(H) on according

Hazard statements (CLP)

H272, H302, H315, H317, H319, H334, H335

Code

Statements

H272

May intensify fire; oxidiser

SECTION 2: Hazards identification

protective NO equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent DNEL 18.2 is based mg/kg on bw/day the calculation methods Not available set United out in Kingdom Annex I of the CLP Regulation, unless otherwise indicated in sections Local Explosive 11 and effect 12. properties DNEL 0.102 mg/cm2 Tel. Product +44 does (0) not 2476 12.4. any SECTION 3. Composition/information IATA: LEGEND: Mobility present contamination 374999 an explosion hazard in soil of skin, NO eyes and personal clothing. These indications apply for both processing staff and those involved in emergency Oxidising The data for procedures. LC50 - ADR: (Inhalation) European Agreement properties evaluation of chemical-physical properties Fax on ingredients of the mixture: concerning the carriage of Dangerous Not are available reported +44 (0) in 247 Not classified goods by (no Road section 6374004 9. significant component) e-mail General address population of the competent via inhalation person route: 3.2. 14.6. LD50 Information - CAS Mixtures Special (Oral) NUMBER

Precautionary statements

not of the available Chemical mixture: for Abstract user Service Number 929,29 mg/kg 9.2. responsible 6.2. LD50 Sistemic - CE50: Safety mixture: (required to induce a 50% effect) 1.03 Data mg/m3 Sheet sales@technicuk.co.uk Not classified (no significant component) Local effect DNEL 1.03 mg/m3 P220 Keep away from clothing and other combustible materials. P260 Do not breathe dust / fume / gas / mist / vapours / spray. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/ protective clothing / eye protection / face protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P304+P340 IF INHALED: remove person to fresh air and keep comfortable for breathing.

Further information

Environmental (Dermal) Effective of concentration effects for the DNEL the

Contains

ADR - CE NUMBER: / RID: Identifier in ESIS HIN (European - Kemler: 50 archive of existing substances) Limited Quantities: 5 kg Tunnel restriction code: (E) 1.4. Emergency telephone number 12.5. The - CLP: Results product EC Regulation of must PBT not and penetrate SODIUM PERSULFATE Identification x = Conc. %

vPvB Substances

Special assessment into the Provision: sewer system - or come into contact with surface water or ground water. General Information Identification IMDG: - DNEL: SODIUM populations Derived No PERSULFATE not available Effect x Level - Hazard via dermal route: = EMS: Conc. F-A, % S-Q quantity: in percentage 100 Kg greater than Packaging 0,1%. instructions: 563 Local effect DNEL 0.051 mg/cm2 SODIUM - GHS: Globally LD50 PERSULFATE (Dermal) Harmonized System Pass.: of classification and labeling hospital showing the SDS > 10000 Maximum of chemicals mg/kg quantity: Rabbit 25 Kg SECTION 10. Stability and reactivity Packaging instructions: 559 12.6. CAS Collect - IATA Other DGR: the LC50 adverse leaked International (Inhalation) 7775-27-1 product effects Air and Transport Special 75 place ≤ x Instructions: < it Association in 100 containers Dangerous Ox. for Sol. recovery 2 > H272, Goods 5 - mg/l/4h or disposal. Acute Regulation Rat Tox. If there 4 H302, are no Eye contraindications, Irrit. 2 H319, Skin use Irrit. jets 2 of H315, water to eliminate General populations - Hazard via oral route: product - IC50: Reactivity Immobilization residues. Concentration 50% 10.1. SECTION Sistemic effects DNEL 9.1 mg/kg bw/day STOT SE 3 H335, Resp. Sens. 1 H334, Skin Sens. 1 H317 identification 14.7. EC Make SKIN Information - IMDG: Transport CORROSION sure International the not in leakage available 231-892-1 bulk / IRRITATION Maritime according site is well Code to aired. Annex for dangerous Evaluate II of Marpol the goods compatibility and the IBC of the Code container to be used, by checking section 10. Contaminated material 2.1. INDEX should There - IMO: Classification are International be disposed no particular of the Maritime of in risks substance compliance of Organization reaction or with mixture with the other provisions substances set forth in normal in point conditions 13 of use Reg Causes Information INDEX no. skin NUMBER not irritation relevant 01-2119495975-15 Identifier in Annex VI of CLP 10.2. The Disposal considerations LC50 Reference Chemical product Lethal is to stability Concentration classified other sections as hazardous 50%

2.1 Classification of the substance or mixture

International be disposed no particular of the Maritime of in risks substance compliance of Organization reaction or with mixture with the other provisions substances set forth in normal in point conditions 13. of use. Reg. Causes Information - INDEX no. skin NUMBER: not irritation relevant 01-2119495975-15 Identifier in Annex VI of CLP 6.4. 10.2. The SECTION 13. Disposal considerations - LC50: Reference Chemical product Lethal is to stability Concentration classified other sections as hazardous 50% pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent amendments 8.2. and Exposure controls The SERIOUS - LD50: supplements). full Lethal wording EYE dose DAMAGE of hazard The 50% product / (H) IRRITATION phrases thus requires is given a in safety section datasheet 16 of the that sheet. complies with the provisions of (EU) Regulation 2015/830. 13.1. Waste treatment methods SECTION Any additional 15. Regulatory information The - OEL: information product Occupational is information stable on personal Exposure in normal concerning protection Level conditions the and risks of disposal use for and health is storage. given and/or in sections the environment 8 and 13. are given in sections 11 and 12 of this sheet. As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is Causes - PBT: Persistent serious eye bioaccumulative irritation and toxic as REACH Regulation SECTION Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product well aired through 4. First effective local measures aspiration. Hazard SODIUM - PEC: Predicted classification PERSULFATE environmental and aid indication: Concentration 15.1. should SECTION When Safety, choosing be evaluated health and according 7. personal environmental protective to applicable storage ask your chemical substance regulations/legislation regulations. specific for the substance or mixture advice. 4.1. Disposal RESPIRATORY - PEL: Description Oxidising Avoid Predicted must of be first exposure solid, Handling OR exposure performed category to: SKIN combustible aid measures SENSITISATION level 2 and equipment, through an authorised waste management firm, in compliance with national and local regulations. substances,reducing substances. H272 supplier for May intensify fire; oxidiser. Personal - PNEC: Acute protective Decomposes Predicted toxicity, before category no effect equipment melting. 4 concentration must be CE marked, showing that it complies Observable thermal decomposition at temperatures H302 with applicable >60°C. Harmful standards. SADT: if swallowed. abt. 180°C (UN Test-H4). Even minor 7.1. Waste Seveso Provide Precautions transportation Category an emergency for - safe Directive may handling shower be 2012/18/EC: subject to ADR restrictions. with face and eye wash station. P8 Sensitising - REACH: EYES: CONTAMINATED Eye decontamination Irrigate copiously irritation, EC for Regulation the category PACKAGING skin or humidity with clean, fresh water for at least 15 minutes. Seek medical advice. 1907/2006 2 may lead to perceptible lowering of the SADT. H319 Causes serious eye irritation. HAND Sensitising - RID: Skin PROTECTION Regulation irritation, for the category concerning respiratory 2 system the international transport of dangerous goods H315 by train Causes skin irritation. SKIN: Ensure Contaminated Restrictions In the case Wash that there of prolonged relating immediately packaging is an to the adequate contact must product with be plenty earthing recovered or contained of system water or disposed substances and for the soap. equipment of in pursuant Remove compliance and to contaminated personnel. Annex penetration-resistant with national XVII Avoid to EC waste clothing. contact Regulation management If with irritation gloves (see 1907/2006 eyes persists, regulations. and skin. seek standard EN 374). Do not medical breathe attention. Wash 10.3. - TLV: contaminated powders, None Possibility Specific Threshold vapours target clothing of Limit hazardous organ Value or mists. before Do using toxicity reactions not eat, - with single them drink the exposure, again. product, protect the hands with H335 or smoke during use. Wash hands after use. Avoid leakage of the product into the environment. May cause work respiratory irritation. Work glove material must be chosen according to the use process and the products that may form. Latex gloves may cause sensitivity GERM - TLV category CEILING: CELL 3 MUTAGENICITY Concentration that should not be exceeded during any time of occupational exposure. INHALATION: reactions. Move the person to open air. If breathing is irregular, seek medical advice. 7.2. INGESTION: SECTION The - TWA Substances Conditions Respiratory powders STEL: 14. in for are Short-term Obtain Candidate sensitization, Transport potentially safe immediate storage, exposure List (Art. including explosive category information medical limit when 59 REACH) 1 attention. any incompatibilities mixed with air. Rinse the mouth with plenty of water. Immediately drink large amounts of water. Do not H334 May cause allergy or asthma symptoms or breathing SKIN PROTECTION Does - TWA: not Time-weighted induce On the vomiting. basis of available meet the classification Never give data, difficulties if inhaled. average exposure anything the product criteria for limit by mouth this hazard class does to not an unconscious contain any SVHC person. in percentage greater than 0,1%. 14.1. Wear UN SODIUM - VOC: Volatile Skin category number sensitization, PERSULFATE organic category long-sleeved II professional Compounds 1A overalls and safety footwear H317 (see Regulation May 2016/425 cause an and allergic standard skin EN reaction. ISO 20344). Wash body Store only in the original container. Store in a ventilated and dry place, far away from sources of ignition. Keep containers well sealed. Keep with soap and water after removing protective clothing. 4.2. the CARCINOGENICITY - vPvB: Substances Most The substance product important Very Persistent in subject clearly symptoms is a strong to labelled authorisation and very oxidant containers. and effects, Bioaccumulative (Annex Avoid and reacts with both XIV overheating. REACH) acute and delayed as for combustible REACH Regulation Avoid violent blows. Keep containers away from any incompatible materials, see and reducing materials. The substance decomposes on heating producing 2.2. EYE ADR - WGK: Label PROTECTION toxic Water / RID, elements and corrosive IMDG, IATA: hazard classes fumes including 1505 (German). sulphur oxides. React violently with powdered metals and strong bases. The solution in water is a section None Wear airtight protective goggles (see standard EN 166). 10 for details. Does weak not acid. meet Not the combustible classification but criteria enhances for this combustion hazard class of other substances. Risk of explosion with reducing agents. 14.2. Hazard Information not available In the UN presence proper labelling shipping

PBT Substances

mg/kg or Rat

Environmental hazards

and 13. are given in sections 11 and 12 of this sheet As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is Causes PBT: Persistent serious eye bioaccumulative irritation and toxic as REACH Regulation SECTION Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product well aired through First effective local measures aspiration Hazard SODIUM PEC: Predicted classification PERSULFATE environmental and aid indication Concentration should SECTION When Safety, choosing be evaluated health and according personal environmental protective to applicable storage ask your chemical substance regulations/legislation regulations specific for the substance or mixture advice Disposal RESPIRATORY PEL Description Oxidising Avoid Predicted must of be first exposure solid, Handling OR exposure performed category to: SKIN combustible aid measures SENSITISATION level and equipment, through an authorised waste management firm, in compliance with national and local regulations substances,reducing substances H272 supplier for May intensify fire; oxidiser Personal PNEC Acute protective Decomposes Predicted toxicity, before category no effect equipment melting concentration must be CE marked, showing that it complies Observable thermal decomposition at temperatures H302 with applicable 60°C Harmful standards SADT if swallowed abt. 180°C (UN Test-H4). Even minor Waste Seveso Provide Precautions transportation Category an emergency for - safe Directive may handling shower be 2012/18/EC subject to ADR restrictions with face and eye wash station P8 Sensitising REACH EYES CONTAMINATED Eye decontamination Irrigate copiously irritation, EC for Regulation the category PACKAGING skin or humidity with clean, fresh water for at least 15 minutes. Seek medical advice

Hazard pictograms

PROTECTION SODIUM PERSULPHATE Information not available Use IMDG: a type P filtering facemask, SODIUM PERSULPHATE whose class (1, 2 or 3) and effective need, must be defined according to the outcome of risk assessment Avoid Does 2. Regulation Follow Substances not environmental doctor's meet (EC) subject orders.

EU Classification

2015/1221 (VII products criteria Atp. for CLP) this of hazard the European class Parliament EXTINGUISHING 11. Regulation (EU) MEDIA 2016/918 NOT (VIII SUITABLE Atp. CLP) of the European Parliament 9.1. SODIUM Do not use ASPIRATION 12. Information Regulation 2018/669 (XI criteria from the if substance Atp. CLP) swallowed. or mixture for this hazard Value class Information A chemical safety assessment has not been performed for the preparation/for the substances indicated in section 3. H319 Causes serious eye irritation. Appearance powder ... / >> H315 Causes skin irritation. H335 May cause respiratory irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction.

Hazard statements

PERSULFATE carbon dioxide extinguishers, foam, water with full jets. on (EU) basic 2016/1179 physical (IX and Atp. chemical CLP) properties 15.2. Chemical safety assessment H272 May intensify fire; oxidiser. 13. Sulphur Regulation oxides, (EU) toxic 2017/776 pyrolysis (X Atp. products. CLP) 5.2. Special Properties Does 14. Regulation H302 hazards arising Harmful not meet the

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. 3.2. Mixtures