BIOMATE MBC781

Hazard statements (CLP)

H314, H317, H410

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Regulation (EC) No 1272/2008 as amended Health hazards Skin corrosion/irritation Category 1C H314 - Causes severe skin burns and eye damage. Serious eye damage/eye irritation Category 1 H318 - Causes serious eye damage. Skin sensitisation Category 1A H317 - May cause an allergic skin reaction. Environmental hazards Hazardous to the aquatic environment, acute Category 1 H400 - Very toxic to aquatic life. aquatic hazard Hazardous to the aquatic environment, Category 1 H410 - Very toxic to aquatic life long-term aquatic hazard with long lasting effects. Hazard summary Causes severe skin burns and eye damage. May cause an allergic skin reaction. Dangerous for the environment if discharged into watercourses. 2.2. Label elements Label according to Regulation (EC) No. 1272/2008 as amended Contains: Reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1) (CAS 55965-84-9) (15,5 g/l) Hazard pictograms Signal word Danger Hazard statements H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements Prevention P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. Response P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE/doctor. Storage Not available. Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Supplemental label information EUH071 - Corrosive to the respiratory tract. 2.3. Other hazards This mixture does not contain substances assessed to be vPvB / PBT according to Regulation (EC) No 1907/2006, Annex XIII. The product does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. SECTION 3: Composition/information on ingredients Mixtures Chemical description Isothiazolinone in aqueous solution Chemical name % CAS-No. / EC No. REACH Registration No. Index No. Notes Reaction mass of 1 - < 3 55965-84-9 - 613-167-00-5 5-chloro-2-methyl-2H-isothiazol-3-one - and 2-methyl-2H-isothiazol-3-one (3:1) Classification: Acute Tox. 3;H301, Acute Tox. 2;H310, Acute Tox. 2;H330, Skin Corr. 1C;H314, Eye Dam. 1;H318, Skin Sens. 1A;H317, Aquatic Acute 1;H400(M=100), Aquatic Chronic 1;H410(M=100) Cupric nitrate < 0,2 3251-23-8 01-2119969290-34 - 221-838-5 Classification: Ox. Sol. 1;H271, Met. Corr. 1;H290, Skin Corr. 1B;H314, Eye Dam. 1;H318, Aquatic Acute 1;H400(M=10), Aquatic Chronic 1;H410(M=1) Material name: BIOMATE MBC781 List of abbreviations and symbols that may be used above ATE: Acute toxicity estimate. M: M-factor PBT: persistent, bioaccumulative and toxic substance. vPvB: very persistent and very bioaccumulative substance. All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. #: This substance has been assigned Union workplace exposure limit(s). The full text for all H-statements is displayed in section 16. SECTION 4: First aid measures General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. 4.1. Description of first aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Call a physician or poison control centre immediately. Chemical burns must be treated by a physician. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control centre immediately. Ingestion Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Call a physician or poison control centre immediately. 4.2. Most important symptoms Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may and effects, both acute and include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including delayed blindness could result. 4.3. Indication of any Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water immediate medical attention immediately. While flushing, remove clothes which do not adhere to affected area. Call an and special treatment needed ambulance. Continue flushing during transport to hospital. Keep victim under observation. Symptoms may be delayed. SECTION 5: Firefighting measures General fire hazards No unusual fire or explosion hazards noted. 5.1. Extinguishing media Suitable extinguishing Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). media Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media 5.2. Special hazards arising During fire, gases hazardous to health may be formed. from the substance or mixture 5.3. Advice for firefighters Special protective Self-contained breathing apparatus and full protective clothing must be worn in case of fire. equipment for firefighters Special fire fighting Move containers from fire area if you can do so without risk. Prevent spillage and fire-fighting water procedures from entering in public sewers or the immediate environment. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist/vapours. personnel Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. It is possible to pass or work near the treated system during product application. For emergency responders Keep unnecessary personnel away. Avoid breathing mist/vapours. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. Use personal protection recommended in Section 8 of the SDS. 6.2. Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Transport and store in approved containers according to applicable national and international regulations. Material name: BIOMATE MBC781 6.3. Methods and material for Keep spills and clean-up residuals out of municipal sewers and open bodies of water. containment and cleaning up Absorb the spill with spill pillows or inert solids such as clay or vermiculite. Transfer contaminated materials to suitable containers for disposal. Deactivate spill area with freshly prepared solution of 5% sodium bicarbonate and 5% sodium hypochlorite in water. Apply solution to the spill area at a ratio of 10 volumes deactivation solution per estimated volume of residual spill to deactivate any residual active ingredient. Let stand for 30 minutes. Flush the spill area with copious amounts of water to chemical sewer in accordance with local procedures, permits and regulations. DO NOT add deactivation solution to the waste pail to deactivate the adsorbed material. Prevent entry into waterways, sewer, basements or confined areas. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. 6.4. Reference to other For personal protection, see section 8 of the SDS. For waste disposal, see section 13 of the SDS. sections SECTION 7: Handling and storage 7.1. Precautions for safe Do not breathe mist/vapours. Do not get in eyes, on skin, or on clothing. Provide adequate handling ventilation. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. 7.2. Conditions for safe Store locked up. Store in tightly closed container. Store away from incompatible materials (see storage, including any Section 10 of the SDS). Store containers closed when not in use, away from extreme temperatures incompatibilities . Product evolves carbon dioxide gas slowly. Store upright in original vented container. Store samples in plastic bottles only. No more then 6 months pressure build-up may rupture glass bottles. 7.3. Specific end use(s) Only for industrial users The material which has been in contact with this product can be cleaned with water. Product is especially designed for the cleaning and disinfection by applying, soaking or circulating of a diluted aqueous solution. The minimum contact time is: 12 hours. Proper treatment levels and frequency of addition should be determined by a study of the normalised system performance and depend on many factors, such as water quality, microbial species, biological activity in the water streams, and conditions particular for a given installation. The product should be used in accordance with control procedures that SUEZ Water Technologies & Solutions establishes for a specific application. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). Recommended monitoring Follow standard monitoring procedures. procedures Derived no effect levels Not available. (DNELs) Predicted no effect concentrations (PNECs) Components Value Assessment factor Notes Cupric nitrate (CAS 3251-23-8) Freshwater 7,8 µg/l 1 Marine water 5,2 µg/l 1 Sediment (freshwater) 87 mg/kg 1 Sediment (marine water) 676 mg/kg 1 Soil 65 mg/kg 1 STP 230 µg/l 1 Material name: BIOMATE MBC781 8.2. Exposure controls Appropriate engineering Good general ventilation should be used. Ventilation rates should be matched to conditions. If controls applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment General information Use personal protective equipment as required. Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield. Face shield is recommended . CEN : EN 166 Skin protection - Hand protection For prolonged or repeated skin contact use suitable protective gloves. Suitable gloves can be recommended by the glove supplier. Full shoulder length butyl gloves (Protection against unintentional short-term contact) Full shoulder length neoprene gloves (Protection against unintentional short-term contact) Full shoulder length nitrile gloves (Protection against unintentional short-term contact) Penetration time: > 480 min Coating thickness: 0.5 mm CEN : EN 374-1/2/3/4; EN 420 - Other Wear appropriate chemical resistant clothing. Chemical resistant clothing that ensures full coverage of the hands, arms and body. Rubber boots. CEN : EN ISO 13688; EN ISO 6530; EN ISO 6529; EN 14605 Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. In case of insufficient ventilation, use a breathing mask with filter type: A2 E2-P CEN : EN 140; EN 14387 Thermal hazards Wear appropriate thermal protective clothing, when necessary. Hygiene measures Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. Environmental exposure Inform appropriate managerial or supervisory personnel of all environmental releases. Emissions controls from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Fume scrubbers, filters or engineering modifications to the process equipment may be necessary to reduce emissions to acceptable levels. Do not empty into drains, dispose of this material and its container to hazardous or special waste collection point. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Colour Yellow to blue-green Physical state Liquid Odour Slight Odour threshold Not available. pH (concentrated product) 3 pH in aqueous solution 4 (5% SOL.) Melting point/freezing point -2 °C Initial boiling point and boiling 104 °C range Flash point Not available. Evaporation rate < 1 (Ether = 1) Flammability (solid, gas) Not applicable. Material name: BIOMATE MBC781 Upper/lower flammability or explosive limits Explosive limit - lower ( %) Not available. Explosive limit – upper Not available. (%) Vapour pressure 18 mm Hg / 2,4 kPa Vapour pressure temp. 21 °C Vapour density < 1 (Air = 1) Relative density 1,03 Relative density temperature 21 °C Solubility Solubility (water) 100 % Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity 8 cps Viscosity temperature 21 °C Explosive properties Not explosive. Oxidising properties Not oxidising. Kinematic viscosity Not available. Particle characteristics Not available. 9.2. Other information Pour point 1 °C Shelf life 360 days Specific gravity 1,03 VOC 0 % (Calculated) SECTION 10: Stability and reactivity 10.1. Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2. Chemical stability Material is stable under normal conditions. 10.3. Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions 10.4. Conditions to avoid Do not freeze. 10.5. Incompatible materials Strong oxidising agents. Strong reducing agents. 10.6. Hazardous Hydrogen chloride. Carbon oxides. Nitrogen oxides (NOx). Sulphur oxides. decomposition products SECTION 11: Toxicological information General information Occupational exposure to the substance or mixture may cause adverse effects. Information on likely routes of exposure

Health hazards

Skin corrosion/irritation Category 1C H314 - Causes severe skin burns and eye damage. Serious eye damage/eye irritation Category 1 H318 - Causes serious eye damage. Skin sensitisation Category 1A H317 - May cause an allergic skin reaction.

Environmental hazards

Hazardous to the aquatic environment, acute Category 1 H400 - Very toxic to aquatic life aquatic hazard Hazardous to the aquatic environment, Category 1 H410 - Very toxic to aquatic life long-term aquatic hazard with long lasting effects. Hazard summary Causes severe skin burns and eye damage. May cause an allergic skin reaction. Dangerous for the environment if discharged into watercourses.

Contains

Reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1) (CAS 55965-84-9) (15,5 g/l)

Signal word

Danger

Hazard statements

H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE/doctor.

Storage

Not available.

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

Supplemental label elements

EUH071 - Corrosive to the respiratory tract.

2.3 Other hazards

This mixture does not contain substances assessed to be vPvB / PBT according to Regulation