1,3-Phenylenediamine Sulfate

SECTION 2: Hazards identification

OSHA OSHA Haz Com: CFR 1910.1200: Acute Toxicity - Oral [Category 3] Acute Toxicity - Dermal [Category 4] Skin Corrosion/Irritation [Category 2] Eye Damage/Irritation [Category 2A] Sensitization - Skin [Category 1] Germ Cell Mutagenicity [Category 2] Toxic to Reproduction [Category 2] Specific Target Organ Toxicity (Single Exposure) [Category 2] Specific Target Organ Toxicity (Repeated Exposure) [Category 1] Specific Target Organ Toxicity (Repeated Exposure) [Category 2] Aquatic Hazard (Acute) [Category 2] Aquatic Hazard (Long-Term) [Category 2]

Signal word

Danger!

Hazard statements

Causes serious eye irritation Causes skin irritation Harmful in contact with skin May cause an allergic skin reaction Suspected of causing genetic defects Suspected of damaging fertility or the unborn child Toxic if swallowed Toxic to aquatic life Toxic to aquatic life with long lasting effects May cause damage to organs: Respiratory System Central Nervous System Causes damage to organs: Liver Nervous System Kidney Urinary Bladder through prolonged or repeated exposure. May cause damage to organs: Blood (System) Respiratory System Cardiovascular System through prolonged or repeated exposure.

Hazard pictograms

or Symbol(s)

Prevention

Do not eat, drink or smoke when using this product. Wash hands and face thoroughly after handling. Wear protective gloves and protective clothing. Wear protective gloves. Wear eye and face protection. Avoid breathing dusts or mists. Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing, eye protection and face protection. Do not breathe dusts or mists. Wash all exposed skin thoroughly after handling.

Response

If swallowed Immediately call a poison center or doctor. Rinse mouth. If on skin Wash with plenty of water. Call a poison center or doctor if you feel unwell. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs Get medical advice/attention. If in eyes Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists Get medical advice or attention. If skin irritation occurs Get medical advice/attention. Wash contaminated clothing before reuse. If exposed: Call a poison center or doctor. If exposed or concerned: Call a poison center or doctor. Get medical advice or attention if you feel unwell.

Storage

Store locked up.

Disposal

Dispose of contents and container in accordance with US EPA guidelines for the classification and determination of hazardous waste listed in 40 CFR 261.3. (See Section 13)