MMA Retarder

Hazard statements (CLP)

H225, H315, H317, H335, H401, H411

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

1999/45/EC EMERGENCY OVERVIEW: This product is a clear liquid with an ester-like odor.

Health hazards

Exposure may cause irritation to eyes, respiratory system and skin with possible sensitization. May be harmful if swallowed. Flammability Hazards: This product is a Flammable liquid with a flash point of 50°F (10°C) Reactivity Hazards: The product is normally supplied in a stabilized form. If the permissible storage period and/or storage temperature is exceeded, the product may polymerize with heat evolution.

Environmental hazards

This product is expected to be harmful to aquatic life with long-lasting effects US DOT SYMBOLS

Signal word

Danger! GHS LABELING AND CLASSIFICATION

Classification according to GHS

Flammable Liquid Category 2 Skin Irritant Category 2 Skin Sensitizer Category 1B STOT SE Category 3 Aquatic Acute Category 2 Aquatic Chronic Category 2

Hazard statements

H225: Highly flammable liquid and vapour H315: Causes skin irritation H317: May cause allergic skin reaction H335: May cause respiratory irritation H401: Toxic to aquatic life. H411: Toxic to aquatic life with long lasting effects.

Prevention

P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233: Keep container tightly closed. P240: Ground/Bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P272: Contaminated work clothing should not be allowed out of the workplace. P264: Wash thoroughly after handling. P271: Use only in a well-ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing/eye protection/face protection

Response

P302+P352 IF ON SKIN Wash with plenty of water P332+P313 If skin irritation occurs Get medical advice/attention P362+P364: Take off contaminated clothing and wash it before. P303+P361+P353 IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water/shower. P370+P378 In case of fire Use dry sand, dry chemical or alcohol-resistant foam for extinction P333+P313 If skin irritation or rash occurs Get medical advice/attention P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P391: Collect spillage.

Storage

P403+P233+P235: Store in a well-ventilated place. Keep container tightly closed. Keep cool. P405: Store locked up.

Disposal

P501: Dispose of contents/container in accordance with local/regional/national/international regulations 2.3 HEALTH HAZARDS OR RISKS FROM EXPOSURE: SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of overexposure for this product are by contact with skin or eyes, inhalation and ingestion. The symptoms of overexposure are described below. ACUTE: INHALATION: Inhalation of vapors or mists may cause respiratory irritation. CONTACT WITH SKIN: Contact may cause irritation with possible sensitization. EYE CONTACT: Liquids, vapors, or mists are irritating to the eyes and can cause stinging or tearing. INGESTION: Ingestion may cause irritation of the gastrointestinal tract and gastrointestinal discomfort with any or any of the following symptoms: nausea, vomiting or diarrhea. CHRONIC: No data available. TARGET ORGANS Acute Skin, Respiratory System and Eyes Chronic No data available

2.1 Classification of the substance or mixture

CLASSIFICATION OF SUBSTANCE OR MIXTURE IN ACCORDANCE WITH 29 CFR 1200 (OSHA HCS) AND THE EUROPEAN UNION DIRECTIVES: This product does meet the definition of a hazardous substance or preparation as defined by 29 CFR 1910. 1200 AND the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives. EU HAZARD CLASSIFICATION OF INGREDIENTS: Index Number: EC# 201-297-1 Annex VI Index# 607-035-00-6 EC 204-881-4 is not listed in Annex VI Substances not listed either individually or in group entries must be self classified. Component(s) Contributing to Classification(s): Methyl methacrylate, 2,6-di-tert-butyl-p-cresol