VANIVA

Hazard statements (CLP)

H411

Code

Statements

H411

Toxic to aquatic life with long lasting effects

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazard statements

H411 Toxic to aquatic life with long lasting effects.

Response

P391 Collect spillage.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Long-term (chronic) aquatic hazard, H411: Toxic to aquatic life with long lasting effects. Category 2 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Hazard pictograms : Hazard statements : H411 Toxic to aquatic life with long lasting effects. Precautionary statements : Response: P391 Collect spillage. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. SECTION 3: Composition/information on ingredients 3.2 Mixtures Components Chemical name CAS-No. Classification Concentration EC-No. (% w/w) Index-No. Registration number cyclobutrifluram 1460292-16-3 Aquatic Chronic 2; >= 30 - < 50 H411 toluene 108-88-3 Flam. Liq. 2; H225 >= 0,1 - < 1 203-625-9 Skin Irrit. 2; H315 601-021-00-3 Repr. 2; H361d 01-2119471310-51- STOT SE 3; H336 xxxx (Central nervous system) STOT RE 2; H373 Asp. Tox. 1; H304 1,2-benzisothiazol-3(2H)-one 2634-33-5 Acute Tox. 4; H302 >= 0,025 - < 220-120-9 Skin Irrit. 2; H315 0,05 613-088-00-6 Eye Dam. 1; H318 01-2120761540-60- Skin Sens. 1; H317 xxxx Aquatic Acute 1; H400 Aquatic Chronic 2; H411 M-Factor (Acute aquatic toxicity): 1 bronopol (INN) 52-51-7 Acute Tox. 4; H302 >= 0,025 - < 200-143-0 Acute Tox. 4; H312 0,1 603-085-00-8 Skin Irrit. 2; H315 01-2119980938-15- Eye Dam. 1; H318 xxxx STOT SE 3; H335 (Respiratory system) Aquatic Acute 1; H400 Aquatic Chronic 1; H410 M-Factor (Acute aquatic toxicity): 10 M-Factor (Chronic aquatic toxicity): 1 For explanation of abbreviations see section 16. SECTION 4: First aid measures 4.1 Description of first aid measures General advice : Have the product container, label or Safety Data Sheet with you when calling the emergency number, a poison control center or physician, or going for treatment. If inhaled : Move the victim to fresh air. If breathing is irregular or stopped, administer artificial respiration. Keep patient warm and at rest. Call a physician or poison control centre immediately. In case of skin contact : Take off all contaminated clothing immediately. Wash off immediately with plenty of water. If skin irritation persists, call a physician. Wash contaminated clothing before re-use. In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Immediate medical attention is required. If swallowed : If swallowed, seek medical advice immediately and show this container or label. Do NOT induce vomiting. 4.2 Most important symptoms and effects, both acute and delayed Symptoms : Nonspecific No symptoms known or expected. 4.3 Indication of any immediate medical attention and special treatment needed Treatment : There is no specific antidote available. Treat symptomatically. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Extinguishing media - small fires Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Extinguishing media - large fires Alcohol-resistant foam or Water spray Unsuitable extinguishing : Do not use a solid water stream as it may scatter and spread media fire. 5.2 Special hazards arising from the substance or mixture Specific hazards during : As the product contains combustible organic components, fire firefighting will produce dense black smoke containing hazardous products of combustion (see section 10). Exposure to decomposition products may be a hazard to health. 5.3 Advice for firefighters Special protective equipment : Wear full protective clothing and self-contained breathing for firefighters apparatus. Further information : Do not allow run-off from fire fighting to enter drains or water courses. Cool closed containers exposed to fire with water spray. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Refer to protective measures listed in sections 7 and 8. 6.2 Environmental precautions Environmental precautions : Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3 Methods and material for containment and cleaning up Methods for cleaning up : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Clean contaminated surface thoroughly. Clean with detergents. Avoid solvents. Retain and dispose of contaminated wash water. 6.4 Reference to other sections For disposal considerations see section 13., Refer to protective measures listed in sections 7 and 8. SECTION 7: Handling and storage 7.1 Precautions for safe handling Advice on safe handling : No special protective measures against fire required. Avoid contact with skin and eyes. When using do not eat, drink or smoke. For personal protection see section 8. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage : No special storage conditions required. Keep containers areas and containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from food, drink and animal feedingstuffs. 7.3 Specific end use(s) Specific use(s) : For proper and safe use of this product, please refer to the approval conditions laid down on the product label. SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational Exposure Limits Components CAS-No. Value type (Form Control parameters Basis of exposure) cyclobutrifluram 1460292- TWA 5 mg/m3 Syngenta 16-3 toluene 108-88-3 OEL-RL 40 ppm ZA OEL Further information: danger of cutaneous absorption, Occupational Exposure Limits - Restricted Limits For Hazardous Chemical Agents TWA 50 ppm 2006/15/EC 192 mg/m3 STEL 100 ppm 2006/15/EC 384 mg/m3 Biological occupational exposure limits Substance name CAS-No. Control parameters Sampling time Basis toluene 108-88-3 Toluene: 0,02 mg/l Prior to last shift of ZA BEI (Blood) workweek Toluene: 0,03 mg/l End of shift ZA BEI (Urine) o-Cresol: 0.3 mg/g End of shift ZA BEI Creatinine (Urine) Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006: Substance name End Use Exposure routes Potential health Value effects propane-1,2-diol Workers Inhalation Long-term systemic 168 mg/m3 effects