Diethylzinc (ca. 15% in Hexane, ca. 1mol/L)

Hazard statements (CLP)

H225, H250, H260, H304, H314, H318, H335, H336, H361f, H372, H411

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour. H250 Catches fire spontaneously if exposed to air. H260 In contact with water releases flammable gases which may ignite spontaneously. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H361f Suspected of damaging fertility. H372 Causes damage to organs (Central nervous system, Periph- eral nervous system) through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects.

Supplemental label elements

EUH014 Reacts violently with water.

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P233 Keep container tightly closed. P260 Do not breathe mist or vapours. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P335 + P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P370 + P378 In case of fire: Use dry sand, dry chemical or alco- hol-resistant foam to extinguish. P391 Collect spillage.

Hazardous Ingredients

Hexane Diethylzinc

Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupt- ing properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commis- sion Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine dis- rupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Com- mission Regulation (EU) 2018/605 at levels of 0.1% or higher

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Pyrophoric liquids, Category 1 H250: Catches fire spontaneously if exposed to air. Substances and mixtures, which in contact H260: In contact with water releases flammable gases with water, emit flammable gases, Category 1 which may ignite spontaneously. Skin corrosion, Sub-category 1B H314: Causes severe skin burns and eye damage. Serious eye damage, Category 1 H318: Causes serious eye damage. Reproductive toxicity, Category 2 H361f: Suspected of damaging fertility. Specific target organ toxicity - single expo- H336: May cause drowsiness or dizziness. sure, Category 3, Central nervous system Specific target organ toxicity - single expo- H335: May cause respiratory irritation. sure, Category 3, Respiratory system Specific target organ toxicity - repeated expo- H372: Causes damage to organs through prolonged or sure, Category 1, Central nervous system, repeated exposure. Peripheral nervous system Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters airways. Long-term (chronic) aquatic hazard, Category H411: Toxic to aquatic life with long lasting effects. 2