General Information
Version
1.2
Revision date
2025-04-12
Product name
2-Methyl-4-nitroaniline
CAS No.
99-52-5
Icons in SDS
Company Information
company name
TCI (Shanghai) DEVELOPMENT CO., LTD
e-mail address of the competent person responsible for the Safety Data Sheet
Sales-CN@TCIchemicals.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H301+H311+H331, H315, H319, H341, H373, H411
Hazard statements
Code
Statements
H301+H311+H331
Toxic if swallowed, in contact with skin or if inhaled
Section 2
SECTION 2: Hazards identification
GHS Classification Emergency Overview Appearance : Solid form Color : yellow - green Toxic if swallowed, in contact with skin or if inhaled. Causes skin irritation. Causes serious eye irritation. Suspected of causing genetic defects. May cause damage to organs through prolonged or repeated expo- sure. Toxic to aquatic life with long lasting effects. GHS Classification Acute toxicity (Oral) Category 3 Acute toxicity (Inhalation) Category 3 Acute toxicity (Dermal) Category 3 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Germ cell mutagenicity Category 2 Specific target organ toxicity - Category 2 repeated exposure Short-term (acute) aquatic hazard Category 2 Long-term (chronic) aquatic haz- ard Category 2
Signal word
Danger
Hazard statements
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H341 Suspected of causing genetic defects. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects.
Prevention
P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response
P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P361 + P364 Take off immediately all contaminated clothing and wash it before reuse. P391 Collect spillage.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Disposal
P501 Dispose of contents/ container to an approved waste disposal plant.
Other physicochemical hazards
Not classified based on available information.
Health hazards
Toxic if swallowed. Toxic if inhaled. Toxic in contact with skin. Causes skin irritation. Causes serious eye irri- tation. Suspected of causing genetic defects. May cause damage to organs through prolonged or repeated exposure.
Environmental hazards
Toxic to aquatic life. Toxic to aquatic life with long lasting effects
Other hazards which do not result in classification
None known.
2.1 Classification of the substance or mixture
Acute toxicity (Oral) : Category 3 Acute toxicity (Inhalation) : Category 3 Acute toxicity (Dermal) : Category 3 Skin corrosion/irritation : Category 2 Serious eye damage/eye irritation : Category 2A Germ cell mutagenicity : Category 2 Specific target organ toxicity - : Category 2 repeated exposure Short-term (acute) aquatic hazard : Category 2 Long-term (chronic) aquatic haz- : Category 2 ard