Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
26447-40-5
Name of the chemical
Methylenediphenyl diisocyanate (see also specific isomers)
Concentration
N/A
General Information
Revision date
2016-11-01
Product name
Deckguard Repair Caulk - Part A
1.2.1 Relevant identified uses
Self-leveling elastomer designed to repair small areas of Deckguard membrane
1.2.2. Uses advised against
of
Emergency telephone
1-800-424-9300 International 01-703-741-5500
Icons in SDS
Company Information
company name
The D.S. Brown Company
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H320, H332, H334, H335, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
GHS Classification ACCORDING TO REGULATION 2012 OSHA HAZARD COMMUNICATION STANDARD; 29 CFR PART 1910.1200
2.1 Classification of the substance or mixture
Acute Toxicity (Inhalation – Mist) – Category 4 Skin Corrosion/Irritation – Category 2 Eye Damage/Eye Irritation – Category 2B Respiratory Sensitization – Category 1 Skin Sensitization – Category 1B STOT SE – Category 3 (Irritating to Respiratory System) STOT RE – Category 2 (By Inhalation)
Signal word
DANGER
Hazard statements
H332 Harmful if inhaled. H315 Causes skin irritation. H320 Causes eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H373 May cause damage to organs (Olfactory organs) through prolonged or repeated exposure (inhalation).
Prevention
P271 Use only outdoors or in a well-ventilated area. P264 Wash with plenty of water and soap thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P284 In case of inadequate ventilation wear respiratory protection. P272 Contaminated work clothing should not be allowed out of the workplace. P260 Do not breathe dust/gas/mist/vapors. P261 Avoid breathing mist. Identification cont’d CLASSIFICATION OF THE SUBSTANCE OR MIXTURE cont’d.
Response
P304+340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P303+352 IF ON SKIN (or hair): Wash with plenty of soap and water. P332+313 If skin irritation occurs: Get medical advice/attention. P362+364 Take off contaminated clothing and wash before reuse. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+311 If eye irritation persists: Call a POISON CENTER or doctor/physician. P333+311 If skin irritation or rash occurs: Call a POISON CENTER or doctor/ physician. P314 Get medical advice/attention if you feel unwell.
Storage
P405: Store locked up. P403+233 Store in a well-ventilated place. Keep container tightly closed. Precautionary : P501 Dispose of contents/container in accordance with federal, state and local
Disposal
environmental control laws.
2.3 Other hazards
No specific dangers know, if the regulations/notes for storage and handling are considered. Labeling of special preparations (GHS): CONTAINS ISOCYANATES. INHALATION OF ISOCYANATES MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE. INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION.