1,2-Phenylenediamine Sulfate

SECTION 2: Hazards identification

WHMIS 2015 OSHA Haz Com: CFR 1910.1200: Acute Toxicity - Oral [Category 4] WHMIS 2015: Acute Toxicity - Dermal [Category 4] Acute Toxicity - Inhalation [Category 3] Eye Damage/Irritation [Category 2A] Sensitization - Skin [Category 1] Germ Cell Mutagenicity [Category 2] Carcinogenicity [Category 2] Specific Target Organ Toxicity (Single Exposure) [Category 1] Specific Target Organ Toxicity (Single Exposure) [Category 2] Specific Target Organ Toxicity (Repeated Exposure) [Category 2] Aquatic Hazard (Acute) [Category 1] Aquatic Hazard (Long-Term) [Category 1]

Signal word

Danger!

Hazard statements

Toxic if inhaled Harmful if swallowed or in contact with skin Causes serious eye irritation May cause an allergic skin reaction Suspected of causing genetic defects Suspected of causing cancer Very toxic to aquatic life Very toxic to aquatic life with long lasting effects Causes damage to: Blood System May cause damage to organs: Liver Respiratory System Nervous System Kidney Muscle May cause damage to organs through prolonged or repeated exposure: Respiratory System Heart Kidney

Hazard pictograms

or Symbol(s)

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust, fume, mist, vapors or spray. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Do not eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out of the workplace. Wash hands and face thoroughly after handling. Wear protective gloves, protective clothing, face protection.

Response

If swallowed Call a poison center or doctor if you feel unwell. Rinse mouth. If on skin Wash with plenty of soap and water. Call a poison center or doctor if you feel unwell. Take off contaminated clothing and wash it before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. If exposed: Call a poison center or doctor. Collect spillage.

Storage

Store in a well-ventilated place. Keep container tightly closed. Store locked up.

Disposal

Dispose of contents and container in accordance with local, regional, national regulations (e.g. US 40 CFR Part 261, EU 91/156/EEC, JP Waste Disposal and Cleaning Act, etc.).

2.3 Other hazards

Causes mild skin irritation. [HNOC]