Black Liquor (Kraft)

Hazard statements (CLP)

H290, H302, H314, H317, H318, H335, H400, H411

Code

Statements

H290

May be corrosive to metals

SECTION 2: Hazards identification

Classification of the Substance or Mixture GHS-US/CA Classification Met. Corr. 1 H290 Acute Tox. 4 (Oral) H302 Skin Corr. 1 H314 Eye Dam. 1 H318 Skin Sens. 1 H317 STOT SE 3 H335 Aquatic Acute 1 H400 Aquatic Chronic 2 H411

Hazard statements

see section 16 : H290 - May be corrosive to metals. H302 - Harmful if swallowed. H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. H318 - Causes serious eye damage. H335 - May cause respiratory irritation. H400 - Very toxic to aquatic life. H411 - Toxic to aquatic life with long lasting effects.

2.2 Label elements

GHS-US/CA Labeling

Hazard pictograms

GHS05 GHS07 GHS09

Signal word

Danger

Precautionary statements

P234 - Keep only in original container. P260 - Do not breathe vapors, mist, or spray. P264 - Wash hands, forearms, and other exposed areas thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, and eye protection. P301+P312 - IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell. P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water . P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER or doctor. P321 - Specific treatment (see section 4 on this SDS). P330 - Rinse mouth. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P390 - Absorb spillage to prevent material-damage. P391 - Collect spillage. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P406 - Store in corrosive resistant container with a resistant inner liner. P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations.

Other hazards

Exposure may aggravate pre-existing eye, skin, or respiratory conditions. May be corrosive to respiratory tract. NEVER pour water into this substance; when dissolving or diluting always add it slowly to the water. Reacts with acids to form Hydrogen sulfide, sulfur oxides, and metal oxides. Hydrogen sulfide and sulfur oxides are both highly toxic gases that can be fatal in high enough concentrations.

Ingredient(s) with unknown acute toxicity

No additional information available

2.1 Classification of the substance or mixture

GHS-US/CA Classification Met. Corr. 1 H290 Acute Tox. 4 (Oral) H302 Skin Corr. 1 H314 Eye Dam. 1 H318 Skin Sens. 1 H317 STOT SE 3 H335 Aquatic Acute 1 H400 Aquatic Chronic 2 H411 Full text of hazard classes and H-statements : see section 16