Eco-FLA Part A

Hazard statements (CLP)

H226, H315, H317, H319, H332, H334, H335, H372

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

1999/45/EC EMERGENCY OVERVIEW: This product is a white viscous liquid with a mild chemical odor.

Health hazards

Exposure may cause irritation to skin. May cause irritation to eyes upon contact. Inhalation of vapors or mist at high concentrations can cause respiratory irritation. May cause skin and / or respiratory sensitization. Prolonged or repeated exposure may cause organ damage. Flammability Hazards: This product is a Combustible liquid with a flash point of 125°F (51.6°C) Reactivity Hazards: None known

Environmental hazards

The Environmental effects of this product have not been investigated. Release of this product may have significant adverse effects in the aquatic environment. US DOT SYMBOLS

Signal word

Danger EU LABELING AND CLASSIFICATION This product does meet the definition of a hazardous substance or preparation as defined by the European Union Council

Classification according to GHS

Flammable Liquid Category 3 Acute Toxicity Category 4 (Inhalation) Skin Irritation Category 2 Eye Irritant Category 2A Respiratory Sensitization Category 1 Skin Sensitization Category 1 Specific Target Organ Toxicity 3 Single Exposure Category 3 (Respiratory Irritation) Specific Target Organ Toxicity 3 Repeated Exposure Category 1

Hazard statements

H226: Flammable liquid and vapour H332: Harmful if inhaled H315: Causes skin irritation H319: Causes serious eye irritation H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled H317: May cause an allergic skin reaction H335: May cause respiratory irritation H372: Causes damage to organs through prolonged or repeated exposure.

Prevention

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233: Keep container tightly closed. P240: Ground and bond container and receiving equipment. P241: Use explosion-proof equipment. P242: Use non-sparking tools. P243: Take action to prevent static discharges. P260: Do not breathe dust/fumes/gas/mist/vapours/spray. P264: Wash thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/ protective clothing / eye and face protection. P284: [In case of inadequate ventilation] wear respiratory protection.

Response

P370+P378 In case of fire Use media defined in Section 5 to extinguish P303+P361+P353 IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P312: Call a POISON CENTER/doctor if you feel unwell. P321: Specific treatment (See Section 4 on this SDS) P333+P313 If skin irritation or rash occurs Get medical attention P362+P364: Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists Get medical advice/attention P342+P311 If experiencing respiratory symptoms Call a POISON CENTER/doctor

Storage

P403+P235: Store in a well-ventilated place. Keep cool. P233: Keep container tightly closed. P405: Store locked up.

Disposal

P501: Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3 HEALTH HAZARDS OR RISKS FROM EXPOSURE: SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of overexposure for this product are by contact with skin or eyes, inhalation and ingestion. The symptoms of overexposure are described below. ACUTE: INHALATION: TDI vapors or mist at concentrations above the TLV can irritate (burning sensation) the mucous membranes in the respiratory tract (nose, throat, lungs) causing runny nose, sore throat, coughing, chest discomfort, shortness of breath and reduced lung function (breathing obstruction). High vapor concentrations may cause central nervous system (CNS) depression as evidenced by giddiness, headache, dizziness, and nausea. CONTACT WITH SKIN: Isocyanates react with skin protein and moisture and can cause irritation. Prolonged contact can cause reddening, swelling, rash, scaling, blistering, and, in some cases, skin sensitization. EYE CONTACT: Liquid, aerosols or vapors are severely irritating and can cause pain, tearing, reddening and swelling. INGESTION: Can result in irritating and corrosive action in the mouth, stomach tissue and digestive tract. Symptoms can include sore throat, abdominal pain, nausea, vomiting and diarrhea. CHRONIC: Repeated exposure above current occupational limits may cause an allergic sensitization of the respiratory tract. This is characterized by an asthma-like response upon re-exposure to the chemical. The symptoms may include coughing, wheezing, shortness of breath and chest tightness, and may be fatal. Central nervous system (CNS) impairment leading to unconsciousness. TARGET ORGANS Acute Skin, Respiratory System and Eyes Chronic Skin, Respiratory System

2.1 Classification of the substance or mixture

This product does meet the definition of a hazardous substance or preparation as defined by the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC, 2015/830/EU and subsequent Directives. EU HAZARD CLASSIFICATION OF INGREDIENTS: Index Number: EC# 500-125-5 This substance is not classified in the Annex VI EC# 236-675-5 This substance is not classified in the Annex VI EC# 203-572-1 Annex VI Index# 607-194-00-1 EC# 223-861-6 Annex VI Index# 615-008-00-5 EC# 215-609-9 This substance is not classified in the Annex VI Substances not listed either individually or in group entries must be self classified. Component(s) Contributing to Classification(s) All Components in Section 3