Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
General Information
Revision date
2019-04-08
Product name
Methylenediphenyl 4,4"-Diisocyanate
CAS No.
101-68-8
Emergency telephone
Chemical Emergencies
Icons in SDS
Company Information
company name
TCI AMERICA
e-mail address of the competent person responsible for the Safety Data Sheet
sales-US@TCIchemicals.com
GHS Information
Signal word
Danger!
Section 2
SECTION 2: Hazards identification
WHMIS 2015 OSHA Haz Com: CFR 1910.1200: Acute Toxicity - Inhalation [Category 2] WHMIS 2015: Skin Corrosion/Irritation [Category 2] Eye Damage/Irritation [Category 2A] Sensitization - Respiratory [Category 1] Sensitization - Skin [Category 1] Carcinogenicity [Category 2] Specific Target Organ Toxicity (Single Exposure) [Category 1] Specific Target Organ Toxicity (Repeated Exposure) [Category 1]
Signal word
Danger!
Hazard statements
Fatal if inhaled Causes skin irritation Causes serious eye irritation May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause an allergic skin reaction Suspected of causing cancer Causes damage to: Respiratory System Causes damage to organs through prolonged or repeated exposure: Respiratory System
Hazard pictograms
or Symbol(s)
Prevention
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust, fume, mist, vapors or spray. Use only outdoors or in a well-ventilated area. Do not eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out of the workplace. Wash hands and face thoroughly after handling. Wear respiratory protection. Wear protective gloves, protective clothing, face protection.
Response
If on skin Wash with plenty of soap and water. If skin irritation or rash occurs Get medical advice or attention. Wash contaminated clothing before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a poison center or doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists Get medical advice or attention. If exposed Call a poison center or doctor
Storage
Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal
Dispose of contents and container in accordance with local, regional, national regulations (e.g. US 40 CFR Part 261, EU 91/156/EEC, JP Waste Disposal and Cleaning Act, etc.).
2.3 Other hazards
May cause polymerization. Lachrymator [HNOC]
