Stonclad GR Amine

Hazard statements (CLP)

H302, H312, H314, H317, H332, H335, H360F

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

1272/2008 Classification of the substance or mixture

2.2 Label elements

Symbol(s) of Product

Signal word

Danger Named Chemicals on Label 4,4'-isopropylidenediphenol, Diethylenetriamine, N-(3-(trimethoxysilyl)propyl)ethylenediamine, 4,4' - isopropylidenediphenol oligomeric reaction products with 1-chloro-2,3-epoxypropane, reaction products with dietheylenetriamine

Hazard statements

Acute Toxicity, Oral, category 4 H302 Harmful if swallowed. Acute Toxicity, Dermal, category 4 H312 Harmful in contact with skin. Skin Corrosion, category 1B H314-1B Causes severe skin burns and eye damage. Skin Sensitizer, category 1 H317 May cause an allergic skin reaction. Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled. STOT, single exposure, category 3, RTI H335 May cause respiratory irritation. Reproductive_ToxicityF_category_1B H360F May damage fertility.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/ face protection. P284 Wear respiratory protection. P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P301+330+331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302+352 IF ON SKIN: Wash with plenty of soap and water. P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention P312 Call a POISON CENTER or doctor/physician if you feel unwell. P333+313 If skin irritation or rash occurs: Get medical advice/attention. P352 Wash with plenty of soap and water. P362+364 Take off contaminated clothing and wash it before reuse. P363 Wash contaminated clothing before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

2.3 Other hazards

This product contains a component that is toxic by inhalation when aerosolized or sprayed. Please refer to section 11 of the SDS for toxicity information. Review the toxicity against the intended use. If product is not being aerosolized or sprayed, the inhalation toxicity may not be applicable. This product is classified as a "Acute Toxicity, Inhalation, Category 1" due to containing Diethylenetriamine (CAS # 111-40-0). Numerous Industrial Hygiene air monitoring studies have been conducted by Stonhard to determine actual levels of exposure to Diethylenetriamine during product installations to application personnel. In each case levels of exposure were found to be well below the ACGIH Threshold Limit Value and NIOSH Recommended Exposure Limit of 1 ppm.

Results of PBT and vPvB assessment

No Information Endocrine disrupting properties - Toxicity Name According to EEC CAS-No. No Information Endocrine disrupting properties - Ecotoxicity Name According to EEC CAS-No. No Information

2.1 Classification of the substance or mixture

Classification according to Classification, Labeling & Packaging Regulation (EC) 1272/2008 HAZARD STATEMENTS Acute Toxicity, Oral, category 4 H302 Acute Toxicity, Dermal, category 4 H312 Skin Corrosion, category 1B H314-1B Skin Sensitizer, category 1 H317 Acute Toxicity, Inhalation, category 4 H332 STOT, single exposure, category 3, RTI H335 Reproductive_ToxicityF_category_1B H360F