Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
>75%
General Information
Revision date
2017-08-30
Product name
Tennant Eco-PJF Part B
Product Synonyms
Polyurethane Elastomer
1.2.1 Relevant identified uses
Part B of a two-component poured polyurethane elastomer CHEMICAL SHIPPING NAME/CLASS See Section 14 for Details
Manufacturer Name
Tennant Company
Emergency telephone
800-424-9300, 1-703-527-3887
Icons in SDS
Company Information
company name
Tennant Benelux N.V
e-mail address of the competent person responsible for the Safety Data Sheet
info@tennantco.com
GHS Information
Signal word
Danger!
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351
Hazard statements
Code
Statements
H315
Causes skin irritation
H317
May cause an allergic skin reaction
H319
Causes serious eye irritation
H332
Harmful if inhaled
H334
May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335
May cause respiratory irritation
H351
Suspected of causing cancer
Section 2
SECTION 2: Hazards identification
1999/45/EC EMERGENCY OVERVIEW: This product is a pale colored liquid with a musty odor.
Health hazards
Exposure may cause mild to moderate irritation to skin. May cause moderate irritation to eyes upon contact. Inhalation of vapors or mist at high concentrations can cause respiratory irritation. May be harmful if swallowed. Flammability Hazards: This product is a Non-Flammable liquid with a flash point of >200°F (>93°C) Reactivity Hazards: None known
Environmental hazards
The Environmental effects of this product have not been investigated. Release of this product may have significant adverse effects in the aquatic environment. US DOT SYMBOLS
Signal word
Danger! EU LABELING AND CLASSIFICATION This product does meet the definition of a hazardous substance or preparation as defined by the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives EU HAZARD CLASSIFICATION OF INGREDIENTS Index Number EC# 202-966-0 Annex VI Index# 615-005-00-9 EC# 203-572-1 Annex VI Index# 607-194-00-1 Substances not listed either individually or in group entries must be self classified Component(s) Contributing to Classification(s) All Components
Classification according to GHS
Acute Inhalation Toxicity Category 4 Skin Irritant Category 2 Eye Irritant Category 2 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Carcinogenetic Category 2 STOT SE Category 3 STOT SE Category 2
Hazard statements
H332: Harmful if inhaled H315: Causes skin irritation H319: Causes serious eye irritation H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled H317: May cause an allergic skin reaction H351: Suspected of causing cancer H335: May cause respiratory irritation
Prevention
P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe dust/fumes/gas/mist/vapours/spray P264: Wash thoroughly after handling P271: Use only outdoors or in a well-ventilated area P272: Contaminated work clothing should not be allowed out of the workplace P280: Wear protective gloves/ eye protection P284: In case of inadequate ventilation, wear respiratory protection.
Response
P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P312: Call a POISON CENTER/doctor if you feel unwell. P342+P311 If experiencing respiratory symptoms Call a POISON CENTER/doctor P302+P352 IF ON SKIN Wash with plenty of water P321: Specific treatment (See Section 4 on this SDS) P333+P313 If skin irritation or rash occurs Get medical attention P362+P364: Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists Get medical advice/attention P308+P313 IF exposed or concerned Get medical advice/attention P314: Get medical advice/attention if you feel unwell.
Storage
P403+P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up.
Disposal
P501: Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3 HEALTH HAZARDS OR RISKS FROM EXPOSURE: SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of overexposure for this product are by contact with skin or eyes, inhalation and ingestion. The symptoms of overexposure are described below. ACUTE: INHALATION: Inhalation of vapors or mists in high concentrations may cause respiratory irritation. Chronic inhalation can result in sensitization. CONTACT WITH SKIN: Mild to moderate irritant. Contact may cause irritation consisting of transient redness and/or swelling. May cause allergic reaction. EYE CONTACT: Moderate irritant. Liquids, vapors, or mists are irritating to the eyes and can cause stinging, burning, lachrymation, or tearing. INGESTION: Ingestion may cause irritation of the gastrointestinal tract and gastrointestinal discomfort with any or all of the following symptoms: nausea, vomiting, lethargy, or diarrhea. CHRONIC: Prolonged or repeated exposure may cause cancer. TARGET ORGANS Acute Skin, Respiratory System and Eyes Chronic Skin, Respiratory System
2.1 Classification of the substance or mixture
This product does meet the definition of a hazardous substance or preparation as defined by the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives. EU HAZARD CLASSIFICATION OF INGREDIENTS: Index Number: EC# 202-966-0 Annex VI Index# 615-005-00-9 EC# 203-572-1 Annex VI Index# 607-194-00-1 Substances not listed either individually or in group entries must be self classified. Component(s) Contributing to Classification(s)