SCT-22 (part A)

Hazard statements (CLP)

H227, H304, H312, H315, H317, H318, H320, H332, H334, H335, H351, H373, H401, H402, H411, H412

Code

Statements

H227

Combustible liquid

OSHA HCS Classification

Acute toxicity, inhalation mist (Category 4) H332 Serious eye damage/eye irritation (Category 2B) H318 Skin corrosion/irritation (Category 2) H312 Skin sensitization (Category 1B) H317 Respiratory sensitization (Category 1) H334 Carcinogenicity (Category 2) H351 Specific target organ toxicity, single exposure (Category 3 respiratory tract irritation) H373 Specific target organ toxicity, repeated exposure (Category 2 respiratory tract irritation) H373 Hazardous to the aquatic environment, acute hazard (Category 3) H401 Hazardous to the aquatic environment, chronic hazard (Category 3) H411 Flammable liquids (Category 4) H227

Signal word

Danger Label Hazard Statements H227: Combustible liquid. H320: Causes eye irritation H315: Causes skin irritation. H332: Harmful if inhaled 2 H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317: May cause an allergic skin reaction. H335: May cause respiratory irritation. H351: Suspected of causing cancer. H373: May cause damage to organs through prolonged or repeated exposure. H402: Harmful to aquatic life. H412: Harmful to aquatic life with long-lasting effects. H304: May be fatal if swallowed and enters airways. Label Precautionary statements P280: Wear protective gloves/protective clothing/eye protection/face protection. P271: Use only outdoors or in a well-ventilated area. P260: Do not breathe dust/fume/gas/mist/vapors/ spray. P202: Do not handle until all safety precautions have been read and understood. P284: [In case of inadequate ventilation] wear respiratory protection. P272: Contaminated work clothing should not be allowed out of the workplace. P264: Wash skin thoroughly after handling. P273: Avoid release to the environment. P210: Keep away from heat/sparks/open flames/hot surfaces. -- No smoking. P201: Obtain special instructions before use. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses if pre- sent and easy to do. Continue rinsing. P304 + P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P308 + P311 IF exposed or concerned Call a POISON CENTER/ doctor P314: Get Medical advice/attention if you feel unwell. P302 + P352 IF ON SKIN Wash with plenty of water P333 + P313 If skin irritation or a rash occurs Get medical advice/attention P362 + P364: Take off contaminated clothing and wash it before reuse. P332+313 If skin irritation occurs Get medical advice/attention P337 + P311: If eye irritation persists get medical advice/attention. P370 + P378 In case of fire Use water spray, dry powder, carbon dioxide, foam to extinguish P403 + P233: Store in a well ventilated place. Keep container tightly closed P405: Store locked up. P501: Dispose of contents and container in accordance with local regulations.

2.3 Other hazards

No specific dangers known, if the regulations/notes for storage and handling are considered. Labeling of special preparations (GHS):

Contains

Isocyanates. Inhalation of isocyanate mists or vapors may cause respiratory irritation, breathlessness, chest discomfort and reduced pulmonary function. Overexposure well above established limits may result in bronchitis, bron- chial spasms and pulmonary edema. Long-term exposure to isocyanates has been reported to cause lung damage, in- cluding reduced lung function which may be permanent. Acute or chronic overexposure to isocyanates may cause sensi- tization in some individuals, resulting in allergic respiratory reactions including wheezing, shortness of breath and diffi- culty breathing. Animal tests indicate that skin contact may play a role in causing respiratory sensitization. Emergency Overview 3 Danger Combustible Liquid. Contains isocyanates. Inhalation of isocyanate mists or vapors may cause respiratory irrita- tion, breathlessness, chest discomfort and reduced pulmonary function. Overexposure well above the PEL may result in bronchitis, bronchial spasms and pulmonary edema. Long-term exposure to isocyanates has been reported to cause lung damage, including reduced lung function which may be permanent. Acute or chronic overexposure to isocyanates may cause sensitization in some individuals, resulting in allergic respiratory reactions including wheezing, shortness of breath and difficulty breathing. Animal tests indicate that skin contact may play a role in causing respiratory sensitization. Avoid contact with skin and eyes. Harmful to aquatic organisms, may cause long0term adverse effects in the aquatic environment. FLAMMABLE LIQUID