Hexamethylene Diisocyanate

Hazard statements (CLP)

H302, H311, H314, H317, H330, H334, H335, H372

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H330 Fatal if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H372 Causes damage to organs (Respiratory system) through pro- longed or repeated exposure.

Prevention

P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 Wear respiratory protection.

Response

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT in- duce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with wa- ter for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doc- tor. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON P362 Take off contaminated clothing and wash before reuse.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards

None known

2.1 Classification of the substance or mixture

Acute toxicity (Oral) : Category 4 Acute toxicity (Inhalation) : Category 1 Acute toxicity (Dermal) : Category 3 Skin corrosion : Category 1B Serious eye damage : Category 1 Respiratory sensitization : Sub-category 1A Skin sensitization : Category 1 Specific target organ toxicity - single exposure : Category 3 (Respiratory system) Specific target organ toxicity - repeated exposure : Category 1 (Respiratory system)