Eco-Crete Part B

Tennant Company

Revision date : 2019-03-11

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

30-60%

EC/CAS

500-079-6/9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

30-60%

EC/CAS

247-714-0/26447-40-5

Name of the chemical

Methylenediphenyl diisocyanate (see also specific isomers)

Concentration

10-30%

General Information

Revision date

2019-03-11

Product name

Eco-Crete Part B

1.2.1 Relevant identified uses

Various uses

1.2.2. Uses advised against

N/A 1.3 NORTH AMERICA

Manufacturer Name

Tennant Company

Icons in SDS

GHS07 GHS08

Company Information

company name

Tennant Company

e-mail address of the competent person responsible for the Safety Data Sheet

info@tennantco.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

OSHA HCS 2012 EMERGENCY OVERVIEW: This product is a dark brown liquid with a musty odor.

Health hazards

Exposure may cause irritation to skin. May cause irritation to eyes upon contact. Inhalation of vapors or mist at high concentrations may be harmful. May cause skin and respiratory sensitization. Flammability Hazards: This product is not a flammable liquid with an estimated flash point of 390.2°F (199°C). Reactivity Hazards: None known

Environmental hazards

The Environmental effects of this product have not been investigated. Release of this product may have significant adverse effects in the aquatic environment. US DOT SYMBOLS CANADA (WHMIS) SYMBOLS EUROPEAN and (GHS) Hazard Symbols See Section 14 for Details Complies with WHMIS 2015

Signal word

Danger! 2.1 EU LABELING AND CLASSIFICATION: This product does meet the definition of a hazardous substance or preparation as defined by: OSHA HCS 2012 (29 CFR 1910. 1200) AND the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC, 2015/830/EU and subsequent Directives AND Mexico NOM-018-STPS-2015. EU HAZARD CLASSIFICATION OF INGREDIENTS: Index Number: EC# 202-966-0 Annex VI Index# 615-005-00-9 EC# 500-079-6 is not listed in Annex VI EC# 247-714-0 Annex VI Index# 615-005-00-9 Remainder of components are not listed in Annex VI Substances not listed either individually or in group entries must be self classified. Component(s) Contributing to Classification(s) All components in Section 3

Classification according to GHS

Acute Toxicity Category 4 (Inhalation) Skin Irritation Category 2 Eye Irritant Category 2A Respiratory Sensitization Category 1 Skin Sensitization Category 1 Carcinogenicity Category 2 Specific Target Organ Toxicity – Single Exposure Category 3 (Respiratory Irritation) Specific Target Organ Toxicity – Repeated Exposure Category 2

Hazard statements

H332: Harmful if inhaled H315: Causes skin irritation H319: Causes serious eye irritation H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled H317: May cause an allergic skin reaction H351: Suspected of causing cancer H335: May cause respiratory irritation H373: May cause damage to organs through prolonged or repeated exposure

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe dust/fumes/gas/mist/vapours/spray. P264: Wash thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/ protective clothing / eye and face protection. P284: [In case of inadequate ventilation] wear respiratory protection.

Response

Phrases P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P312: Call a POISON CENTER/doctor if you feel unwell. P302+P352 IF ON SKIN Wash with plenty of water P321: Specific treatment (See Section 4 on this SDS) P333+P313 If skin irritation or rash occurs Get medical attention P362+P364: Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists Get medical advice/attention P342+P311 If experiencing respiratory symptoms Call a POISON CENTER/doctor P308+P313 IF exposed or concerned Get medical advice/attention

Storage

Phrases P405: Store locked up. P403+P233: Store in a well-ventilated place. Keep container tightly closed.

Disposal

Phrases P501: Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3 HEALTH HAZARDS OR RISKS FROM EXPOSURE: SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of overexposure for this product are by contact with skin or eyes, inhalation and ingestion. The symptoms of overexposure are described below. ACUTE: INHALATION: Inhalation of vapors or mists in high concentrations may cause respiratory irritation. Chronic inhalation can result in sensitization. CONTACT WITH SKIN: Mild to moderate irritant. Contact may cause irritation consisting of transient redness and/or swelling. May cause allergic reaction. EYE CONTACT: Moderate irritant. Liquids, vapors, or mists are irritating to the eyes and can cause stinging, burning, lachrymation, or tearing. INGESTION: Ingestion may cause irritation of the gastrointestinal tract and gastrointestinal discomfort with any or all of the following symptoms: nausea, vomiting, lethargy, or diarrhea. CHRONIC: Prolonged or repeated exposure may cause cancer. TARGET ORGANS Acute Skin, Respiratory System and Eyes Chronic Skin, Respiratory System

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