Dess-Martin Periodinane (8-12% in Dichloromethane)

Hazard statements (CLP)

H225, H272, H302, H315, H319, H336, H341, H350, H370, H372, H373, H411

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification Emergency Overview Appearance : liquid Color : colorless - yellow Highly flammable liquid and vapor. May intensify fire; oxidizer. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of causing genetic defects. May cause cancer. Causes damage to organs (Respiratory system, Central nervous system). Causes dam- age to organs (Liver, Central nervous system) through prolonged or repeated exposure. May cause damage to organs (Blood) through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. GHS Classification Flammable liquids Category 2 Oxidizing liquids Category 3 Acute toxicity (Oral) Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Germ cell mutagenicity Category 2 Carcinogenicity Category 1B Specific target organ toxicity - Category 1 (Respiratory system, Central nervous system) single exposure Specific target organ toxicity - Category 3 (Narcotic effects) single exposure Specific target organ toxicity - Category 1 (Liver, Central nervous system) repeated exposure Specific target organ toxicity - Category 2 (Blood) repeated exposure Short-term (acute) aquatic hazard Category 2 Long-term (chronic) aquatic haz- Category 2 ard

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapor. H272 May intensify fire; oxidizer. H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H341 Suspected of causing genetic defects. H350 May cause cancer. H370 Causes damage to organs (Respiratory system, Central nervous system). H372 Causes damage to organs (Liver, Central nervous system) through prolonged or repeated exposure. H373 May cause damage to organs (Blood) through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P220 Keep/Store away from clothing/ combustible materials. P221 Take any precaution to avoid mixing with combustibles. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311 IF exposed or concerned: Call a POISON CENTER/ doctor. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol- resistant foam to extinguish. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly 2 / 10 closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Highly flammable liquid and vapor May intensify fire; oxidizer.

Health hazards

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Suspected of causing genetic de- fects. May cause cancer. Causes damage to organs. May cause drowsiness or dizziness. Causes damage to organs through prolonged or repeated exposure. May cause damage to organs through prolonged or re- peated exposure.

Environmental hazards

Toxic to aquatic life. Toxic to aquatic life with long lasting effects

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Flammable liquids : Category 2 Oxidizing liquids : Category 3 Acute toxicity (Oral) : Category 4 Skin corrosion/irritation : Category 2 Serious eye damage/eye irritation : Category 2A Germ cell mutagenicity : Category 2 Carcinogenicity : Category 1B Specific target organ toxicity - : Category 1 (Respiratory system, Central nervous system) single exposure Specific target organ toxicity - : Category 3 (Narcotic effects) single exposure Specific target organ toxicity - : Category 1 (Liver, Central nervous system) repeated exposure Specific target organ toxicity - : Category 2 (Blood) repeated exposure Short-term (acute) aquatic hazard : Category 2 Long-term (chronic) aquatic haz- : Category 2 ard