None

the danzer group

Revision date : 2014-06-02

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GHS07 GHS08
Health risk rating 4
Safety risk rating 1
Environmental risk rating 1

General Information

Revision date

2014-06-02

Product name

None

1.2.1 Relevant identified uses

Composite adhesive

Emergency telephone

(+41 44 251 51 51 Tox Center

Icons in SDS

GHS07 GHS08

Company Information

company name

the danzer group

GHS Information

Signal word

Warning

Hazard Codes

Hazard statements (CLP)

H315, H319, H332, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

EU Classification

Regulation (EC) No 1272/2008 (GHS/CLP) Acute toxicity, inhal., Gases, Cat. 4, H332 Skin corrosion/irritation, Cat. 2, H315 Serious eye damage/eye irritation, Cat. 2, H319 Carcinogenicity, Cat. 2, H351 Specific target organ toxicity (repeated exposure), Cat. 2, H373 Contains isocyanates. May produce an allergic reaction The product is classified and labelled according to Regulation (EC) No. 1272/2008 (GHS/CLP). Xn; R20 Directives 67/548/EEC or 1999/45/EC Carc. Cat. 3; R40 Xi; R36/37/38 R42/43 Xn; R48/20

Additional information

For the full text of the phrases mentioned in this Section, see Section 16.

2.2 Label elements

Warning H315: Causes skin irritation. H319: Causes serious eye irritation. H332: Harmful if inhaled.

Hazard statements

H351: Suspected of causing cancer. H373: May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

P201: Obtain special instructions before use. P260: Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P280c: Wear protective gloves/ eye protection/ face protection. P302+P352 IF ON SKIN Wash with plenty of water/…. P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Additional advice Contains isocyanates. May produce an allergic reaction.

Product definition

4-Isocyanatosulphonyltoluene; Tosyl isocyanate, CAS-No. 4083-64-1, EC- No. 223-810-8 Polypropylenglykol, CAS-No. 25322-69-4, EC-No. 500-039-8 diphenylmethane-4,4'-diisocyanate, oligomers, CAS- No. 25686-28-6, EC- No. 500-040-3 Labelling according to Directives 67/548/EEC or 1999/45/EC Xn - Harmful.

R-phrase(s)

R36/37/38: Irritating to eyes, respiratory system and skin. R42/43: May cause sensitization by inhalation and skin contact. R48/20 Harmful danger of serious damage to health by prolonged exposure through inhalation. R20: Harmful by inhalation. R40: Limited evidence of a carcinogenic effect.

S-phrase(s)

S23: Do not breathe vapor/spray S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37: Wear suitable protective clothing and gloves. S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Additional advice Contains isocyanates. See information supplied by the manufacturer. Hazardous component(s) which must 4-Isocyanatosulphonyltoluene; Tosyl isocyanate, be listed on the label CAS-No. 4083-64-1, EC-No. 223-810-8 Polypropylenglykol, CAS-No. 25322-69-4, EC-No. 500-039-8 diphenylmethane-4,4'-diisocyanate, oligomers, CAS- No. 25686-28-6, EC-No. 500-040-3

2.3 Other hazards

Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. Persons already sensitized to diisocyanates may develop allergic reactions when using this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.

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