Methyllithium, complexed with lithium bromide in ethyl ether (1.5M)

Strem Chemicals, Inc

Revision date : 2021-07-19

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GHS02 GHS05 GHS07
Health risk rating 3
Safety risk rating 4
Environmental risk rating 1

General Information

Revision date

2021-07-19

Product name

Methyllithium, complexed with lithium bromide in ethyl ether (1.5M)

Emergency telephone

+ 1 (800) 424-9300

Icons in SDS

Company Information

company name

Strem Chemicals, Inc

e-mail address of the competent person responsible for the Safety Data Sheet

info@strem.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H224, H250, H252, H260, H302, H315, H318, H336

Hazard statements

Code

Statements

H224

Extremely flammable liquid and vapour

Section 2

2.1 Classification of the substance or mixture

d ~  GHS02 Flame Flam. Liq. 1 H224 Extremely flammable liquid and vapor. Pyr. Liq. 1 H250 Catches fire spontaneously if exposed to air. Self-heat. 2 H252 Self-heating in large quantities; may catch fire. Water-react. 1 H260 In contact with water releases flammable gases, which may ignite spontaneously. d ~  GHS05 Corrosion Eye Dam. 1 H318 Causes serious eye damage. d ~  GHS07 Acute Tox. 4 H302 Harmful if swallowed. Skin Irrit. 2 H315 Causes skin irritation. STOT SE 3 H336 May cause drowsiness or dizziness.

2.2 Label elements

The product is classified and labeled according to the Globally Harmonized System (GHS)

Hazard pictograms

d ~  d ~  d ~  GHS02 GHS05 GHS07

Signal word

Danger

Hazardous Ingredients

Diethyl ether, anhydrous methyllithium

Hazard statements

H224 Extremely flammable liquid and vapor. H250 Catches fire spontaneously if exposed to air. H252 Self-heating in large quantities; may catch fire. H260 In contact with water releases flammable gases, which may ignite spontaneously. H302 Harmful if swallowed. H315 Causes skin irritation. H318 Causes serious eye damage. H336 May cause drowsiness or dizziness.

Precautionary statements

P231+P232 Handle under inert gas. Protect from moisture. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P422 Store contents under inert gas. P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification system

NFPA ratings (scale 0 - 4) 3 Health = 2 2 1 Fire = 3 W — Reactivity = 1 The substance demonstrates unusual reactivity with water. · HMIS-ratings (scale 0 - 4) HEALTH 2 Health = 2 FIRE 3 Fire = 3 REACTIVITY 1 Reactivity = 1

PBT Substances

Not applicable

vPvB Substances

Not applicable

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