KEROSENE 1-K UNDYED

Hazard statements (CLP)

H226, H304, H315, H336, H411

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

OSHA Hazards GHS Classification Flammable Liquids – Category 3 H226

Aspiration hazard

Category 1 H304 Skin corrosion/irritation- Category 2 H315 Specific target organ toxicity (single exposure) - Category 3 H336 Hazardous to the aquatic environment, chronic toxicity- Category 2 H411

Signal word

Danger Flammable liquid and vapor. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Causes skin irritation. Toxic to aquatic life with long lasting effects.

Precautionary statements

Keep away from/heat/sparks/open flames-hot surfaces. No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist/vapors/spray. Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Avoid release into the environment. Wear protective gloves/protective clothing and eye/face protection. IF SWALLOWED: immediately call a POISON CENTER or doctor/physician. Do not induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical or foam for extinction. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Dispose of contents/container to an approved waste disposal plant. R00000005800, KEROSENE 1-K UNDYED 1

Hazard pictograms

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2.3 Other hazards

Vapors may cause flash fire or explosion. Static accumulator. May form an ignitable vapor/air mixture. Ratings Key: 0 = least, 1 = slight, 2 = moderate, 3 = high, 4 = extreme Health Fire Reactivity PPI NFPA 2 0 HMIS 2 0 X 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS No. Amount (Vol%) HYDRODESULFURIZED KEROSENE 64742-81-0 99 - 100 NAPHTHALENE 91-20-3 0 - 3 XYLENE 1330-20-7 0 - 0.9 TOLUENE 108-88-3 0 - 0.3 ETHYL BENZENE 100-41-4 0 - 0.2 N-HEXANE 110-54-3 0 - 0.1 BENZENE 71-43-2 0 - 0.07 CUMENE 98-82-8 0 - 0.07 PROPRIETARY ADDITIVES 0 - 0.01 4. FIRST AID MEASURES • INHALATION Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and continue to monitor. Get immediate medical attention. • SKIN Wash with soap and water for 20 minutes. Get medical attention if irritation develops or persists. Wash clothing before reuse. • EYES Flush eye with water for 20 minutes. Get medical attention. • INGESTION Do not induce vomiting! Do not give liquids! Get medical attention immediately. 5. FIRE FIGHTING MEASURES • EXTINGUISHING MEDIA Regular foam; Dry chemical; Carbon dioxide; Water may be ineffective. Carbon dioxide can displace oxygen in confined spaces. • FIRE FIGHTING INSTRUCTIONS Use water spray to cool fire exposed tanks and containers. Wear structural fire fighting gear. The use of fresh air equipment such as Self Contained Breathing Apparatus (SCBA) or Supplied Air Respirators should be worn for fire fighting if exposure or potential exposure to products of combustion is expected. FLAMMABLE PROPERTIES Flammable. This material can be ignited by heat, sparks or open flames or other sources of ignition (e.g., static electricity, pilot lights, mechanical/electrical equipment, electronic devices such as cell phones, computers, calculators). Vapors may travel considerable distances to a source of ignition where they can ignite, flash back or R00000005800, KEROSENE 1-K UNDYED 2 explode. May create vapor/air explosions hazard indoors, confined spaces, outdoors or in sewers. This product will float and can be reignited on surface water. Vapors are heavier than air and can accumulate in low areas. If container is not properly cooled, it can ruptured in the heat of fire. HAZARDOUS COMBUSTION PRODUCTS: Combustion may yield smoke, carbon monoxide, and other products of incomplete combustion. Oxides of nitrogen and sulfur may also be formed. 6. ACCIDENTAL RELEASE MEASURES Prevent ignition, stop leak and ventilate the area. Spillages of liquid product will create a fire hazard and may form an explosive atmosphere. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Use appropriate personal protective equipment as stated in Section 8 of this MSDS. Advise the Environmental Protection Agency (EPA) and appropriate state agencies, if required. Absorb spill with inert material (e.g., dry sand or earth), then place in a chemical waste container. Vacuum or sweep up material and place in a disposal container. Use explosion-proof electrical equipment. 7. HANDLING AND STORAGE • HANDLING Follow all MSDS/label precautions even after container is emptied because it may retain product residue. Use only in a well-ventilated area. STATIC ACCUMULATOR. This liquid may form an ignitable vapor-air mixture in closed tanks or containers. This liquid may accumulate static electricity even when transferred into properly grounded containers. Bonding and grounding may be insufficient to remove static electricity. Static electricity accumulation may be significantly increased by the presence of small quantities of water. Always bond receiving container to the fill pipe before and during loading, following NFPA-77 and/or API RP 2003 requirements. Automatic gauging devices and other floats in vessels or tanks which contain static accumulating liquids should be electrically bonded to the shell. Bonding and grounding alone may be inadequate to eliminate fire and explosion hazards associated with electrostatic charges. In addition to bonding and grounding, efforts to mitigate the hazards of an electrostatic discharge may include, but are not limited to, ventilation, inerting and/or reduction of transfer velocities. Always keep the nozzle in contact with the container throughout the loading process. Do not fill any portable containers in or on a vehicle. Special precautions, such as reduced loading rates and increased monitoring, must be observed during "switch loading" operations (i.e. loading this material in tanks or shipping compartments that previously contained middle distillates or similar products). Non-equilibrium conditions may increase the risks associated with static electricity such as tank and container filling, tank cleaning, sampling, gauging, loading, filtering, mixing, agitation, etc. Dissipation of electrostatic charges may be improved with the use of conductivity additives when used with other mitigating efforts, including bonding and grounding. Avoid breathing (dust, vapor, mist, gas). Avoid prolonged or repeated contact with skin. Avoid contact with eyes. Wash thoroughly after handling. Never siphon by mouth. "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty drums should be completely drained, properly bunged, and promptly returned to a drum reconditioned, or properly disposed of.

Storage

Keep away from heat, sparks, and flame. Keep container closed when not in use. Store in a cool place in original container and protect from sunlight. Outside or detached storage is preferred. NFPA class II storage. Flash point is greater than 100 degrees F and less than 140 degrees F. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Consult With a Health and Safety Professional for Specific Selections • ENGINEERING CONTROLS Use with adequate ventilation. Mechanical ventilation recommended. Good general ventilation should be sufficient to control airborne levels. • PERSONAL PROTECTION  EYE PROTECTION Splash proof chemical goggles are recommended to protect against the splash of product. R00000005800, KEROSENE 1-K UNDYED 3  GLOVES or HAND PROTECTION The glove(s) listed below may provide protection against permeation. Gloves of other chemically resistant materials may not provide adequate protection. Protective gloves are recommended to protect against contact with product. Polyvinyl chloride (PVC); Neoprene; Nitrile; Polyvinyl alcohol; Viton; Polyethylene;  RESPIRATORY PROTECTION Concentration in air determines the level of respiratory protection needed. Use only NIOSH certified respiratory equipment. Half-mask air purifying respirator with organic vapor cartridges is acceptable for exposures to ten (10) times the exposure limit. Full-face air purifying respirator with organic vapor cartridges is acceptable for exposures to fifty (50) times the exposure limit. Exposure should not exceed the cartridge limit of 1000 ppm. Protection by air purifying respirators is limited. Use a positive pressure-demand full-face supplied air respirator or SCBA for exposures greater than fifty (50) times the exposure limit. If exposure is above the IDLH (Immediately Dangerous to Life and Health) or there is the possibility of an uncontrolled release, or exposure levels are unknown, then use a positive pressure-demand full-face supplied air respirator with escape bottle or SCBA. Wear a NIOSH-approved (or equivalent) full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.  OTHER Where splashing is possible, full chemically resistant protective clothing and boots are required. The following materials are acceptable for use as protective clothing: Polyvinyl alcohol (PVA); Polyvinyl chloride (PVC); Neoprene; Nitrile; Viton. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Remove contaminated clothing and wash before reuse. For non-fire emergencies, positive pressure SCBA and structural firefighter's protective clothing will provide only limited protection. EXPOSURE GUIDELINES CAS No. Governing Body Exposure Limits Limit for the product ACGIH TLV 30 ppm BENZENE 71-43-2 ACGIH STEL 2.5 ppm BENZENE

Potential health effects

 INHALATION High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis and loss of consciousness and even death). High vapor concentrations are irritating to the eyes, nose, throat, and lungs. Intentional misuse (sniffing) can cause damage to the brain, liver and kidneys and may cause sudden death.  SKIN CORROSION/IRRITATION Practically non-toxic if absorbed through the skin. Moderately irritating to the skin. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Contains a material that has caused skin tumors in laboratory animals.  SERIOUS EYE DAMAGE AND IRRITATION Mildly irritating to the eyes. Contact with the eye may cause redness, burning, tearing and/or blurred vision.  INGESTION Pulmonary aspiration hazard. May be fatal if swallowed and enter airways. While ingesting or vomiting, may enter lungs and produce damage.  SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): May cause drowsiness and dizziness.  PRE-EXISTING MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE The following diseases or disorders may be aggravated by exposure to this product: skin, eye, nervous system, respiratory system, lung (asthma-like conditions), Additional Toxicology Information Dermal exposure to middle distillates have caused skin irritation and skin cancer in laboratory animals when repeatedly applied and left in place between applications. Studies to further evaluate the carcinogenic potential of middle distillates are currently underway. Component Toxicity Information Cumene may be harmful or fatal if swallowed. Pulmonary aspiration hazard. After ingestion, may enter lungs and cause damage. May cause respiratory irritation, fluid in the lungs and lung damage. May be irritating to the skin and eyes. May cause nervous system effects, including drowsiness, dizziness, coma and even death. Overexposure has caused kidney, nose, and liver damage in laboratory animals. Following inhalation exposure, an increased tumor incidence has been observed in experimental animals. The significance of this finding to human health is presently unknown. Overexposure to naphthalene, a minor component of this product, may cause skin, eye and respiratory tract irritation, anemia, loss of vision, nervous system effects and kidney and thymus damage. Naphthalene has been evaluated in two year inhalation studies in both rats and mice. The US National Toxicology Program concluded that there is clear evidence of carcinogenicity in male and female rats based on increased incidences of respiratory epithelial adenomas and olfactory epithelial neuroblastomas of the nose. NTP found some evidence of carcinogenicity in female mice (alveolar adenomas) and no evidence of carcinogenicity in male mice.

ECOLOGICAL INFORMATION

Toxic to aquatic life with long lasting effects. Persistence and Degradability: The hydrocarbons in this material are not readily biodegradable but are regarded as inherently biodegradable since their hydrocarbon components can be degraded by microorganisms. Bioaccumulative Potential: Hydrocarbon constituents of kerosene show measured or predicted Log Kow values ranges from 3 to 6 and above and therefore would be regarded as having the potential to bioaccumulate. In practice, metabolic processes may reduce bioconcentration. Mobility in Soil: On release to water, hydrocarbons will float on the surface and since they are sparingly soluble, the only significant loss is to volatilization to air. It is possible that some of the higher hydrocarbons will be absorbed on sediment. Biodegradation in water is a minor loss process. In air, these hydrocarbons are photodegraded by reaction with hydroxyl radicals with half-lives varying from 0.1 to 0.7 days. R00000005800, KEROSENE 1-K UNDYED 6 13. DISPOSAL CONSIDERATIONS Follow federal, state and local regulations. This material is a RCRA hazardous waste. Do not flush material to drain or storm sewer. Contract to authorized disposal service. 14. TRANSPORT INFORMATION Governing Body Mode Proper Shipping Name DOT Ground Kerosene Governing Body Mode

Hazard categories

UN/NA No. Label DOT Ground 3 (Flammable 1223 liquid) 15. REGULATORY INFORMATION

Further information

Follow all MSDS/label precautions even after container is emptied because it may retain product residue. Email Address: For MSDS requests/information please contact sunocomsds@sunocoinc.com R00000005800, KEROSENE 1-K UNDYED 11 GREER LIME COMPANY - MATERIAL SAFETY DATA SHEET

Health hazards

Information Routes of Entry Inhalation? Absorption Through Skin? Ingestion (Swallowing)? YES Acute Corrosive to skin and eyes. Causes irritation and inflammation to mucus membranes and respiratory passages. Long-term exposure can cause irritation, ulceration, and Chronic perforation of nasal septum. Carcinogenicity NTP? IARC Monographs?

Medical Conditions Generally Aggravated by Exposure

Respiratory Disease, Skin Conditions

2.1 Classification of the substance or mixture

Flammable Liquids – Category 3 H226 Aspiration hazard – Category 1 H304 Skin corrosion/irritation- Category 2 H315 Specific target organ toxicity (single exposure) - Category 3 H336 Hazardous to the aquatic environment, chronic toxicity- Category 2 H411