Tosyl azide, 30% w/w in toluene

Hazard statements (CLP)

H225, H300, H304, H315, H335, H336, H361, H373, H401, H411

Code

Statements

H225

Highly Flammable liquid and vapour

Classification (GHS-US)

Flam. Liq. 2 H225 - Highly flammable liquid and vapour Acute Tox. 2 (Oral) H300 - Fatal if swallowed Skin Irrit. 2 H315 - Causes skin irritation Repr. 2 H361 - Suspected of damaging fertility or the unborn child STOT SE 3 H336 - May cause drowsiness or dizziness STOT SE 3 H335 - May cause respiratory irritation STOT RE 2 H373 - May cause damage to organs through prolonged or repeated exposure Asp. Tox. 1 H304 - May be fatal if swallowed and enters airways Aquatic Acute 2 H401 - Toxic to aquatic life Aquatic Chronic 2 H411 - Toxic to aquatic life with long lasting effects

Hazard statements

see section 16 : H225 - Highly flammable liquid and vapor H300 - Fatal if swallowed H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H361 - Suspected of damaging fertility or the unborn child H373 - May cause damage to organs through prolonged or repeated exposure H411 - Toxic to aquatic life with long lasting effects

2.2 Label elements

GHS-US labeling

Hazard pictograms

GHS02 GHS06 GHS07 GHS08 GHS09

Signal word

Danger

Precautionary statements

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat/sparks/open flames/hot surfaces. No smoking P233 - Keep container tightly closed P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical/ventilating/lighting equipment P242 - Use only non-sparking tools 12/08/2016 EN (English US) SDS ID: 8669107 P243 - Take precautionary measures against static discharge P260 - Do not breathe fumes, mist, spray, vapors P264 - Wash skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P310 - If swallowed: Immediately call a poison center/doctor/… P302+P352 - If on skin: Wash with plenty of soap and water P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P308+P313 - If exposed or concerned: Get medical advice/attention P312 - Call a POISON CENTER or doctor/physician if you feel unwell P314 - Get medical advice/attention if you feel unwell P321 - Specific treatment (see supplemental first aid instructions on this label) P330 - Rinse mouth P331 - Do NOT induce vomiting P332+P313 - If skin irritation occurs: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse P370+P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish P391 - Collect spillage P403+P233 - Store in a well-ventilated place. Keep container tightly closed P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents/container to an approved waste disposal plant

2.3 Other hazards

No additional information available 2.4.

Ingredient(s) with unknown acute toxicity

Not applicable