Note: Ingredients listed on restricted chemical lists
EC/CAS
212-485-8/822-06-0
Name of the chemical
Hexamethylene diisocyanate
Concentration
0.1--1%
General Information
Revision date
2018-09-05
Product name
Tennant CRU - Part A
Product Synonyms
Urethane Polymer
1.2.1 Relevant identified uses
Various uses CHEMICAL SHIPPING NAME/CLASS Resin Solution, Class 3, PGIII
Manufacturer Name
Tennant Company
Emergency telephone
800-424-9300, 1-703-527-3887
Icons in SDS
Company Information
company name
Tennant Benelux N.V
e-mail address of the competent person responsible for the Safety Data Sheet
info@tennantco.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H312, H315, H317, H319, H332, H334
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
1999/45/EC EMERGENCY OVERVIEW: This product is a neutral colored liquid with a slight odor.
Health hazards
Exposure may cause irritation to skin. May be harmful if absorbed through the skin or inhaled. May cause allergic skin or respiratory system reaction. May cause irritation to eyes upon contact. Flammability Hazards: This product is a Flammable liquid with a flash point of 80°F (26.7°C) Reactivity Hazards: None known
Environmental hazards
The Environmental effects of this product have not been investigated. Release of this product may have significant adverse effects in the aquatic environment. US DOT SYMBOLS
Signal word
Danger EU LABELING AND CLASSIFICATION This product does meet the definition of a hazardous substance or preparation as defined by the European Union Council
Classification according to GHS
Flammable Liquid Category 2 Acute Toxicity Category 4 (Dermal) Acute Toxicity Category 4 (Inhalation) Skin Irritation Category 2 Eye Irritation Category 2A Skin Sensitization Category 1 Respiratory Sensitization Category 1
Hazard statements
H225: Highly flammable liquid and vapour H312: Harmful in contact with skin H332: Harmful if inhaled H315: Causes skin irritation H319: Causes serious eye irritation H317: May cause an allergic skin reaction H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled
Prevention
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233: Keep container tightly closed. P240: Ground and bond container and receiving equipment. P241: Use explosion proof equipment. P242: Use non-sparking tools. P243: Take action to prevent static discharges. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P264: Wash thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection. P284: [In case of inadequate ventilation] wear respiratory protection.
Response
P303+P361+P353 IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P312: Call a POISON CENTER/doctor if you feel unwell. P342+P311 If experiencing respiratory symptoms Call a POISON CENTER/doctor P321: Specific Treatment (See Section 4 of this SDS). P333+P313 If skin irritation or rash occurs Get medical advice/attention P362+P364: Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists Get medical advice/attention
Storage
P403+P233: Store in a well-ventilated place. Keep container tightly closed. P235: Keep cool.
Disposal
P501: Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3 HEALTH HAZARDS OR RISKS FROM EXPOSURE: SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of overexposure for this product are by contact with skin or eyes, inhalation and ingestion. The symptoms of overexposure are described below. ACUTE: INHALATION: Inhalation may cause respiratory irritation. Contains materials that have the potential to cause headaches, nausea, and dizziness. CONTACT WITH SKIN: Irritant. May be harmful if absorbed through the skin. May cause allergic reaction. EYE CONTACT: Contains materials which may cause eye irritation. During application/use of this product, contact lenses should NOT be worn. INGESTION: Under normal conditions of intended use, this material is not expected to be an ingestion hazard. Ingestion may cause gastrointestinal irritation, nausea and vomiting. CHRONIC: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling this product may be harmful or fatal. TARGET ORGANS Acute Skin, Respiratory System and Eyes Chronic Skin, Respiratory System
2.1 Classification of the substance or mixture
This product does meet the definition of a hazardous substance or preparation as defined by the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC, 2015/830/EU and subsequent Directives. EU HAZARD CLASSIFICATION OF INGREDIENTS: Index Number: EC# 500-060-2 not listed in Annex VI EC# 215-535-7 Annex VI Index# 601-022-00-9 EC# 202-849-4 Annex VI Index# 601-023-00-4 EC# 212-485-8 Annex VI Index# 615-011-00-1 Substances not listed either individually or in group entries must be self classified. Component(s) Contributing to Classification(s) All components listed in Section 3