o-Toluidine

Hazard statements (CLP)

H227, H301+H331, H313, H316, H319, H350, H370, H372, H400, H411

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

Emergency Overview Appearance : liquid Color : colorless - yellow Combustible liquid. Toxic if swallowed or if inhaled. May be harmful in contact with skin. Causes mild skin irritation. Causes serious eye irritation. May cause cancer. Causes damage to organs (Blood, Kidney, Blad- der). Causes damage to organs (Blood) through prolonged or repeated exposure. Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. GHS Classification Flammable liquids Category 4 Acute toxicity (Oral) Category 3 Acute toxicity (Inhalation) Category 3 Acute toxicity (Dermal) Category 5 Skin corrosion/irritation Category 3 Serious eye damage/eye irritation Category 2A Carcinogenicity Category 1A Specific target organ toxicity - Category 1 (Blood, Kidney, Bladder) single exposure Specific target organ toxicity - Category 1 (Blood) repeated exposure Short-term (acute) aquatic hazard Category 1 Long-term (chronic) aquatic haz- ard Category 2

Signal word

Danger

Hazard statements

H227 Combustible liquid. H301 + H331 Toxic if swallowed or if inhaled. H313 May be harmful in contact with skin. H316 Causes mild skin irritation. H319 Causes serious eye irritation. H350 May cause cancer. H370 Causes damage to organs (Blood, Kidney, Bladder). H372 Causes damage to organs (Blood) through prolonged or repeat- ed exposure. H400 Very toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311 IF exposed or concerned: Call a POISON CENTER/ doctor. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol- resistant foam to extinguish. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Combustible liquid

Health hazards

Toxic if swallowed. Toxic if inhaled. May be harmful in contact with skin. Causes mild skin irritation. Causes serious eye irritation. May cause cancer. Causes damage to organs. Causes damage to organs through pro- longed or repeated exposure

Environmental hazards

Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. 2 / 9

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Flammable liquids : Category 4 Acute toxicity (Oral) : Category 3 Acute toxicity (Inhalation) : Category 3 Acute toxicity (Dermal) : Category 5 Skin corrosion/irritation : Category 3 Serious eye damage/eye irritation : Category 2A Carcinogenicity : Category 1A Specific target organ toxicity - : Category 1 (Blood, Kidney, Bladder) single exposure Specific target organ toxicity - : Category 1 (Blood) repeated exposure Short-term (acute) aquatic hazard : Category 1 Long-term (chronic) aquatic haz- : Category 2 ard