Methyldichlorophosphine, 97%

Hazard statements (CLP)

H226, H252, H314, H318, H330

Code

Statements

H226

Flammable liquid and vapour

2.1 Classification of the substance or mixture

d ~  GHS02 Flame Flam. Liq. 3 H226 Flammable liquid and vapor. Self-heat. 2 H252 Self-heating in large quantities; may catch fire. d ~  GHS06 Skull and crossbones Acute Tox. 2 H330 Fatal if inhaled. d ~  GHS05 Corrosion Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage.

2.2 Label elements

The substance is classified and labeled according to the Globally Harmonized System (GHS).

Hazard pictograms

d ~  d ~  d ~  GHS02 GHS05 GHS06

Signal word

Danger (Contd. of page 1)

Hazardous Ingredients

methylphosphonous dichloride

Hazard statements

H226 Flammable liquid and vapor. H252 Self-heating in large quantities; may catch fire. H330 Fatal if inhaled. H314 Causes severe skin burns and eye damage.

Precautionary statements

P231 Handle under inert gas. P284 [In case of inadequate ventilation] wear respiratory protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P422 Store contents under inert gas. P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification system

NFPA ratings (scale 0 - 4) 4 Health = 3 3 2 Fire = 4 W — Reactivity = 2 The substance demonstrates unusual reactivity with water. · HMIS-ratings (scale 0 - 4) HEALTH 3 Health = 3 FIRE 4 Fire = 4 REACTIVITY 2 Reactivity = 2

PBT Substances

Not applicable

vPvB Substances

Not applicable