1,4-Phenylenediamine

Hazard statements (CLP)

H301+H311+H331, H317, H319, H334, H370, H372, H373, H410

Code

Statements

H301+H311+H331

Toxic if swallowed, in contact with skin or if inhaled

SECTION 2: Hazards identification

GHS Classification Emergency Overview Appearance : Solid form Color : white - red Toxic if swallowed, in contact with skin or if inhaled. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Causes damage to or- gans (Heart, Kidney, muscle). Causes damage to organs (Liver, Nervous system, Kidney) through prolonged or repeated exposure. May cause damage to organs (Heart, muscle) through prolonged or repeated expo- sure. Very toxic to aquatic life with long lasting effects. GHS Classification Acute toxicity (Oral) Category 3 Acute toxicity (Inhalation) Category 3 Acute toxicity (Dermal) Category 3 Serious eye damage/eye irritation Category 2A Respiratory sensitization Category 1 Skin sensitization Category 1 Specific target organ toxicity - Category 1 (Heart, Kidney, muscle) single exposure Specific target organ toxicity - Category 1 (Liver, Nervous system, Kidney) repeated exposure Specific target organ toxicity - Category 2 (Heart, muscle) repeated exposure Short-term (acute) aquatic hazard Category 1 Long-term (chronic) aquatic haz- ard Category 1

Signal word

Danger

Hazard statements

H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if H370 Causes damage to organs (Heart, Kidney, muscle). H372 Causes damage to organs (Liver, Nervous system, Kidney) through prolonged or repeated exposure. H373 May cause damage to organs (Heart, muscle) through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 Wear respiratory protection.

Response

P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311 IF exposed or concerned: Call a POISON CENTER/ doctor. P333 + P313 If skin irritation or rash occurs: Get medical advice/ atten- tion. P337 + P313 If eye irritation persists: Get medical advice/ attention. P361 + P364 Take off immediately all contaminated clothing and wash it before reuse. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Not classified based on available information.

Health hazards

Toxic if swallowed. Toxic if inhaled. Toxic in contact with skin. Causes serious eye irritation. May cause al- lergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. May cause damage to organs through prolonged or repeated exposure. 2 / 9

Environmental hazards

Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Acute toxicity (Oral) : Category 3 Acute toxicity (Inhalation) : Category 3 Acute toxicity (Dermal) : Category 3 Serious eye damage/eye irritation : Category 2A Respiratory sensitization : Category 1 Skin sensitization : Category 1 Specific target organ toxicity - : Category 1 (Heart, Kidney, muscle) single exposure Specific target organ toxicity - : Category 1 (Liver, Nervous system, Kidney) repeated exposure Specific target organ toxicity - : Category 2 (Heart, muscle) repeated exposure Short-term (acute) aquatic hazard : Category 1 Long-term (chronic) aquatic haz- : Category 1 ard