Envoy 20 WP

Hazard statements (CLP)

H302, H332, H335, H373, H400, H410

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

1999/45/EC Harmful by inhalation. Harmful if swallowed. Very toxic to aquatic organisms may cause long-term adverse effects in the aquatic environment. For the classifications not written out in full in this section the full text can be found in section 16.

Signal word

Warning

Hazard statements

H332: Harmful if inhaled. H302: Harmful if swallowed. H335: May cause respiratory irritation. H373: May cause damage to organs (Gastrointestinal tract) through prolonged or repeated exposure (oral). H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects. EUH401: To avoid risks to human health and the environment, comply with the instructions for use

Prevention

P271: Use only outdoors or in a well-ventilated area. P260: Do not breathe dust/gas/mist/vapors. P270: Do not eat, drink or smoke when using this product. P264: Wash contaminated body parts thoroughly after handling.

Response

P311: Call a POISON CENTER or doctor/physician. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P301 + P330 IF SWALLOWED rinse mouth P391: Collect spillage

Storage

P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up.

Precautionary statements

Disposal) P501 Dispose of contents/container to hazardous or special waste collection Point. Labeling of special preparations (GHS): EUH208 May produce an allergic reaction.

Contains

TEBUFENPYRAD

Hazardous Ingredients

for labelling TEBUFENPYRAD, SODIUM DODECYL SULPHATE According to

Hazard pictograms

Xn: Harmful. N: Dangerous for the environment.

R-phrase(s)

R20: Harmful by inhalation. R22: Harmful if swallowed. R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S-phrase(s)

S2 :Keep out of the reach of children. S13: Keep away from food, drink and animal feeding stuffs. S20/21: When using do not eat, drink or smoke. S35: This material and its container must be disposed of in a safe way. S46: If swallowed, seek medical advice immediately and show this container or label. S57: Use appropriate container to avoid environmental contamination. Hazard determining component(s) for labelling: TEBUFENPYRAD, SODIUM DODECYL SULPHATE The product contains: TEBUFENPYRAD

Further information

In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow reaching sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. ACCIDENTAL RELEASE MEASURE: 6.1. Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Avoid contact with the skin, eyes and clothing. Avoid dust formation. 6.2. Environmental precautions Do not allow contamination of public drains or surface or ground waters. Inform local water plc if spillage enters drains and the Environment Agency (England & Wales), the Scottish Environmental Protection Agency (Scotland), or the Environment and Heritage Service (Northern Ireland) if it enters surface or ground waters. Keep people and animals away. 6.3. Methods and material for containment and cleaning up For small amounts: Contain with dust binding material and dispose of. For large amounts: Sweep/shovel up. Avoid raising dust. Cleaning operations should be carried out only while wearing breathing apparatus. Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. 6.4. Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13. HANDLING AND STORAGE: 7.1. Precautions for safe handling No special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. Protection against fire and explosion: Dust can form an explosive mixture with air. Avoid dust formation. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy. 7.2. Conditions for safe storage, including any incompatibilities Segregate from foods and animal feeds. Further information on storage conditions: Protect against moisture. Keep away from heat. Protect from direct sunlight. Protect from temperatures above: 30 °C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time. 7.3. Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed. Exposure control / PERSONAL PROTECTION: 8.1. Control parameters Components with occupational exposure limits. 1332-58-7: Kaolin TWA value 2 mg/m3 (WEL/EH 40 (UK)), Respirable dust 7631-86-9: Silicon dioxide TWA value 6 mg/m3 (WEL/EH 40 (UK)), Inhalable dust TWA value 2.4 mg/m3 (WEL/EH 40 (UK)), Respirable dust Refer to the current edition of HSE Guidance Note EH40 Occupational Exposure Limits (United Kingdom). For normal use and handling refer to the product label/leaflet. In all other cases the following apply 8.2. Exposure controls Personal protective equipment Respiratory protection: Suitable respiratory protection for higher concentrations or long-term effect: Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2) Hand protection: Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended Protective index 6, corresponding > 480 minutes of permeation time according to EN 374) E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) etc. Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust). General safety and hygiene measuresThe statements on personal protective equipment in the instructions for use apply when handling crop-protection agents in final-consumer packing. Wearing of closed work clothing is recommended. Store work clothing separately. Keep away from food, drink and animal feeding stuffs. PHYSICAL AND CHEMICAL PROPERTIES: 9.1. Information on basic physical and chemical properties: Form powder Color Beige Odour faint odour Odour threshold Not determined since harmful by inhalation pH value approx. 8 – 9 (1 %(m), 21 °C) (as suspension) Melting point > 460 °C The data given are those of the active ingredient. Boiling point The product is a non-volatile solid Flash point not applicable Evaporation rate not applicable Flammability not self-igniting Lower explosion limit As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used Appropriately and in accordance with the intended use. Upper explosion limit As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. Vapour pressure The product has not been tested Relative vapour density not applicable Solubility in water Dispersible Partitioning coefficient n- not applicable octanol\water Self ignition not self-igniting Thermal composition No decomposition if stored and handled as prescribed/indicated. Viscosity, dynamic: not applicable, the product is a solid Explosion hazard: Based on the chemical structure there is no indicating of explosive properties. Fire promoting properties: Based on its structural properties the product is not classified as oxidizing Bulk density approx. 300 - 400 kg/m3 (20 °C) STABILITY AND REACTIVITY: 10.1. Reactivity No hazardous reactions if stored and handled as prescribed/indicated. 10.2. Chemical stability The product is stable if stored and handled as prescribed/indicated. 10.3. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. 10.4. Conditions to avoid See MSDS section 7 - Handling and storage. 10.5. Incompatible materials Substances to avoid: strong acids, strong bases, strong oxidizing agents 10.6. Hazardous decomposition products Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated TOXICOLOGICAL INFORMATION: 11.1. Information on toxicological effects Acute toxicity Assessment of acute toxicity: The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Of moderate toxicity after short-term inhalation. Of moderate toxicity after single ingestion. Virtually nontoxic after a single skin contact. Experimental/calculated data: LD50 rat (oral): 1,278 mg/kg LC50 rat (by inhalation): 2.1 mg/l 4 h LD50 rat (dermal): > 4,000 mg/kg No mortality was observed Irritation Assessment of irritating effects: Not irritating to the eyes. Not irritating to the skin. Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Serious eye damage/irritation rabbit: non-irritant Respiratory/Skin sensitization Assessment of sensitization: There is no evidence of a skin-sensitizing potential. Experimental/calculated data: Modified Buehler test guinea pig: Skin sensitizing effects were not observed in animal studies. Germ cell mutagenicity Assessment of mutagenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Mutagenicity tests revealed no genotoxic potential. Carcinogenicity Assessment of carcinogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: Kaolin Assessment of carcinogenicity: Indication of possible carcinogenic effect in animal tests. However, the relevance of this result for humans is unclear Reproductive toxicity Assessment of reproduction toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of animal studies gave no indication of a fertility impairing effect. Developmental toxicity Assessment of teratogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals. Specific target organ toxicity (single exposure) Assessment of STOT single: Causes temporary irritation of the respiratory tract. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: Tebufenpyrad Assessment of repeated dose toxicity: Repeated oral exposure may affect certain organs. Damages the gastrointestinal tract. Assessment of repeated dose toxicity: Repeated inhalative uptake of particles/dust reaching the alveoli may cause damage to the lungs. Other relevant toxicity information Misuse can be harmful to health. ECOLOGICAL INFORMATION: - 12.1. Toxicity: Assessment of aquatic toxicity: Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Toxicity to fish: LC50 (96 h) 0.019 mg/l, Oncorhynchus mykiss Aquatic invertebrates: LC50 (48 h) 0.277 mg/l, Daphnia magna Aquatic plants: EC50 (72 h) 6.6 mg/l, Pseudokirchneriella subcapitata