Interactive an protection effects emergency shower with face and eye wash station. classification derives from criteria established by the CLP Regulation, Annex I, Part 2. The data for Substances Chemical and in physical Candidate hazards: List (Art. Product 59 REACH) ... / >>

Precautionary statements

P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P333+P313 If skin irritation or rash occurs: Get medical advice / attention. P362+P364 Take off contaminated clothing and wash it before reuse. P280 Wear protective gloves. P321 Specific treatment (see . . . on this label). P272 Contaminated work clothing should not be allowed out of the workplace.

Contains

2-METHYLISOTHIAZOL-3(2H)-ONE 1,2-BENZISOTHIAZOLIN-3-ONE

Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%.