PLESIVA STAR 60WG

Hazard statements (CLP)

H351, H400, H410

Code

Statements

H351

Suspected of causing cancer

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Warning

Hazard statements

H351 Suspected of causing cancer. H410 Very toxic to aquatic life with long lasting effects.

Supplemental label elements

EUH401 To avoid risks to human health and the environment, comply with the instructions for use.

Prevention

P201 Obtain special instructions before use. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

P308 + P313 IF exposed or concerned: Get medical advice/ attention. P391 Collect spillage.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Hazardous Ingredients

pymetrozine (ISO)

Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher May form combustible dust concentrations in air.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Carcinogenicity, Category 2 H351: Suspected of causing cancer. Acute aquatic toxicity, Category 1 H400: Very toxic to aquatic life. Chronic aquatic toxicity, Category 1 H410: Very toxic to aquatic life with long lasting effects. 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Hazard pictograms : Signal word : Warning Hazard statements : H351 Suspected of causing cancer. H410 Very toxic to aquatic life with long lasting effects. Supplemental Hazard : EUH401 To avoid risks to human health and the Statements environment, comply with the instructions for use. Precautionary statements : Prevention: P201 Obtain special instructions before use. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P308 + P313 IF exposed or concerned: Get medical advice/ attention. P391 Collect spillage. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Hazardous components which must be listed on the label: pymetrozine (ISO) 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. May form combustible dust concentrations in air. SECTION 3: Composition/information on ingredients 3.2 Mixtures Hazardous components Chemical name CAS-No. Classification Concentration EC-No. (% w/w) Index-No. Registration number pymetrozine (ISO) 123312-89-0 Carc. 2; H351 >= 50 - < 70 Aquatic Chronic 3; 613-202-00-4 H412 cyantraniliprole 736994-63-1 Aquatic Acute 1; >= 10 - < 20 H400 Aquatic Chronic 1; H410 sodium 25417-20-3 Acute Tox. 4; H302 >= 1 - < 2.5 dibutylnaphthalenesulphonate 246-960-6 Acute Tox. 4; H332 Skin Irrit. 2; H315 Eye Irrit. 2; H319 Aquatic Chronic 3; H412 For explanation of abbreviations see section 16. SECTION 4: First aid measures 4.1 Description of first aid measures General advice : Have the product container, label or Safety Data Sheet with you when calling the emergency number, a poison control center or physician, or going for treatment. If inhaled : Move the victim to fresh air. If breathing is irregular or stopped, administer artificial respiration. Keep patient warm and at rest. Call a physician or poison control centre immediately. In case of skin contact : Take off all contaminated clothing immediately. Wash off immediately with plenty of water. If skin irritation persists, call a physician. Wash contaminated clothing before re-use. In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Immediate medical attention is required. If swallowed : If swallowed, seek medical advice immediately and show this container or label. Do NOT induce vomiting. 4.2 Most important symptoms and effects, both acute and delayed Symptoms : No symptoms known or expected. 4.3 Indication of any immediate medical attention and special treatment needed Treatment : There is no specific antidote available. Treat symptomatically. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Extinguishing media - small fires Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Extinguishing media - large fires Alcohol-resistant foam or Water spray Unsuitable extinguishing : Do not use a solid water stream as it may scatter and spread media fire. 5.2 Special hazards arising from the substance or mixture Specific hazards during : As the product contains combustible organic components, fire firefighting will produce dense black smoke containing hazardous products of combustion (see section 10). Exposure to decomposition products may be a hazard to health. 5.3 Advice for firefighters Special protective equipment : Wear full protective clothing and self-contained breathing for firefighters apparatus. Further information : Do not allow run-off from fire fighting to enter drains or water courses. Cool closed containers exposed to fire with water spray. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Refer to protective measures listed in sections 7 and 8. Avoid dust formation. 6.2 Environmental precautions Environmental precautions : Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3 Methods and material for containment and cleaning up Methods for cleaning up : Contain spillage, pick up with an electrically protected vacuum cleaner or by wet-brushing and transfer to a container for disposal according to local regulations (see section 13). Do not create a powder cloud by using a brush or compressed air. Clean contaminated surface thoroughly. Clean with detergents. Avoid solvents. Retain and dispose of contaminated wash water. 6.4 Reference to other sections For disposal considerations see section 13., Refer to protective measures listed in sections 7 and 8. SECTION 7: Handling and storage 7.1 Precautions for safe handling Advice on safe handling : This material is capable of forming flammable dust clouds in air, which, if ignited, can produce a dust cloud explosion. Flames, hot surfaces, mechanical sparks and electrostatic discharges can serve as ignition sources for this material. Electrical equipment should be compatible with the flammability characteristics of this material. The flammability characteristics will be made worse if the material contains traces of flammable solvents or is handled in the presence of flammable solvents. This material can become readily charged in most operations. Avoid contact with skin and eyes. When using do not eat, drink or smoke. For personal protection see section 8. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage : Keep containers tightly closed in a dry, cool and well- areas and containers ventilated place. Keep out of the reach of children. Keep away from food, drink and animal feedingstuffs. 7.3 Specific end use(s) Specific use(s) : For proper and safe use of this product, please refer to the approval conditions laid down on the product label. SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational Exposure Limits Components CAS-No. Value type (Form Control parameters Basis of exposure) pymetrozine (ISO) 123312-89- TWA 0.8 mg/m3 Syngenta 0 cyantraniliprole 736994-63- TWA 5 mg/m3 Syngenta 1 silica 61790-53-2 TWA (inhalable 4 mg/m3 CH SUVA dust) Further information Harm to the unborn child is not to be expected when the OEL-value is respected 8.2 Exposure controls Engineering measures Containment and/or segregation is the most reliable technical protection measure if exposure cannot be eliminated. The extent of these protection measures depends on the actual risks in use. Maintain air concentrations below occupational exposure standards. Where necessary, seek additional occupational hygiene advice. Personal protective equipment Eye protection : No special protective equipment required. Hand protection Remarks : No special protective equipment required. Skin and body protection : No special protective equipment required. Select skin and body protection based on the physical job requirements. Respiratory protection : No personal respiratory protective equipment normally required. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Protective measures : The use of technical measures should always have priority over the use of personal protective equipment. When selecting personal protective equipment, seek appropriate professional advice. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : granules Colour : beige to brown Odour : No data available Odour Threshold : No data available pH : 7 - 11 Concentration: 1 % w/v Melting point/range : No data available Boiling point/boiling range : No data available Flash point : No data available Evaporation rate : No data available Flammability (solid, gas) : May form combustible dust concentrations in air. Burning number : 3 (20 °C) 5 (100 °C) Upper explosion limit / Upper : No data available flammability limit Lower explosion limit / Lower : No data available flammability limit Relative vapour density : No data available Solubility(ies) Solubility in other solvents : No data available Partition coefficient: n- : No data available octanol/water Auto-ignition temperature : > 400 °C Decomposition temperature : No data available Viscosity Viscosity, dynamic : No data available Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. 9.2 Other information Minimum ignition energy : 300 - 1,000 mJ SECTION 10: Stability and reactivity 10.1 Reactivity None reasonably foreseeable. 10.2 Chemical stability Stable under normal conditions. 10.3 Possibility of hazardous reactions Hazardous reactions : No dangerous reaction known under conditions of normal use. 10.4 Conditions to avoid Conditions to avoid : No decomposition if used as directed. 10.5 Incompatible materials Materials to avoid : None known. 10.6 Hazardous decomposition products Combustion or thermal decomposition will evolve toxic and irritant vapours. SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Product: Acute oral toxicity : LD50 (Rat, female): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat, male and female): > 5.03 mg/l Test atmosphere: dust/mist Acute toxicity estimate: > 5 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method Acute dermal toxicity : LD50 (Rat, male and female): > 5,000 mg/kg Components: pymetrozine (ISO): Acute oral toxicity : LD50 (Rat, male and female): 5,820 mg/kg Acute inhalation toxicity : LC50 (Rat, male and female): > 1.8 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rat, male and female): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity cyantraniliprole: Acute oral toxicity : LD50 (Rat, female): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5.24 mg/l Exposure time: 4 h Test atmosphere: dust/mist Acute dermal toxicity : LD50 (Rat, female): > 5,000 mg/kg sodium dibutylnaphthalenesulphonate: Acute oral toxicity : Assessment: The component/mixture is moderately toxic after single ingestion. Acute inhalation toxicity : Assessment: The component/mixture is moderately toxic after short term inhalation. Skin corrosion/irritation Product: Species: Rabbit Result: No skin irritation Components: pymetrozine (ISO): Species: Rabbit Result: No skin irritation cyantraniliprole: Species: Rabbit Result: No skin irritation Serious eye damage/eye irritation Product: Species: Rabbit Result: No eye irritation Components: pymetrozine (ISO): Species: Rabbit Result: No eye irritation cyantraniliprole: Species: Rabbit Result: No eye irritation sodium dibutylnaphthalenesulphonate: Result: Eye irritation Respiratory or skin sensitisation Product: Species: Guinea pig Result: Did not cause sensitisation on laboratory animals. Components: pymetrozine (ISO): Species: Guinea pig Result: Did not cause sensitisation on laboratory animals. cyantraniliprole: Test Type: mouse lymphoma cells Species: Mouse Result: Did not cause sensitisation on laboratory animals. Germ cell mutagenicity Components: pymetrozine (ISO): Germ cell mutagenicity- : Did not show mutagenic or teratogenic effects in animal Assessment experiments. cyantraniliprole: Germ cell mutagenicity- : Animal testing did not show any mutagenic effects. Assessment Carcinogenicity Components: pymetrozine (ISO): Carcinogenicity - : Increased levels of liver tumours were observed at high doses Assessment in rats and mice. The relevance of these findings to humans is questionable. ,Limited evidence of carcinogenicity in animal studies cyantraniliprole: Carcinogenicity - : No evidence of carcinogenicity in animal studies. Assessment Reproductive toxicity Components: pymetrozine (ISO): Reproductive toxicity - : No toxicity to reproduction Assessment cyantraniliprole: Reproductive toxicity - : No toxicity to reproduction Assessment Repeated dose toxicity Product: Remarks: No information available. Components: cyantraniliprole: Remarks: The substance or mixture is not classified as specific target organ toxicant, repeated exposure. SECTION 12: Ecological information 12.1 Toxicity Product: Toxicity to fish : LC50 (Cyprinus carpio (Carp)): > 100 mg/l Exposure time: 96 h Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0.18 mg/l aquatic invertebrates Exposure time: 48 h Toxicity to algae : ErC50 (Pseudokirchneriella subcapitata (green algae)): > 100 mg/l Exposure time: 72 h Components: pymetrozine (ISO): Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 87 mg/l aquatic invertebrates Exposure time: 48 h Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): 16.9 mg/l Exposure time: 96 h NOEC (Pseudokirchneriella subcapitata (green algae)): 6.28 mg/l Exposure time: 96 h Toxicity to microorganisms : EC50 (activated sludge): > 100 mg/l Exposure time: 3 h Toxicity to fish (Chronic : NOEC: 11.7 mg/l