Phenylhydrazine

Hazard statements (CLP)

H227, H301+H331, H310, H315, H317, H319, H341, H350, H370, H372, H400

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

in accordance with the Hazardous Products Regulations Flammable liquids Category 4 Acute toxicity (Oral) : Category 3 Acute toxicity (Inhalation) : Category 3 Acute toxicity (Dermal) Skin irritation Eye irritation : Category 2 : Category 2A Skin sensitisation Germ cell mutagenicity : Category 1 : Category 2 Carcinogenicity Category 1B Specific target organ toxicity - single exposure Category 1 (Blood) Specific target organ toxicity - repeated exposure Category 1 (Blood) Short-term (acute) aquatic hazard Category 1

Signal word

Danger

Hazard statements

H227 Combustible liquid. H301 + H331 Toxic if swallowed or if inhaled. H310 Fatal in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H341 Suspected of causing genetic defects. H350 May cause cancer. H370 Causes damage to organs (Blood). H372 Causes damage to organs (Blood) through prolonged or re- peated exposure. H400 Very toxic to aquatic life.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P302 + P352 + P310 IF ON SKIN: Wash with plenty of water. Imme- diately call a POISON CENTER/ doctor. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311 IF exposed or concerned: Call a POISON CENTER/ doctor. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P361 + P364 Take off immediately all contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol- resistant foam to extinguish. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards

None known