Regulations 1995

Hazard statements (CLP)

H315, H319, H332, H335, H410

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazard statements

H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. Supplemental EUH401 To avoid risks to human health and the environment comply with the instructions for use.

Precautionary statements

P261 Avoid breathing mist P264 Wash hands and face thoroughly after handling. P280 Wear protective gloves/ protective clothing/ eye protection/face protection. P337+P313 If eye irritation persists: Get medical advice/ attention. P391 Collect spillage. P501 Dispose of contents/container to a licensed hazard- ous-waste disposal contractor or collection site ex- cept for empty triple rinsed clean containers which can be disposed of as non-hazardous waste. 6

Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Acute toxicity, Category 4 - H302: Harmful if swallowed. Eye irritation, Category 2 - H319: Causes serious eye irritation. Short-term (acute) aquatic hazard, Category 1 - H400: Very toxic to aquatic life. Long-term (chronic) aquatic hazard, Category 1 - H410: Very toxic to aquatic life with long lasting effects. H332: Harmful if inhaled. H315: Causes skin irritation. 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Hazard pictograms Hazard Statements H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. Supplemental EUH401 To avoid risks to human health and the environment Hazard Statements comply with the instructions for use. Precautionary Statements P261 Avoid breathing mist P264 Wash hands and face thoroughly after handling. P280 Wear protective gloves/ protective clothing/ eye protection/face protection. P337+P313 If eye irritation persists: Get medical advice/ attention. P391 Collect spillage. P501 Dispose of contents/container to a licensed hazard- ous-waste disposal contractor or collection site ex- cept for empty triple rinsed clean containers which can be disposed of as non-hazardous waste. 6 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.2 Mixtures Components Chemical Name CAS-No. Classification Concentration EC-No. (% w/w) Index-No. Registration number Propanoic acid, 34451-19-9 Skin Irrit. 2; H315 >= 30 - < 50 2-hydroxy-, butyl 205-316-4 Eye Irrit. 2; H319 ester, (2S)- difenoconazole 119446-68-3 Acute Tox. 4; H302 >= 2.5 - < 10 Eye Irrit. 2; H319 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 M-Factor (Acute aquatic toxicity): 10 M-Factor (Chronic aquatic toxicity): 10 benzovindiflupyr (ISO) 1072957-71-1 Acute Tox. 3; H301 >= 1 - < 2.5 Acute Tox. 3; H331 616-218-00-X Aquatic Acute 1; H400 01-2119929229-31 Aquatic Chronic 1; H410 M-Factor (Acute aquatic toxicity): 100 M-Factor (Chronic aquatic toxicity): 100 For explanation of abbreviations see section 16. SECTION 4. FIRST AID MEASURES 4.1 Description of first aid measures General advice: Have the product container, label or Safety Data Sheet with you when calling the emergency number, a poison control center or physician, or going for treatment. If inhaled: Move the victim to fresh air. If breathing is irregular or stopped, administer artificial respiration. Keep patient warm and at rest. Call a physician or poison control centre immediately. 7 In case of skin contact: Take off all contaminated clothing immediately. Wash off immediately with plenty of water. If skin irritation persists, call a physician. Wash contaminated clothing before re-use. In case of eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Immediate medical attention is required. If swallowed: If swallowed, seek medical advice immediately and show this container or label. Do NOT induce vomiting. 4.2 Most important symptoms and effects, both acute and delayed symptoms Symptoms: Nonspecific. No symptoms known or expected. 4.3 Indication of any immediate medical attention and special treatment needed Treatment: There is no specific antidote available. Treat symptomatically. SECTION 5. FIRE-FIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media: Extinguishing media - small fires Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Extinguishing media - large fires Use alcohol-resistant foam or water spray. Unsuitable extinguishing media: Do not use a solid water stream as it may scatter and spread fire. 5.2 Specific hazards arising from the substance or mixture Specific hazards during fire-fighting: As the product contains combustible organic components, fire will produce dense black smoke containing hazardous products of combustion (see section 10). Exposure to decomposition products may be a hazard to health. 5.3 Advice for firefighters Special protective equipment: Wear full protective clothing and self-contained breathing apparatus. Do not allow run-off from fire fighting to enter drains or water courses. Cool closed containers exposed to fire with water spray. SECTION 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions: Refer to protective measures listed in sections 7 and 8. 6.2 Environmental precautions Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up: Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Clean 8 contaminated surface thoroughly. Clean with detergents. Avoid solvents. Retain and dispose of contaminated wash water. 6.4 Reference to other sections For disposal considerations see section 13., Refer to protective measures listed in sections 7 and 8. SECTION 7. HANDLING AND STORAGE 7.1 Precautions for safe handling Advice on safe handling: No special protective measures against fire required. Avoid contact with skin and eyes. When using, do not eat, drink or smoke. For personal protection see section 8. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers: No special storage conditions required. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from food, drink and animal feedingstuffs. 7.3 Specific end use(s) Specific use(s): For proper and safe use of this product, please refer to the approval conditions laid down on the product label. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters Occupational Exposure Limits Components CAS-No. Value type Control Basis (Form of exposure) parameters Propanoic acid, 2-hydroxy-, 34451-19-9 OELV - 8 hrs 5 ppm IE OEL butyl ester, (2S)- (TWA) 25 mg/m3 Further information: Where no specific short-term exposure limit is listed, a figure three times the long-term exposure limit value should be used difenoconazole 119446-68-3 TWA 5 mg/m3 Syngenta benzovindiflupyr (ISO) 1072957-71-1 TWA 1 mg/m3 Syngenta Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006: Substance name End Use Exposure routes Potential health effects Value benzovindiflupyr (ISO) Workers Inhalation