Tetrafluoroboric acid diethyl ether complex

Hazard statements (CLP)

H261, H302, H302+H312+H332, H312, H314, H318, H332, H335, H336

Code

Statements

H261

In contact with water releases flammable gas

SECTION 2: Hazards identification

Classification of the substance or mixture GHS US classification Substances and mixtures which in contact with water emit flammable H261 In contact with water releases flammable gas gases Category 2 Acute toxicity (oral) Category 4 H302 Harmful if swallowed Acute toxicity (dermal) Category 4 H312 Harmful in contact with skin Acute toxicity (inhalation) Category 4 H332 Harmful if inhaled Skin corrosion/irritation Category 1B H314 Causes severe skin burns and eye damage Serious eye damage/eye irritation Category 1 H318 Causes serious eye damage Specific target organ toxicity – Single exposure, Category 3, Narcosis H336 May cause drowsiness or dizziness Specific target organ toxicity – Single exposure, Category 3, H335 May cause respiratory irritation Respiratory tract irritation Full text of H statements : see section 16

2.2 Label elements

GHS US labeling

Signal word

Danger

Hazard statements

H261 - In contact with water releases flammable gas H302+H312+H332 - Harmful if swallowed, in contact with skin or if inhaled H314 - Causes severe skin burns and eye damage H318 - Causes serious eye damage H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness

Precautionary statements

P223 - Do not allow contact with water. P231+P232 - Handle under inert gas. Protect from moisture. P260 - Do not breathe fumes, mist, spray, vapors. P264 - Wash skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301+P312 - If swallowed: Call a POISON CENTER or doctor/ physician if you feel unwell P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting. P302+P352 - If on skin: Wash with plenty of soap and water P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER or doctor/ physician P321 - Specific treatment (see supplemental first aid instructions on this label) P322 - Specific treatment (see supplemental first aid instruction on this label) P330 - Rinse mouth. P335+P334 - Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. P362+P364 - Take off contaminated clothing and wash it before reuse. P363 - Wash contaminated clothing before reuse. P370+P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish P402+P404 - Store in a dry place. Store in a closed container. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/container to an approved waste disposal plant

Other hazards which do not result in classification

Reacts violently with water.

Ingredient(s) with unknown acute toxicity

No additional information available

2.1 Classification of the substance or mixture

GHS US classification Substances and mixtures which in contact with water emit flammable H261 In contact with water releases flammable gas gases Category 2 Acute toxicity (oral) Category 4 H302 Harmful if swallowed Acute toxicity (dermal) Category 4 H312 Harmful in contact with skin Acute toxicity (inhalation) Category 4 H332 Harmful if inhaled Skin corrosion/irritation Category 1B H314 Causes severe skin burns and eye damage Serious eye damage/eye irritation Category 1 H318 Causes serious eye damage Specific target organ toxicity – Single exposure, Category 3, Narcosis H336 May cause drowsiness or dizziness Specific target organ toxicity – Single exposure, Category 3, H335 May cause respiratory irritation Respiratory tract irritation Full text of H statements : see section 16