SORTE/TYPE P - NT (2036460_03)

SECTION 2: Hazards identification

R 10 Xn ; R 20 BUTYLGLYCOL ACETATE; EC-No. 203-933-3; CAS-No.: 112-07-2 Percentage ; 5 - 10 O/o

2.1 Classification of the substance or mixture

Xn ; R 20/21 SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM.; EC-No. 265-199-0; CAS-No. 64742-95-6 Percentage 5 - 10 010 Classjficatjon · Xn_;_R_65 ___________________ ----- 2-METHOXY-1-METHYLETHYL ACETATE; EC-No. 203-603-9; CAS-No. 108-65-6 Percentage 5 - 10 °/o

Classifications

R 10 Xi ; R 36

Hazard statements

Flammable · Harmful by inhalation lf4. FlrsT-aicfmeasures General In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Unconsciousness: lateral position - call a physician. After inhalation Remove concerned person out of danger area:Take the casualty into the fresh air and keep warm. Irregular breathing/no breathing: artificial respiration. Page: 2 /7 After skin contact Wash away with soap and water and rinse. Do NOT use solvents or thinners. After eye contact Remove contact lenses, keep eyelids open. Flush with plenty of water (10 - 15 min.). call a physician. After ingestion Do not induce vomiting - call a physician. Keep at rest. os "'Flre. fiiihtmameasures------·------------·------·------------·-··------·------- Suitable extinguishing media Alcohol resistant foam, C02, powders, water spray. Unsuitable extinguishing media Waterjet. Special risk posed by the substance or by the actual preparation, its combustion products or gases discharged Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Special protective equipment Appropriate breathing apparatus may be required.

Additional information

Cool endangered containers with water in case of fire. Do not allow the quenching water into the sewage system. Personal precautions Remove ignition sources. Provide for sufficient ventilation. Refer to protective measures listed in sections 7 and 8. Environmental precautions Do not empty into drains. If the product contaminates lakes, rivers or sewages, inform appropriate authorities in accordance with local regulations. - --·---- -- ·-Methods-for-cleaning-upjcollecting--·--· -··------·--·--·-------- ----- --- Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in container for disposal according to local regulations (see section 13). Clean preferabily with a detergent~ avoid use of solvents. 01. HanClffng and'sF0raae----~~ Information for safe handling Prevent the creation of inflammable or exploSlve concentrations of vapour in air and avoid vapour concentrations higher than the OEL (=Occupational Exposure Limit). Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Comply with the health and safety at work laws. Information about protection against explosions and fires Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. Requirements to be met by storerooms and containers Containers which are opened must be carefully resealed and kept upright to prevent leakage. Information about separation of incompatible products Page:3/7 Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. Further information about storage conditions Always keep in containers of same material as the original one. See also instructions on the label. Avoid heating and direct sunlight. Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and solvent vapour below the OEL (=Occupational Exposure Limit) , suitable respiratory protection must be worn. Components with critical values that require monitoring at the workplace (exposure limits) CYCLOHEXANONE ; CAS-No. 108-94-1 Specification Short term exposure limit ( EC ) Value: 20 ppm I 81,6 mg/m3

Remarks

version date 08.06.00 Specification threshold limit value ( EC ) Value: 10 ppm / 40,8 mg/m3 version date 08.06.00 Specification Short term exposure limit ( GB ) Value: 100 ml/m3 I 400 mg/m3 version date 01.01.89 Specification threshold limit value ( GB ) Value: 2S ml/m3 I 100 mg/m3 version date 01.01.89 BUTYLGLYCOL ACETATE; CAS-No.: 112-07-2 -- ------·--value·-: - -- --so ppm 1-333 mg7m3 __________________________ , ____ _ Specification Short term exposure limit ( EC ) version date 08.06.00 Specification threshold limit value ( EC ) Value: 20 ppm I 133 mg/m3 version date 08.06.00 2-METHOXY-1-METHYLETHYL ACETATE; CAS-No. 108-65-6 Specification ; Short term exposure limit ( EC ) Value: 100 ppm I 550 mg/m3 version date 08.06.00 Specification threshold limit value ( EC ) Value: 50 ppm I 275 mg/m3 version date 08.06.00 Page 4 / 7 Personal protective equipment Respiratory protection If workplace limits are exceeded, a gas mask approved for this purpose must be worn. Hand protection Solvent-resistent protective gloves must be worn. After washing hands replace lost skin fat by fat containing skin creams. Eye protection Use safety glasses. Body protection Personal should wear antistatic clothings made of natural fiber or of high temperature resistant synthetic fiber. All parts of the body should be washed after contact. Use appropriate skin protection cream before work. Image Form: Pasty to liquid. Colour: Coloured. Odour: Like solvent. Relevant safety data Boiling point/ range ( 1013 hPa) 145 - 195 literature Flash point ca. 43 Ignition temperature 200 - 300 Lower explosion limit: 0,6 0/o b.v. literature Upper explosion limit 10 0/o b.v. literature Vapour pressure (50°C) 1000 hPa Dampfdruck c20°c) ca. hPa literature Density: c20°c) 1,05 - 1,5 g/cm3 Solvent-separation test c20°c) Solubility in water (20°c) insoluble pH value: 6 - 8 Flow time: (20°C) 90 DIN-cup 4 mm 10. Stabilill( l!ni! rgl!!;J;ivitll Conditions to avoid Stable under recommended storage and handling conditions(See section 7). Materials to avoid Keep away from oxidizing agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions. Hazardous decomposition products When exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide and dioxide, smoke, oxides of nitrogen. 11~. ,,_,toxrco10q1ca1~-.-n1oyr'mat101i-- mrnWH, om~~-····----o_,,,,~,_,~,_,~~-~~-----_,,_,_, Experience on practice This product is unlikely to harm health, given normal and proper handling and hygenic precautions. Prolonged inhalation of vapours in high concentrations may lead to headache, giddiness and nausea. In case of contact with the product: danger of resorption throl\Qh the skin, irritation of skin/mucous membranes. Page: s f7 Additional toxicological information The product was classified in toxicological terms on the basis of the results of the calculation procedure outlined within General Directive on Preparations (88/379/EEC). Additional ecological information General ecological information Do not empty into waters or drains. Toxic effect on fishes and micro-organismes. Product Do not empty into waters or drains. Can be taken to a suitable incineration centre in oberseivance of local regulations. Waste key ABFALLSCHLOSSEL nach AW/EWC 08 03 14 Druckfarbenschlamme, die gefiihrliche Stoffe enthalten. Die empfohlene Abfalleinstufung bezieht sich nur auf den reinen Druckfarbenabfall. Contaminated packaging Recommendation Empty containers should be scrapped or reconditioned. Containers, which have not been emptied properly must be treated as special waste. Land transport ADR/RID and GGVS/GGVE (2001) Classification Class: 3 Kemlercode 30 Substance number 1210 Classification-Code Fl ADR: · (<= 450 I) Proper shipping name INK Packaging Packaging group III Label: 3 Maritime transport IMDG/GGVSea Classification IMDG·Code: 3 IMDG - Page: 3377·1 UN number: 1210 Marine Poll. MFAG-Table: 311 EmS number: 3·05 IMDG·Code . ( < = 450 I) Proper shipping name INK Packaging Packaging group III Page:6/7 Label: 3 Air transport ICAO-TI and IATA-DGR Classification Class: 3 UN number: 1210 Proper shipping name PRINTING INK Packaging Packaging group III Label 3 Classification according to EEC directives Danger symbol and danger designation n ; Harmful R-phrases 10 Flammable 20 Harmful by inhalation S-phrases 51 Use only in well-ventilated areas. 16. other-liii'Ormation Further information The details in this material safety data sheet satisfy national and EU legislation. We have no knowleclge or _____ .. -·---·. ----- --·-- -- -control over the-User's working conditions however. The product may not be used for any purpose other than that specified in chapter 1 unless written consent has been obtained. The user is responsible for the observance of all required statutory provisions. Relevant changes 02. Hazardous components · 08. Components with critical values that require monitoring at the workplace (exposure limits)· 14. Land transport ADR/RID and GGVS/GGVE (2001) · 14. Proper shipping name (ADR 2001) · 14. Maritime transport IMDG/GGVSea · 15. ·R-phrases · 15. 5-phrases R-Phrases of components 10 Flammable 20 Harmful by inhalation 20/21 Harmful by inhalation and in contact with skin 36 Irritating to eyes 65 Harmful: may cause lung damage if swallowed Department issuing data sheet Abt. SHE Page 7 f7 These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific