(-)-B-Chlorodiisopinocampheylborane (55-65% in Heptane, ca. 1.7mol/L)

Hazard statements (CLP)

H225, H304, H314, H335, H336, H373, H410

Code

Statements

H225

Highly flammable liquid and vapour

H304

May be fatal if swallowed and enters airways

H314

Causes severe skin burns and eye damage.

H335

May cause respiratory irritation

H336

May cause drowsiness or dizziness

H373

May cause damage to organs through prolonged or repeated exposure

H410

Very toxic to aquatic life with long lasting effects

SECTION 2: Hazards identification

Emergency Overview Appearance : liquid Color : colorless Highly flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes severe skin burns and eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. May cause damage to organs (Liver) through prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects. GHS Classification Flammable liquids Category 2 Skin corrosion/irritation Category 1B Serious eye damage/eye irritation Category 1 Specific target organ toxicity - Category 3 (respiratory tract irritation, Narcotic effects) single exposure Specific target organ toxicity - Category 2 (Liver) repeated exposure

Aspiration hazard

Category 1 Short-term (acute) aquatic hazard Category 1 Long-term (chronic) aquatic haz- ard Category 1

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H373 May cause damage to organs (Liver) through prolonged or re- peated exposure. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P314 Get medical advice/ attention if you feel unwell. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol- resistant foam to extinguish. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Highly flammable liquid and vapor

Health hazards

Causes severe skin burns and eye damage. Causes serious eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated expo- sure. May be fatal if swallowed and enters airways

Environmental hazards

Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Flammable liquids : Category 2 Skin corrosion/irritation : Category 1B Serious eye damage/eye irritation : Category 1 Specific target organ toxicity - : Category 3 (respiratory tract irritation, Narcotic effects) single exposure Specific target organ toxicity - : Category 2 (Liver) repeated exposure Aspiration hazard : Category 1 Short-term (acute) aquatic hazard : Category 1 Long-term (chronic) aquatic haz- : Category 1 ard