Eco-TCU Part A

Hazard statements (CLP)

H226, H317, H319, H340, H350, H372

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

1999/45/EC EMERGENCY OVERVIEW: This product is a clear to light yellow liquid.

Health hazards

Exposure may cause irritation to eyes and skin sensitization. Contains chemicals suspected as a carcinogen and germ cell mutagen hazard. May cause organ damage through prolonged exposure. Flammability Hazards: This product is a flammable liquid with a flash point of 125°F (52°C). Reactivity Hazards: None known

Environmental hazards

The Environmental effects of this product have not been investigated. Release of this product is not expected to have significant adverse effects in the aquatic environment. US DOT SYMBOLS

Signal word

Danger! EU LABELING AND CLASSIFICATION This product does meet the definition of a hazardous substance or preparation as defined by the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives EU HAZARD CLASSIFICATION OF INGREDIENTS PER DIRECTIVE 1272/2008/EC Index Number EC# 412-060-9 Annex VI Index# 607-350-00-9 EC# 232-489-3 Annex VI Index# 649-345-00-4 Remaining components are not listed in Annex VI Substances not listed either individually or in group entries must be self classified Component(s) Contributing to Classification(s) All components listed in Section 3

Classification according to GHS

Flammable Liquid Category 3 Eye Irritant Category 2A Skin Sensitization Category 1 Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1B Specific Target Organ Toxicity – Repeated Exposure - Category 1

Hazard statements

H226: Flammable liquid and vapour H319: Causes serious eye irritation H317: May cause an allergic skin reaction H340: May cause genetic defects H350: May cause cancer H372: Causes damage to organs through prolonged or repeated exposure

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233: Keep container tightly closed. P240: Ground and bond container and receiving equipment. P241: Use explosion-proof equipment. P242: Use non-sparking tools. P243: Take action to prevent static discharges. P260: Do not breathe dust/fume/vapor/mist/spray. P264: Wash thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection

Response

Phrases P303+P361+P353 IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P370+P378 In case of fire Use media listed in Section 5 to extinguish P302+P352 IF ON SKIN Wash with plenty of water P321: Specific Treatment (See Section 4 of this SDS). P333+P313 If skin irritation or rash occurs Get medical advice/attention P362+P364: Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists Get medical advice/attention P308+P313 IF exposed or concerned Get medical advice/attention

Storage

Phrases P405: Store locked up. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

Phrases P501: Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3 HEALTH HAZARDS OR RISKS FROM EXPOSURE: SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of overexposure for this product are by contact with skin or eyes, inhalation and ingestion. The symptoms of overexposure are described below. ACUTE: INHALATION: Inhalation of vapors or mists in high concentrations may cause respiratory irritation. CONTACT WITH SKIN: Contact may cause irritation. EYE CONTACT: Liquids, vapors, or mists are irritating to the eyes and can cause stinging or tearing. INGESTION: Ingestion may cause irritation of the gastrointestinal tract and gastrointestinal discomfort with any or all of the following symptoms: nausea, vomiting or diarrhea. CHRONIC: Contains a chemical suspected to be a cancer hazard. TARGET ORGANS Acute Skin, Respiratory System and Eyes Chronic Organs

2.1 Classification of the substance or mixture

This product does meet the definition of a hazardous substance or preparation as defined by the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives. EU HAZARD CLASSIFICATION OF INGREDIENTS PER DIRECTIVE 1272/2008/EC: Index Number: EC# 412-060-9 Annex VI Index# 607-350-00-9 EC# 232-489-3 Annex VI Index# 649-345-00-4 Remaining components are not listed in Annex VI Substances not listed either individually or in group entries must be self classified. Component(s) Contributing to Classification(s) All components listed in Section 3