1,2-Phenylenediamine Sulfate

SECTION 2: Hazards identification

OSHA OSHA Haz Com: CFR 1910.1200: Acute Toxicity - Oral [Category 4] Acute Toxicity - Dermal [Category 4] Acute Toxicity - Inhalation [Category 3] Eye Damage/Irritation [Category 2A] Sensitization - Skin [Category 1] Germ Cell Mutagenicity [Category 2] Carcinogenicity [Category 2] Specific Target Organ Toxicity (Single Exposure) [Category 1] Specific Target Organ Toxicity (Single Exposure) [Category 2] Specific Target Organ Toxicity (Repeated Exposure) [Category 2] Aquatic Hazard (Acute) [Category 1] Aquatic Hazard (Long-Term) [Category 1]

Signal word

Danger!

Hazard statements

Causes serious eye irritation Harmful if swallowed Harmful in contact with skin May cause an allergic skin reaction Suspected of causing cancer Suspected of causing genetic defects Toxic if inhaled Very toxic to aquatic life Very toxic to aquatic life with long lasting effects Causes damage to: Blood (System) May cause damage to organs: Liver Respiratory System Nervous System Kidney Muscle May cause damage to organs: Respiratory System Heart Kidney through prolonged or repeated exposure.

Hazard pictograms

or Symbol(s)

Prevention

Do not eat, drink or smoke when using this product. Wash hands and face thoroughly after handling. Wear protective gloves and protective clothing. Do not breathe dusts or mists. Use only outdoors or in a well- ventilated area. Wear eye and face protection. Avoid breathing dusts or mists. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing, eye protection and face protection. Wash all exposed skin thoroughly after handling.

Response

If swallowed Immediately call a poison center or doctor. Rinse mouth. If on skin Wash with plenty of water. Call a poison center or doctor if you feel unwell. Take off contaminated clothing and wash it before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. If skin irritation occurs Get medical advice/attention. Wash contaminated clothing before reuse. If exposed Call a poison center or doctor. If exposed or concerned Get medical advice or attention. If exposed or concerned Call a poison center or doctor. Get medical advice or attention if you feel unwell.

Storage

Store in a well-ventilated place. Keep container tightly closed. Store locked up.

Disposal

Dispose of contents and container in accordance with US EPA guidelines for the classification and determination of hazardous waste listed in 40 CFR 261.3. (See Section 13)

2.3 Other hazards

HNOC] Causes mild skin irritation