SDS-001

Sunnen Products

Revision date : 2015-06-02

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Health risk rating
Safety risk rating
Environmental risk rating

Note: Ingredients listed on restricted chemical lists

EC/CAS

7440-66-6

Name of the chemical

Zinc

Concentration

0.139 - 0.908

EC/CAS

7440-50-8

Name of the chemical

Copper

Concentration

N/A

EC/CAS

7429-90-5

Name of the chemical

Aluminium

Concentration

N/A

EC/CAS

7440-02-0

Name of the chemical

Nickel

Concentration

<1%

EC/CAS

7440-47-3

Name of the chemical

Chromium; chromic acid and its salts

Concentration

N/A

EC/CAS

7440-48-4

Name of the chemical

Cobalt, Metall (2020/217)

Concentration

N/A

EC/CAS

7440-21-3

Name of the chemical

Silicon

Concentration

<3%

Listed in

EC/CAS

13598-36-2

Name of the chemical

Phosphonic acid

Concentration

<1.5%

Listed in

General Information

Revision date

2015-06-02

Product name

SDS-001

1.2.1 Relevant identified uses

Tooling used in the honing process

supplier name

Sunnen Products

Emergency telephone

1 (314) 781-2100 8 a.m.-3p.m. C.S.T (US

Icons in SDS

Company Information

company name

Sunnen Products

e-mail address of the competent person responsible for the Safety Data Sheet

SDS@sunnen.com

GHS Information

Signal word

Danger

Section 2

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Downstream use of this product, results in hazardous elements being emitted under certain processing conditions such as but not limited to: abrading, cutting, welding, sanding, burning, milling or grinding. The classifications given below pertains to when used during these processes. Sensitization T Toxi

Signal word

Danger WPS-SUN-003 - GUIDE SHOE, MANDREL, TRUING SLEEVE, ALIGNMENT Revision Date: 2-Jun-2015 BUSHING Copper (metallic) 7440-50-8 0-85 * Aluminum 7429-90-5 0-12 * Nickel 7440-02-0 0-3 * Manganese 7439-96-5 0-2 F Chromium 1440-47-3 0-2 - Cobalt 7440-48-4 <1.5 * Vanadium 7440-62-2 0-1 * Sulfur 7704-34-9 0-1 * Silicon 7440-21-3 0-1 * Phosphorous acid 13598-36-2 0-1 * Molybdenum 7439-98-7 0-1 7 *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of necessary first-aid measures General Advice If exposed or concerned: Get medical attention/advice Eye Contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Skin Contact Wash skin with soap and water. If skin irritation or rash occurs: Get medical advice/attention. Contaminated clothing presents a fire hazard and should be removed immediately. Inhalation IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Ingestion Call a POISON CENTER or doctor/physician if exposed or you feel unwell. Most important symptoms/effects, acute and delayed Most Important Symptoms/Effects Asthma-like and/ or skin allergy-like symptoms. Difficulty in breathing. Coughing and/ or wheezing. Rashes Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician May cause sensitization of susceptible persons. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media None Specific Hazards Arising from the Chemical None known Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures WPS-SUN-003 - GUIDE SHOE, MANDREL, TRUING SLEEVE, ALIGNMENT Revision Date: 2-Jun-2015 BUSHING Silicon TWA: 15 mg/m? total dust TWA: 10 mg/m? total dust 7440-21-3 TWA: 5 mg/m? respirable fraction TWA: 5 mg/m? respirable dust (vacated) TWA: 10 mg/m? total dust (vacated) TWA: 5 mg/m3 respirable fraction Molybdenum TWA: 10 mg/m® inhalable (vacated) TWA: 10 mg/m? IDLH: 5000 mg/m? 7439-98-7 fraction TWA: 3 mg/m? respirable fraction Vanadium (vacated) TWA: 0.05 mg/m4 Ceiling: 0.05 mg/m? V dust and 7440-62-2 V205 respirable dust fume 15 min (vacated) TWA: 0.05 mg/m? TWA: 1 mg/m? V205 fume STEL: 3mg/m? = Ferrovanadium Ceiling: 0.5 mg/m’ V205 dust respirable dust Ceiling: 0.1 mg/m? V205 fume Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection Always wear approved safety glasses with side shields when operating machinery. Skin and Body Protection Wear protective gloves/clothing. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. = 9. PHYSICAL AND CHEMICAL PROPERTIES zi Information on basic physical and chemical properties Physical State Appearance Various shades Black Silver Brass Odor No information available Odor Threshold No information available Property Values Remarks/ - Method pH Not applicable None known Melting Point/Range Not applicable None known Boiling Point/Boiling Range Not applicable None known Flash Point Not applicable. None known Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air upper flammability limit No data available lower flammability limit No data available Vapor Pressure No data available None known Vapor Density No data available None known Specific Gravity None known Water Solubility Not applicable None known Solubility in other solvents Not applicable None known Partition coefficient: n-octanol/waterNo data available None known Autoignition Temperature No data available None known Decomposition Temperature No data available None known Viscosity Not applicable None known Flammable Properties Not flammable Explosive Properties No data available Oxidizing Properties No data available WPS-SUN-003 - GUIDE SHOE, MANDREL, TRUING SLEEVE, ALIGNMENT Revision Date 2-Jun-2015 BUSHING Chemical Name ACGIH IARC NTP OSHA Nickel Group 2B Reasonably Anticipated Xx Chromium Group 3 Cobalt A3 Group 2B Reasonably Anticipated X ACGIH: (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC: (international Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans Group 3: Not Classifiable as to its Carcinogenicity to Humans NTP: (National Toxicity Program) Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen OSHA: (Occupational Safety & Health Administration) X - Present Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure if inhaled Aspiration Hazard No information available. Numerical measures of toxicity - Product The following values are calculated based on chapter 3.1 of the GHS document: Not applicable 12. ECOLOGICAL INFORMATION ml Ecotoxicity Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Daphnia Magna (Water Microorganisms Flea) Iron - LC50 96 h: = 0.56 mg/L - 7439-89-6 semi-static (Cyprinus carpio) LC50 96 h: = 13.6 mg/L static (Morone saxatilis) Zinc EC50 72h: 0.09 -0.125 LC50 96 h: 0.211-0.269 EC50 48h: 0.139 - 0.908 7440-66-6 mg/L static mg/L semi-static mg/L Static (Daphnia (Pseudokirchneriella (Pimephales promelas) magna) subcapitata) LC50 96 h: 2.16-3.05 mg/L EC50 96h: 0.14 - 0.271 flow-through (Pimephales mg/L static promelas) (Pseudokirchneriella LC50 96 h: = 0.24 mg/L subcapitata) flow-through (Oncorhynchus mykiss) LC50 96 h: = 0.41 mg/L static (Oncorhynchus mykiss) LC50 96 h: = 0.45 mg/L semi-static (Cyprinus carpio) LC50 96 h: = 0.59 mg/L semi-static (Oncorhynchus mykiss) LC50 96 h: = 2.66 mg/L static (Pimephales promelas) LC50 96 h: = 3.5 mg/L static (Lepomis macrochirus) LC50 96 h: = 30 mg/L (Cyprinus carpio) LC50 96 h: = 7.8 mg/L static (Cyprinus carpio) Page 7/10 WPS-SUN-003 - GUIDE SHOE, MANDREL, TRUING SLEEVE, ALIGNMENT Revision Date 2-Jun-2015 BUSHING DOT Not regulated TDG Not regulated MEX Not regulated Ex 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL Complies Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. Chemical Name CAS-No Weight % SARA 313 - Threshold Values % Zinc 7440-66-6 96 1.0 Copper 7440-50-8 85 1.0 Aluminum 7429-90-5 12 1.0 Nickel 7440-02-0 3 0.1 Chromium 7440-47-3 2 1.0 Cobalt 7440-48-4 1.5 0.1 Vanadium 7440-62-2 1 1.0 SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42): Chemical Name CWA - Reportable CWA - Toxic Pollutants | CWA - Priority Pollutants CWA - Hazardous Quantities

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