p-Toluidine

Hazard statements (CLP)

H301+H311+H331, H316, H317, H319, H335, H351, H370, H372, H410

Code

Statements

H301+H311+H331

Toxic if swallowed, in contact with skin or if inhaled

SECTION 2: Hazards identification

GHS Classification Emergency Overview Appearance : Solid form Color : white - yellow Toxic if swallowed, in contact with skin or if inhaled. Causes mild skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. Suspected of causing cancer. Caus- es damage to organs (Blood, Kidney, Central nervous system, Bladder). Causes damage to organs (Blood, Bladder) through prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects. GHS Classification Acute toxicity (Oral) Category 3 Acute toxicity (Inhalation) Category 3 Acute toxicity (Dermal) Category 3 Skin corrosion/irritation Category 3 Serious eye damage/eye irritation Category 2A Skin sensitization Category 1 Carcinogenicity Category 2 Specific target organ toxicity - Category 1 (Blood, Kidney, Central nervous system, Bladder) single exposure Specific target organ toxicity - Category 3 (respiratory tract irritation) single exposure Specific target organ toxicity - Category 1 (Blood, Bladder) repeated exposure Short-term (acute) aquatic hazard Category 1 Long-term (chronic) aquatic haz- ard Category 1

Signal word

Danger

Hazard statements

H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H316 Causes mild skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H370 Causes damage to organs (Blood, Kidney, Central nervous system, Bladder). H372 Causes damage to organs (Blood, Bladder) through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311 IF exposed or concerned: Call a POISON CENTER/ doctor. P333 + P313 If skin irritation or rash occurs: Get medical advice/ atten- tion. P337 + P313 If eye irritation persists: Get medical advice/ attention. P361 + P364 Take off immediately all contaminated clothing and wash it before reuse. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Not classified based on available information.

Health hazards

Toxic if swallowed. Toxic if inhaled Toxic in contact with skin. Causes mild skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. Causes damage to organs. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure. 2 / 10

Environmental hazards

Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Acute toxicity (Oral) : Category 3 Acute toxicity (Inhalation) : Category 3 Acute toxicity (Dermal) : Category 3 Skin corrosion/irritation : Category 3 Serious eye damage/eye irritation : Category 2A Skin sensitization : Category 1 Carcinogenicity : Category 2 Specific target organ toxicity - : Category 1 (Blood, Kidney, Central nervous system, Bladder) single exposure Specific target organ toxicity - : Category 3 (respiratory tract irritation) single exposure Specific target organ toxicity - : Category 1 (Blood, Bladder) repeated exposure Short-term (acute) aquatic hazard : Category 1 Long-term (chronic) aquatic haz- : Category 1 ard