HPE55D-ISO-SL000502

SYNTHENE SAS

Revision date : 2025-03-28

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

0,1 - 0,5

EC/CAS

227-534-9/5873-54-1

Name of the chemical

2,4’-Methylenediphenyl diisocyanate

Concentration

0,1 - 0,5

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

0,1 - 0,5

EC/CAS

212-485-8/822-06-0

Name of the chemical

Hexamethylene diisocyanate

Concentration

<0,1

EC/CAS

247-722-4/26471-62-5

Name of the chemical

m-Tolylidendiisocyanat

Concentration

<0,0391

General Information

Version

7.00

Revision date

2025-03-28

Product name

HPE55D-ISO-SL000502

Emergency telephone

+44 20 7188 7188

Icons in SDS

GHS07 GHS08 M004 M009 M010 M013

Company Information

company name

SYNTHENE SAS

e-mail address of the competent person responsible for the Safety Data Sheet

qual@synthene.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

No additional information available

Hazard pictograms

GHS07 GHS08

Signal word

Danger

Contains

Alkyl alcohol reaction product of alkyl diisocyanate base; Homopolymère 1,6-diisocyanate d'hexaméthylène; Aromatic polyisocyanate prepolymer; 1,6-HEXAMETHYLENE DIISOCYANATE; Oxirane, methyl-, polymer with 1,1'- methylenebis[isocyanatobenzene], methyloxirane polymer with oxirane ether with oxybis[propanol] (2:1), and oxirane; 4,4'- methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate; Diphenylmethane- 2,4'-di-isocyanate; Diphenylmethane diisocyanate isomers and homologues; m-tolylidene diisocyanate; toluene-diisocyanate

Hazard statements

H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer.

Precautionary statements

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P261 - Avoid breathing mist, vapours. P264 - Wash hands, forearms and face thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing should not be allowed out of the workplace. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P284 - In case of inadequate ventilation wear respiratory protection. P302+P352 - IF ON SKIN: Wash with plenty of water, soap. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 - IF exposed or concerned: Get medical advice/attention. P312 - Call a POISON CENTRE or doctor if you feel unwell. P321 - Specific treatment (see supplemental first aid instruction on this label). P332+P313 - If skin irritation occurs: Get medical advice/attention. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER, a doctor. P362+P364 - Take off contaminated clothing and wash it before reuse. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents and container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

2.3 Other hazards

Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute toxicity (inhalation:dust,mist) Category 4 H332 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity – Single exposure, Category 3, H335 Respiratory tract irritation Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects No additional information available

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