Tris(trimethylsilylmethyl)phosphine

Hazard statements (CLP)

H250, H261, H302, H315, H319, H331, H335

Code

Statements

H250

Catches fire spontaneously if exposed to air

SECTION 2: Hazards identification

Classification (GHS-US) Classification of the substance or mixture Classification (GHS-US) Pyr. Sol. 1 H250 - Catches fire spontaneously if exposed to air Water-react. 2 H261 - In contact with water releases flammable gases Acute Tox. 4 (Oral) H302 - Harmful if swallowed Acute Tox. 3 (Inhalation) H331 - Toxic if inhaled Skin Irrit. 2 H315 - Causes skin irritation Eye Irrit. 2A H319 - Causes serious eye irritation STOT SE 3 H335 - May cause respiratory irritation Full text of H-phrases: see section 16

2.2 Label elements

GHS-US labeling

Hazard pictograms

GHS02 GHS06 GHS07

Signal word

Danger

Hazard statements

H250 - Catches fire spontaneously if exposed to air H261 - In contact with water releases flammable gases H302 - Harmful if swallowed H315 - Causes skin irritation H319 - Causes serious eye irritation H331 - Toxic if inhaled H335 - May cause respiratory irritation

Precautionary statements

P210 - Keep away from heat/sparks/open flames/hot surfaces. No smoking P222 - Do not allow contact with air P223 - Do not allow contact with water P231+P232 - Handle under inert gas. Protect from moisture P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P264 - Wash skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area 10/13/2017 EN (English US) SDS ID: 5180111 Page 1 P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P312 - If swallowed: Call a POISON CENTER or doctor/ physician if you feel unwell P302+P352 - If on skin: Wash with plenty of soap and water P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P311 - Call a POISON CENTER or doctor/physician P312 - Call a POISON CENTER or doctor/physician if you feel unwell P321 - Specific treatment (see supplemental first aid instructions on this label) P330 - Rinse mouth P332+P313 - If skin irritation occurs: Get medical advice/attention P335+P334 - Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages P337+P313 - If eye irritation persists: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse P370+P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish P402+P404 - Store in a dry place. Store in a closed container P403+P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P422 - Store contents under ... P501 - Dispose of contents/container to an approved waste disposal plant

2.3 Other hazards

No additional information available

Ingredient(s) with unknown acute toxicity

Not applicable

2.1 Classification of the substance or mixture

Classification (GHS-US) Pyr. Sol. 1 H250 - Catches fire spontaneously if exposed to air Water-react. 2 H261 - In contact with water releases flammable gases Acute Tox. 4 (Oral) H302 - Harmful if swallowed Acute Tox. 3 (Inhalation) H331 - Toxic if inhaled Skin Irrit. 2 H315 - Causes skin irritation Eye Irrit. 2A H319 - Causes serious eye irritation STOT SE 3 H335 - May cause respiratory irritation Full text of H-phrases: see section 16