ORONDIS ULTRA

Hazard statements (CLP)

H410

Code

Statements

H410

Very toxic to aquatic life with long lasting effects

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Warning

Hazard statements

H410 Very toxic to aquatic life with long lasting effects.

Supplemental label elements

EUH401 To avoid risks to human health and the environment, comply with the instructions for use. EUH208 Contains 1,2-benzisothiazol-3-one. May produce an allergic reaction.

Response

P391 Collect spillage.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Acute aquatic toxicity, Category 1 H400: Very toxic to aquatic life. Chronic aquatic toxicity, Category 1 H410: Very toxic to aquatic life with long lasting effects. 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Hazard pictograms : Signal word : Warning Hazard statements : H410 Very toxic to aquatic life with long lasting effects. Supplemental Hazard : EUH401 To avoid risks to human health and the Statements environment, comply with the instructions for use. EUH208 Contains 1,2-benzisothiazol-3-one. May produce an allergic reaction. Precautionary statements : Response: P391 Collect spillage. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. SECTION 3: Composition/information on ingredients 3.2 Mixtures Hazardous components Chemical name CAS-No. Classification Concentration EC-No. (% w/w) Registration number mandipropamid (ISO) 374726-62-2 Aquatic Acute 1; >= 20 - < 25 H400 Aquatic Chronic 1; H410 oxathiapiprolin 1003318-67-9 Aquatic Acute 1; >= 2.5 - < 10 H400 Aquatic Chronic 1; H410 1,2-benzisothiazol-3(2H)-one 2634-33-5 Acute Tox. 4; H302 >= 0.025 - < 220-120-9 Skin Irrit. 2; H315 0.05 Eye Dam. 1; H318 Skin Sens. 1; H317 Aquatic Acute 1; H400 bronopol (INN) 52-51-7 Acute Tox. 4; H302 >= 0.025 - < 200-143-0 Acute Tox. 4; H312 0.1 Skin Irrit. 2; H315 Eye Dam. 1; H318 STOT SE 3; H335 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 For explanation of abbreviations see section 16. SECTION 4: First aid measures 4.1 Description of first aid measures General advice : Have the product container, label or Safety Data Sheet with you when calling the emergency number, a poison control center or physician, or going for treatment. If inhaled : Move the victim to fresh air. If breathing is irregular or stopped, administer artificial respiration. Keep patient warm and at rest. Call a physician or poison control centre immediately. In case of skin contact : Take off all contaminated clothing immediately. Wash off immediately with plenty of water. If skin irritation persists, call a physician. Wash contaminated clothing before re-use. In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Immediate medical attention is required. If swallowed : If swallowed, seek medical advice immediately and show this container or label. Do NOT induce vomiting. 4.2 Most important symptoms and effects, both acute and delayed Symptoms : No information available. 4.3 Indication of any immediate medical attention and special treatment needed Treatment : There is no specific antidote available. Treat symptomatically. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Extinguishing media - small fires Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Extinguishing media - large fires Alcohol-resistant foam or Water spray Unsuitable extinguishing : Do not use a solid water stream as it may scatter and spread media fire. 5.2 Special hazards arising from the substance or mixture Specific hazards during : As the product contains combustible organic components, fire firefighting will produce dense black smoke containing hazardous products of combustion (see section 10). Exposure to decomposition products may be a hazard to health. 5.3 Advice for firefighters Special protective equipment : Wear full protective clothing and self-contained breathing for firefighters apparatus. Further information : Do not allow run-off from fire fighting to enter drains or water courses. Cool closed containers exposed to fire with water spray. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Refer to protective measures listed in sections 7 and 8. 6.2 Environmental precautions Environmental precautions : Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3 Methods and material for containment and cleaning up Methods for cleaning up : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Clean contaminated surface thoroughly. Clean with detergents. Avoid solvents. Retain and dispose of contaminated wash water. 6.4 Reference to other sections For disposal considerations see section 13., Refer to protective measures listed in sections 7 and 8. SECTION 7: Handling and storage 7.1 Precautions for safe handling Advice on safe handling : No special protective measures against fire required. Avoid contact with skin and eyes. When using do not eat, drink or smoke. For personal protection see section 8. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage : No special storage conditions required. Keep containers areas and containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from food, drink and animal feedingstuffs. 7.3 Specific end use(s) Specific use(s) : For proper and safe use of this product, please refer to the approval conditions laid down on the product label. SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational Exposure Limits Components CAS-No. Value type (Form Control parameters Basis of exposure) mandipropamid 374726-62- TWA 5 mg/m3 Syngenta (ISO) 2 poly(oxy-1,2- 25322-68-3 TWA 1,000 mg/m3 CH SUVA ethanediyl), alpha- hydro-omega- hydroxy- Further information Harm to the unborn child is not to be expected when the OEL-value is respected 8.2 Exposure controls Engineering measures Containment and/or segregation is the most reliable technical protection measure if exposure cannot be eliminated. The extent of these protection measures depends on the actual risks in use. Maintain air concentrations below occupational exposure standards. Where necessary, seek additional occupational hygiene advice. Personal protective equipment Eye protection : No special protective equipment required. Hand protection Remarks : No special protective equipment required. Skin and body protection : No special protective equipment required. Select skin and body protection based on the physical job requirements. Respiratory protection : No personal respiratory protective equipment normally required. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Protective measures : The use of technical measures should always have priority over the use of personal protective equipment. When selecting personal protective equipment, seek appropriate professional advice. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : opaque Colour : off-white to light brown pH : 7.68 Concentration: 1 % w/v Density : 1.0159 g/cm3 (25 °C) 1.083 g/cm3 (20 °C) Auto-ignition temperature : approximately 460 °C Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. 9.2 Other information No data available SECTION 10: Stability and reactivity 10.1 Reactivity See section "Possibility of hazardous reactions". 10.2 Chemical stability Stable under normal conditions. 10.3 Possibility of hazardous reactions Hazardous reactions : Corrosive in contact with metals 10.4 Conditions to avoid Conditions to avoid : No decomposition if used as directed. 10.5 Incompatible materials Materials to avoid : Aluminium Mild steel Iron 10.6 Hazardous decomposition products Combustion or thermal decomposition will evolve toxic and irritant vapours. SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Product: Acute oral toxicity : LD50 (Rat, female): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat, male and female): > 5.33 mg/l Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rat, male and female): > 5,000 mg/kg Components: mandipropamid (ISO): Acute oral toxicity : LD50 (Rat, female): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat, male and female): > 5.19 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rat, male and female): > 5,050 mg/kg oxathiapiprolin: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat, male and female): > 5.1 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rat, male and female): > 5,000 mg/kg 1,2-benzisothiazol-3(2H)-one: Acute oral toxicity : Assessment: The component/mixture is moderately toxic after single ingestion. bronopol (INN): Acute oral toxicity : Assessment: The component/mixture is moderately toxic after single ingestion. Acute toxicity estimate: 500 mg/kg Method: Converted acute toxicity point estimate Acute dermal toxicity : Assessment: The component/mixture is moderately toxic after single contact with skin. Acute toxicity estimate: 1,100 mg/kg Method: Converted acute toxicity point estimate Skin corrosion/irritation