Thiourea

Hazard statements (CLP)

H301, H317, H320, H335, H351, H361, H372, H411

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

GHS Classification Emergency Overview Appearance : Solid form Color : white Toxic if swallowed. May cause an allergic skin reaction. Causes eye irritation. May cause respiratory irrita- tion. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Causes damage to organs (Thyroid) through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. GHS Classification Acute toxicity (Oral) Category 3 Serious eye damage/eye irritation Category 2B Skin sensitization Category 1 Carcinogenicity Category 2 Reproductive toxicity Category 2 Specific target organ toxicity - Category 3 (respiratory tract irritation) single exposure Specific target organ toxicity - Category 1 (Thyroid) repeated exposure Short-term (acute) aquatic hazard Category 2 Long-term (chronic) aquatic haz- ard Category 2

Signal word

Danger

Hazard statements

H301 Toxic if swallowed. H317 May cause an allergic skin reaction. H320 Causes eye irritation. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H361 Suspected of damaging fertility or the unborn child. H372 Causes damage to organs (Thyroid) through prolonged or re- peated exposure. H411 Toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/ atten- tion. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Not classified based on available information.

Health hazards

Toxic if swallowed. Causes eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause respiratory irritation. Causes damage to or- gans through prolonged or repeated exposure Environmental hazards Toxic to aquatic life. Toxic to aquatic life with long lasting effects

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Acute toxicity (Oral) : Category 3 Serious eye damage/eye irritation : Category 2B Skin sensitization : Category 1 Carcinogenicity : Category 2 Reproductive toxicity : Category 2 Specific target organ toxicity - : Category 3 (respiratory tract irritation) single exposure Specific target organ toxicity - : Category 1 (Thyroid) repeated exposure Short-term (acute) aquatic hazard : Category 2 Long-term (chronic) aquatic haz- : Category 2 ard