substance or mixture

SECTION 2: Hazards identification

1272/2008 IMPORTANT - This section covers the hazardous materials from which this product is manufactured. This data has been classified according to the criteria of the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) as required and defined in OSHA Hazard Communication Standard (29 CFR Part 1910.1200). The fumes and gases produced during welding with normal use of this product are addressed in Section 8. HAZARDOUS CAS EINECS¹ REGULATORY HAZARD E Z IARC H NTP OSHA 65Φ INGREDIENT CLASSIFICATION/DESIGNATION

67/548/EEC

Copper 7440-50-8 231-159-6 None - Iron 7439-89-6 231-096-4 None - Manganese 7439-96-5 231-105-1 Xn-R20/22y - Silicon 7440-21-3 231-130-8 None - (Amorphous Silica 69012-64- 273-761-5 None 3 K - X Fume) 2 ¹ European INventory of Existing Chemical Substances Number Δ –European Union Directive 67/548/EEC-Annex 1 E – International Agency for Research on Cancer (1-Human Carcinogen, 2A-Probably Carcinogenic to Humans, 2B-Possibly Carcinogenic to Humans, 3 – Unclassifiable as to Carcinogenicity in Humans, 4 -Probably Not Carcinogenic to Humans) Z-US National Toxicology Program (K-Known Carcinogen, S-Suspected Carcinogen) H-OSHA Known Carcinogen List ө-California Proposition 65 (X –On Proposition 65 list) ---Dashes indicate the ingredient is not listed with the IARC, NTP, OSHA or 65 Ф- Carcinogen, Mutagen or Reproductive Category per European Council Directive 67/548/EEC Annex 1 Y- Manganese Dioxide EU 67/548/EEC Classification/Designation X –Molybdenum Trioxide EU 67/548/EEC Classification/Designation The following symbols correspond with the EU 67/548/EEC column above are in European Union Directive 67/548/EEC Annex 1 and EC 1272/2008 Annex VI – Table 3.2: Xn – Harmful Xi – Irritant WARNING! -Avoid breathing welding fumes and gases; they may be dangerous to your health. Always use adequate ventilation. Always use appropriate personal protective equipment

Principle Routes of Exposure

Respiratory System, Eyes and/or skin ELECTRIC SHOCK: Arc welding and associated processes can kill. See Section 8. ARC RAYS: The welding arc can injure eyes and burn skin FUMES AND GASES: Can be dangerous to your health. Welding fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being welded, the process, procedures and electrodes used. Most fume ingredients are present as complex oxides and compounds and not as pure metals. When the electrode is consumed, the fume and gas decomposition products generated are different and form from the ingredients listed in Section 3. Decomposition products of normal operation include those originating from the volatilization, reaction or oxidation of the materials shown in this section, plus those from the base metal and coating, etc., as noted above. Monitor for the materials identified in the list within this section. Fumes from the use of this product may contain complex oxides or compounds of the following elements and molecules: amorphous silica fume, copper and manganese. Other reasonably expected constituents of the fume would also include complex oxides of iron and molybdenum. Gaseous reaction products may include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc. Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal being welded (such as paint, plating or galvanizing), the number of welders and the volume of the work area, the quality and amount of ventilation, the position of the welder’s head with respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning an degreasing activities). One recommended way to determine the composition and quality of fumes and gases to which workers are exposed is to take an air sample inside the welder’s helmet if worn or in the worker’s breathing zone. See ANSI/AWS F1.1, available from the “American Welding Society”, P.O. Box 351040, Miami, FL 33135. Also, from AWS is F1.3 “Evaluating Contaminants in the Welding Environment-A Sampling Strategy Guide”, which gives additional advice on sampling