Tennant Eco-MVS Part B

Hazard statements (CLP)

H302, H314, H317, H361, H410

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

1999/45/EC EMERGENCY OVERVIEW: This product is a clear liquid with an amine-like odor.

Health hazards

Corrosive Exposure may cause mild to moderate irritation to skin. May cause severe irritation to eyes upon contact with possible tissue damage. Inhalation of vapors or mist at high concentrations can cause respiratory irritation. May be harmful if swallowed. Flammability Hazards: This product is a non-flammable liquid with a flash point of >200°F (>93°C) Reactivity Hazards: None known

Environmental hazards

The Environmental effects of this product have not been investigated. Release of this product may have significant adverse effects in the aquatic environment. US DOT SYMBOLS

Signal word

Danger! GHS LABELING AND CLASSIFICATION

Classification according to GHS

Acute Toxicity Category 4 (Oral) Skin Corrosion Category 1 Skin Sensitization Category 1 Reproductive Toxicity Category 2 Aquatic Chronic Category 1

Hazard statements

H302: Harmful if swallowed H314: Causes severe skin burns and eye damage H317: May cause an allergic skin reaction H361: Suspected of damaging fertility or the unborn child H410: Very toxic to aquatic life with long lasting effects

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P272: Contaminated work clothing should not be allowed out of the workplace. P264: Wash thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing/eye protection/face protection.

Response

P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P303+P361+P353 IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P363: Wash contaminated clothing before reuse. P333+P313 If skin irritation or rash occurs Get medical advice/attention P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P310: Immediately call a POISON CENTER/doctor. P321: Specific treatment (See Section 4 of this SDS). P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362+P364: Take off contaminated clothing and wash it before. P308+P313 IF exposed or concerned Get medical advice/attention P391: Collect spillage.

Storage

P405: Store locked up.

Disposal

P501: Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3 HEALTH HAZARDS OR RISKS FROM EXPOSURE: SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of overexposure for this product are by contact with skin or eyes, inhalation and ingestion. The symptoms of overexposure are described below. ACUTE: INHALATION: If mists or sprays of this solution are inhaled, this product may cause pulmonary irritation, irritation of the mucus membranes, and coughing. CONTACT WITH SKIN: Prolonged or repeated skin contact may dry the skin. Symptoms may include redness, drying and cracking of skin. Additional symptoms of skin contact may include: allergic skin reaction (delayed skin rash which may be followed by blistering, scaling and other skin effects), and numbness. Passage of this material into the body through the skin is possible, and may add to toxic effects from breathing or swallowing. EYE CONTACT: Severe irritation and/or burns can occur following eye exposure. Contact may cause impairment of vision and injure eye tissue. INGESTION: Though ingestion is not anticipated to be a significant route of over-exposure to this product, if ingestion does occur, irritation of the mouth, throat, esophagus, and other tissues of the digestive system may occur upon contact. CHRONIC: Repeated skin contact with this product may result in dermatitis (inflammation and reddening of the skin). TARGET ORGANS Acute Skin, Respiratory System and Eyes Chronic Skin

2.1 Classification of the substance or mixture

CLASSIFICATION OF SUBSTANCE OR MIXTURE IN ACCORDANCE WITH 29 CFR 1200 (OSHA HCS) AND THE EUROPEAN UNION DIRECTIVES: This product does meet the definition of a hazardous substance or preparation as defined by 29 CFR 1910. 1200 AND the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives. EU HAZARD CLASSIFICATION OF INGREDIENTS: Index Number: EC# 695-873-3 is not listed in Annex VI EC# 284-325-5 Annex VI Index# 601-053-00-8 EC# 247-134-8 is not listed in Annex VI EC# 216-032-5 is not listed in Annex VI EC# 202-679-0 Annex VI Index# 604-090-00-8 EC# 202-013-9 Annex VI Index# 603-069-00-0 EC# 275-162-0 is not listed in Annex VI Substances not listed either individually or in group entries must be self classified. Component(s) Contributing to Classification(s) All Components in Section 3