Note: Ingredients listed on restricted chemical lists
EC/CAS
811-97-2
Name of the chemical
1,1,1,2-Tetrafluoroethane
Concentration
N/A
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
N/A
General Information
Revision date
2008-05-22
Product name
Polyurethane Foam System
1.2.1 Relevant identified uses
POLYURETHANE FOAM SYSTEM - ISOCYANATE
Emergency telephone
989-636-4400
Icons in SDS
Company Information
company name
The Dow Chemical Company
GHS Information
Signal word
WARNING!
Section 2
SECTION 2: Hazards identification
29 CFR 1910.1200) Emergency Overview Color: Brown Physical State: Liquid Odor: Musty Hazards of product: WARNING! May cause eye irritation. May cause skin irritation. May cause allergic skin reaction. May cause allergic respiratory reaction. Vapor reduces oxygen available for breathing. May cause central nervous system effects. Keep upwind of spill. May cause anesthetic effects. May cause respiratory tract irritation. May cause lung injury. May react with water. Stay out of low areas. Material reacts slowly with water, releasing carbon dioxide which can cause pressure buildup and rupture of closed containers. Elevated temperatures accelerate this reaction. Toxic fumes may be released in fire situations. Contents under pressure. Avoid temperatures above 41 °C (106 °F). Avoid temperatures below 20 °C (68 °F). OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Potential health effects
Eye Contact: May cause moderate eye irritation. May cause slight temporary corneal injury. Skin Contact: Prolonged contact may cause skin irritation with local redness. May stain skin. Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts. Skin Sensitization: Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. Inhalation: In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.) Effects may be delayed. Decreased lung function has been associated with overexposure to isocyanates. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). May cause central nervous system effects. Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed. Respiratory Sensitization: May cause allergic respiratory response. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. Observations in animals include: Gastrointestinal irritation. Effects of Repeated Exposure: Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols.
Cancer information
Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI. Birth Defects/Developmental Effects: In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Based on information for component(s): 1,1,1,2-Tetrafluoroethane. Has been toxic to the fetus in lab animals at doses toxic to the mother.