ADVION EVOLUTION COCKROACH GEL BAIT

SECTION 2: Hazards identification

OSHA Classifications Not Applicable

Precautionary statements

Not Applicable

Other hazards

Statements None

2.1 Classification of the substance or mixture

Not Applicable Signal Word (OSHA): Not Applicable Hazard Statements: Not Applicable Hazard Symbols: Precautionary Statements: Not Applicable Other Hazard Statements: None 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Common Name CAS Number Concentration Starch 9005-25-8 <5.0% Other ingredients Trade Secret >94.4% methyl (4aS)-7-chloro-2,5-dihydro-2- Indoxacarb Technical 173584-44-6 0.60% [[(methoxycarbonyl)[4- (trifluoromethoxy)phenyl]amino]carbonyl]in deno[1,2-e][1,3,4]oxadiazine-4a(3H)- carboxylate Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications. N\A 4. FIRST AID MEASURES Have the product container, label or Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison control center or doctor, or going for treatment. Ingestion: If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment advice. Do not give any liquid to the person. Do not induce vomiting unless told to do so after calling 800-888- 8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Eye Contact: If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Skin Contact: If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Inhalation: If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call Syngenta (800-888-8372), a poison control center or doctor for further treatment advice. Most important symptoms/effects: Not Applicable Indication of immediate medical attention and special treatment needed: There is no specific antidote if this product is ingested. Treat symptomatically. 5. FIRE FIGHTING MEASURES Suitable (and unsuitable) extinguishing media: Use dry chemical, foam or CO2 extinguishing media. If water is used to fight fire, dike and collect runoff. Specific Hazards: None known. Special protective equipment and precautions for firefighters: Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment, and emergency procedures: Follow exposure controls/personal protection outlined in Section 8. Methods and materials for containment and cleaning up: Avoid dust formation. Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. Sweep up material and place in a compatible disposal container. Scrub area with hard water detergent (e.g. commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition. N\A 7. HANDLING AND STORAGE Precautions for safe handling: Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Conditions for safe storage, including any incompatibilities: Not Applicable 8. EXPOSURE CONTROLS/PERSONAL PROTECTION THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION AND PACKAGING OF THIS PRODUCT. FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL. Occupational Exposure Limits: Chemical Name OSHA PEL ACGIH TLV Other Source Starch 15 mg/m³ (total) TWA; 5 10 mg/m³ TWA 10 mg/m³ (total) NIOSH mg/m³ (resp) TWA TWA; 5 mg/m³ (resp) TWA Other ingredients Not Established Not Applicable Indoxacarb Technical Not Established 1 mg/m³ 8hr & 12hr Manufacturer TWA (respirable) Appropriate engineering controls: Use effective engineering controls to comply with occupational exposure limits (if applicable). Individual protection measures: Ingestion: Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Eye Contact: Where eye contact is likely, use dust-proof chemical goggles. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Skin Contact: Where contact is likely, wear chemical-resistant (such as nitrile or butyl) gloves, coveralls, socks and chemical-resistant footwear. Inhalation: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below exposure limits. A NIOSH-certified combination air-purifying respirator with an N, P or R 95 or HE class filter and an organic vapor cartridge may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is limited. Use a pressure demand atmosphere-supplying respirator if there is any potential for uncontrolled release, exposure levels are not known, or under any other circumstances where air- purifying respirators may not provide adequate protection. N\A 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Yellow gel Odor: No characteristic odor Odor Threshold: Not Available pH: 6.08 Melting point/freezing point: Not Available Initial boiling point and boiling range: Not Available Flash Point (Test Method): Not Available Flammable Limits (% in Air): Not Available Flammability: Not Available Vapor Pressure: Indoxacarb Technical Not Available Vapor Density: Not Available Relative Density: 1.0755 g/ml % @ 68°F (20°C) Solubility (ies): Indoxacarb Technical Not Available Partition coefficient: n-octanol/water: Autoignition Temperature: Not Available Decomposition Temperature: Not Available Viscosity: Not Available Other: None 10. STABILITY AND REACTIVITY Reactivity: Not reactive. Chemical stability: Stable under normal use and storage conditions. Possibility of hazardous reactions: Will not occur. Conditions to Avoid: Not Available Incompatible materials: None known. Hazardous Decomposition Products: Not Available 11. TOXICOLOGICAL INFORMATION Health effects information Likely routes of exposure: Dermal, Inhalation Symptoms of exposure: Not Applicable Delayed, immediate and chronic effects of exposure: Not Applicable Numerical measures of toxicity (acute toxicity/irritation studies (finished product)) Ingestion: Oral (LD50 Female Rat) : > 5000 mg/kg body weight N\A Dermal: Dermal (LD50 Rat) : > 5000 mg/kg body weight Inhalation: Inhalation (LC50 Rat) : > 5.5 mg/l air - 4 hours (applies to the active ingredient) Eye Contact: Non-Irritating (Rabbit) Skin Contact: Non-Irritating (Rabbit) Skin Sensitization: Not a Sensitizer (Mouse) Reproductive/Developmental Effects Indoxacarb Technical: Animal testing showed effects on reproduction at levels equal to or above those causing parental toxicity. Animal testing showed effects on embryo-fetal development at levels equal to or above those causing maternal toxicity. Chronic/Subchronic Toxicity Studies Indoxacarb Technical: The following effects occurred at levels of exposure that significantly exceed those expected under labeled usage conditions. Inhalation; rat; Incoordination, mortality, red blood cell destruction causing abnormal decrease in number of red blood cells (anemia) Carcinogenicity Indoxacarb Technical: Animal testing did not show any carcinogenic effects. Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Did not cause genetic damage in animals. Chemical Name NTP/IARC/OSHA Carcinogen Starch No Other ingredients No methyl (4aS)-7-chloro-2,5-dihydro-2- No [[(methoxycarbonyl)[4- (trifluoromethoxy)phenyl]amino]carbonyl]inden o[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylate Other Toxicity Information Not Available Toxicity of Other Components Other ingredients Not Established Starch May cause eye and skin irritation. May cause respiratory tract irritation. Target Organs Active Ingredients Indoxacarb Technical: Nervous system Inert Ingredients Other ingredients: Not Established Starch: Eye, skin, respiratory tract