JOHNSEN"S DE-ICER 10 OZ

Hazard statements (CLP)

H301+H311, H311

Code

Statements

H301+H311

Toxic if swallowed or in contact with skin

SECTION 2: Hazards identification

OSHA according to Federal Register

Health hazards

Toxic in contact with skin Symptoms/injuries after eye contact May cause slight eye irritation . Inflammation/damage of the eye tissue. Irritation of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. Suitable extinguishing media Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media Do not use a heavy water stream. Fire hazard Flammable aerosol. Explosion hazard Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. DO NOT fight fire when fire

Further information

Aerosol Level 2. General measures ignition sources. Use special care to avoid static electric charges. 6.1.1. For non-emergency personnel Protective equipment Gloves. Safety glasses. Emergency procedures Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment Equip cleanup crew with proper protection. Avoid breathing dust,fume,gas,mist,vapor spray. Emergency procedures Ventilate area. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. For containment Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Methods for cleaning up Store away from other materials. See Heading 8. Exposure controls and personal protection. Additional hazards when processed Hazardous waste due to potential risk of explosion. Pressurized container: Do not pierce or burn, even after use. Precautions for safe handling Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Do not spray on an open flame or other ignition source. Do not breathe dust,fumes,gas,mist,vapor spray. Hygiene measures Wash contaminated clothing before reuse. Always wash hands after handling the product. Remove contaminated clothes. Separate working clothes from town clothes. Launder separately. Do not eat, drink or smoke when using this product. Wash affected areas thoroughly after handling. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Technical measures Proper grounding procedures to avoid static electricity should be followed. Storage conditions Keep only in the original container in a cool, well ventilated place away from Keep container closed when not in use. Do not expose to temperatures exceeding 50 °C/ 122 °F. Keep in fireproof place. Incompatible products Strong bases. Strong acids. Incompatible materials Sources of ignition. Direct sunlight. Heat sources. Storage area Store in a well-ventilated place. Follow Label Directions. 100 mg/m? (Ethylene glycol; USA; Momentary value TLV - Adopted Value) USA ACGIH | | ACGIH TWA (ppm) | 3 ppm (Ethanolamine; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value) USA ACGIH ACGIH STEL (ppm) 6 ppm (Ethanolamine; USA; Short time value; TLV - Adopted Value) USA ACGIH ACGIH TWA (ppm) 1000 ppm Listed under Aliphatic hydrocarbon gases alkane C1-C4 Do not eat, drink or smoke during use. Physical state Gas Appearance Liquid. Color Colourless to light yellow. Odor Mild . Sweet. Alcohol odour. Odor threshold No data available pH No data available Relative evaporation rate (butyl acetate=1) No data available Melting point No data available Freezing point No data available Boiling point 65 °C (Lowest Component) Flash point -96.23 °C (Lowest Component) Auto-ignition temperature No data available Decomposition temperature No data available Flammability (solid, gas) No data available Vapor pressure No data available Relative vapor density at 20 °C No data available Relative density > 0.85 Solubility Soluble in alcohols. Soluble in water. Log Pow No data available Log Kow No data available Viscosity, kinematic No data available Viscosity, dynamic No data available Explosive properties No data available Oxidizing properties No data available Explosion limits No data available VOC content according to Federal Register Avoid release to the environment. Waste disposal recommendations Dispose in a safe manner in accordance with local/national regulations. Container under pressure. Do not drill or burn even after use. Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. Additional information Flammable vapors may accumulate in the container. Ecology - waste materials Avoid release to the environment. Hazardous waste due to toxicity. US DOT (ground): UN1950, Aerosols, 2.1, Limited Quantity ICAO/IATA (air): UN1950, Aerosols, 2.1 (6.1), Ill IMO/IMDG (water): UN1950, Aerosols, 2.1 (6.1), Ill Special Provisions: N82 - See 173.306 of this subchapter for classification criteria for flammable aerosols Proper Shipping Name (DOT) Aerosols Flammable, (each not exceeding 1 L capacity) Class (DOT) 2.1- Class 2.1 - Flammable gas 49 CFR 173.115 Hazard labels (DOT) 2.1 - Flammable gas DOT Special Provisions (49 CFR 172.102) N82 - See 173.306 of this subchapter for classification criteria for flammable aerosols DOT Packaging Exceptions (49 CFR 173.xxx) 306 DOT Packaging Non Bulk (49 CFR 173.xxx) None DOT Packaging Bulk (49 CFR 173.xxx) None

Aspiration hazard

Not classified Potential Adverse human health effects and Based on available data, the classification criteria are not met. Toxic if swallowed. Toxic in symptoms contact with skin. Symptoms/injuries after inhalation Shortness of breath. Symptoms/injuries after skin contact Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Symptoms/injuries after eye contact May cause slight eye irritation . Inflammation/damage of the eye tissue. Irritation of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. according to Federal Register